An Intriguing Structural and Functional Analogy Between Large Cations and Anion-Centered (X2−Mn+) Clusters Exemplifiedby Double Chalcogenides K, Rb, Cs, TI(I) and Ag(I), Cu(I)
The structures of chalcogenides where some large S 2− , Se 2− , Te 2− anions are closely surrounded by 6–12 Cu + or Ag + cations in 3–4 coordination are considered. These compact (X 2− M n + ) groups, being the anion-centered clusters (ACCs), can be thought as highly charged voluminous analogues of...
Gespeichert in:
| Veröffentlicht in: | Journal of structural chemistry 2019-03, Vol.60 (3), p.449-456 |
|---|---|
| 1. Verfasser: | |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 456 |
|---|---|
| container_issue | 3 |
| container_start_page | 449 |
| container_title | Journal of structural chemistry |
| container_volume | 60 |
| creator | Bakakin, V. V. |
| description | The structures of chalcogenides where some large S
2−
, Se
2−
, Te
2−
anions are closely surrounded by 6–12 Cu
+
or Ag
+
cations in 3–4 coordination are considered. These compact (X
2−
M
n
+
) groups, being the anion-centered clusters (ACCs), can be thought as highly charged voluminous analogues of large K, Rb, T1
(I)
, Cs cations. Together they perform related structural functions. |
| doi_str_mv | 10.1134/S0022476619030132 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2220800806</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2220800806</sourcerecordid><originalsourceid>FETCH-LOGICAL-c268t-b2405ce735d272b19b732401e916280035cefcfbf3bdb4b0ae1b1292f63c1fae3</originalsourceid><addsrcrecordid>eNp1UctOwkAUnRhNRPQD3E3iBiLVeUAfS6ygRIyJYOKumWlva0mZ4kwnyh-49k_8Jb_EQUxcGDf3cV6LexE6puSMUt4_nxHCWD_wfRoRTihnO6hFBwH3wiCIdlFrQ3sbfh8dGLMghERh5LfQx1DhiWp0WdhSFXjWaJs2VosKC5XhsVVpU9bKrUNX6mKNL6B5AVB4KnQBOBYb2nyLh8qNXgyqAQ0Z7jyyz7f3W3XaxXFljQMNHr3CclWVeQmZXOPL2srKZTyJKq0LUGUGBt_08L3s4dj08HzSmXS30YWbHGhdO0R7uagMHP30NnoYj-bxtTe9u5rEw6mXMj9sPMn6ZJBCwAcZC5ikkQy4gyhE1GchIdyReZrLnMtM9iURQCVlEct9ntJcAG-jk23uStfPFkyTLGqr3RVMwhgjLiIkvlPRrSrVtTEa8mSly6XQ64SSZPOZ5M9nnIdtPcZpVQH6N_l_0xejko63</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2220800806</pqid></control><display><type>article</type><title>An Intriguing Structural and Functional Analogy Between Large Cations and Anion-Centered (X2−Mn+) Clusters Exemplifiedby Double Chalcogenides K, Rb, Cs, TI(I) and Ag(I), Cu(I)</title><source>SpringerNature Journals</source><creator>Bakakin, V. V.</creator><creatorcontrib>Bakakin, V. V.</creatorcontrib><description>The structures of chalcogenides where some large S
2−
, Se
2−
, Te
2−
anions are closely surrounded by 6–12 Cu
+
or Ag
+
cations in 3–4 coordination are considered. These compact (X
2−
M
n
+
) groups, being the anion-centered clusters (ACCs), can be thought as highly charged voluminous analogues of large K, Rb, T1
(I)
, Cs cations. Together they perform related structural functions.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476619030132</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anions ; Atomic ; Atomic/Molecular Structure and Spectra ; Cations ; Cesium ; Chalcogenides ; Chemistry ; Chemistry and Materials Science ; Clusters ; Copper ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Rubidium ; Silver ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2019-03, Vol.60 (3), p.449-456</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-b2405ce735d272b19b732401e916280035cefcfbf3bdb4b0ae1b1292f63c1fae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476619030132$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476619030132$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Bakakin, V. V.</creatorcontrib><title>An Intriguing Structural and Functional Analogy Between Large Cations and Anion-Centered (X2−Mn+) Clusters Exemplifiedby Double Chalcogenides K, Rb, Cs, TI(I) and Ag(I), Cu(I)</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>The structures of chalcogenides where some large S
2−
, Se
2−
, Te
2−
anions are closely surrounded by 6–12 Cu
+
or Ag
+
cations in 3–4 coordination are considered. These compact (X
2−
M
n
+
) groups, being the anion-centered clusters (ACCs), can be thought as highly charged voluminous analogues of large K, Rb, T1
(I)
, Cs cations. Together they perform related structural functions.</description><subject>Anions</subject><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Cations</subject><subject>Cesium</subject><subject>Chalcogenides</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Clusters</subject><subject>Copper</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Rubidium</subject><subject>Silver</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1UctOwkAUnRhNRPQD3E3iBiLVeUAfS6ygRIyJYOKumWlva0mZ4kwnyh-49k_8Jb_EQUxcGDf3cV6LexE6puSMUt4_nxHCWD_wfRoRTihnO6hFBwH3wiCIdlFrQ3sbfh8dGLMghERh5LfQx1DhiWp0WdhSFXjWaJs2VosKC5XhsVVpU9bKrUNX6mKNL6B5AVB4KnQBOBYb2nyLh8qNXgyqAQ0Z7jyyz7f3W3XaxXFljQMNHr3CclWVeQmZXOPL2srKZTyJKq0LUGUGBt_08L3s4dj08HzSmXS30YWbHGhdO0R7uagMHP30NnoYj-bxtTe9u5rEw6mXMj9sPMn6ZJBCwAcZC5ikkQy4gyhE1GchIdyReZrLnMtM9iURQCVlEct9ntJcAG-jk23uStfPFkyTLGqr3RVMwhgjLiIkvlPRrSrVtTEa8mSly6XQ64SSZPOZ5M9nnIdtPcZpVQH6N_l_0xejko63</recordid><startdate>20190301</startdate><enddate>20190301</enddate><creator>Bakakin, V. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20190301</creationdate><title>An Intriguing Structural and Functional Analogy Between Large Cations and Anion-Centered (X2−Mn+) Clusters Exemplifiedby Double Chalcogenides K, Rb, Cs, TI(I) and Ag(I), Cu(I)</title><author>Bakakin, V. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-b2405ce735d272b19b732401e916280035cefcfbf3bdb4b0ae1b1292f63c1fae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Anions</topic><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Cations</topic><topic>Cesium</topic><topic>Chalcogenides</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Clusters</topic><topic>Copper</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Rubidium</topic><topic>Silver</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bakakin, V. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bakakin, V. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Intriguing Structural and Functional Analogy Between Large Cations and Anion-Centered (X2−Mn+) Clusters Exemplifiedby Double Chalcogenides K, Rb, Cs, TI(I) and Ag(I), Cu(I)</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2019-03-01</date><risdate>2019</risdate><volume>60</volume><issue>3</issue><spage>449</spage><epage>456</epage><pages>449-456</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>The structures of chalcogenides where some large S
2−
, Se
2−
, Te
2−
anions are closely surrounded by 6–12 Cu
+
or Ag
+
cations in 3–4 coordination are considered. These compact (X
2−
M
n
+
) groups, being the anion-centered clusters (ACCs), can be thought as highly charged voluminous analogues of large K, Rb, T1
(I)
, Cs cations. Together they perform related structural functions.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476619030132</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4766 |
| ispartof | Journal of structural chemistry, 2019-03, Vol.60 (3), p.449-456 |
| issn | 0022-4766 1573-8779 |
| language | eng |
| recordid | cdi_proquest_journals_2220800806 |
| source | SpringerNature Journals |
| subjects | Anions Atomic Atomic/Molecular Structure and Spectra Cations Cesium Chalcogenides Chemistry Chemistry and Materials Science Clusters Copper Inorganic Chemistry Molecular Optical and Plasma Physics Physical Chemistry Rubidium Silver Solid State Physics |
| title | An Intriguing Structural and Functional Analogy Between Large Cations and Anion-Centered (X2−Mn+) Clusters Exemplifiedby Double Chalcogenides K, Rb, Cs, TI(I) and Ag(I), Cu(I) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-16T02%3A50%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=An%20Intriguing%20Structural%20and%20Functional%20Analogy%20Between%20Large%20Cations%20and%20Anion-Centered%20(X2%E2%88%92Mn+)%20Clusters%20Exemplifiedby%20Double%20Chalcogenides%20K,%20Rb,%20Cs,%20TI(I)%20and%20Ag(I),%20Cu(I)&rft.jtitle=Journal%20of%20structural%20chemistry&rft.au=Bakakin,%20V.%20V.&rft.date=2019-03-01&rft.volume=60&rft.issue=3&rft.spage=449&rft.epage=456&rft.pages=449-456&rft.issn=0022-4766&rft.eissn=1573-8779&rft_id=info:doi/10.1134/S0022476619030132&rft_dat=%3Cproquest_cross%3E2220800806%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2220800806&rft_id=info:pmid/&rfr_iscdi=true |