Investigation on 2-mercaptobenzothiazole behavior as corrosion inhibitor for 316-stainless steel in acidic media
Purpose – The purpose of this paper is to describe the behavior of 2-mercaptobenzothiazole (MBT) on the corrosion of 316 stainless steel (SS) in acidic media and the mechanism of its action. Design/methodology/approach – The inhibitive effect of MBT towards the corrosion of 316 SS in acid solution i...
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creator | Goudarzi, Narges Farahani, Hadi |
description | Purpose
– The purpose of this paper is to describe the behavior of 2-mercaptobenzothiazole (MBT) on the corrosion of 316 stainless steel (SS) in acidic media and the mechanism of its action.
Design/methodology/approach
– The inhibitive effect of MBT towards the corrosion of 316 SS in acid solution is studied by means of weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy. The effect of inhibitor concentration and temperature against inhibitor action is investigated. Adsorption isotherm and adsorption mechanism are also discussed.
Findings
– MBT acts as inhibitor for this type of steel in acidic medium. This compound is mixed-type inhibitor and inhibition efficiency increased with increasing inhibitor concentration. MBT retards the rate of both anodic and cathodic corrosion reactions by adsorbing and forming a layer on the steel surface and the adsorption obeys Temkin adsorption isotherms. The inhibition efficiency is temperature dependence in the range from 25 to 65°C and some thermodynamic parameters were calculated and analyzed.
Originality/value
– The results shown in this paper are an insight to the understanding of the corrosion resistance and electrochemical behavior of 316 SS in the presence of MBT for future industrial applications and development. It is the first time that corrosion inhibition effects of MBT on 316 SS have been evaluated. |
doi_str_mv | 10.1108/ACMM-11-2012-1223 |
format | Article |
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– The purpose of this paper is to describe the behavior of 2-mercaptobenzothiazole (MBT) on the corrosion of 316 stainless steel (SS) in acidic media and the mechanism of its action.
Design/methodology/approach
– The inhibitive effect of MBT towards the corrosion of 316 SS in acid solution is studied by means of weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy. The effect of inhibitor concentration and temperature against inhibitor action is investigated. Adsorption isotherm and adsorption mechanism are also discussed.
Findings
– MBT acts as inhibitor for this type of steel in acidic medium. This compound is mixed-type inhibitor and inhibition efficiency increased with increasing inhibitor concentration. MBT retards the rate of both anodic and cathodic corrosion reactions by adsorbing and forming a layer on the steel surface and the adsorption obeys Temkin adsorption isotherms. The inhibition efficiency is temperature dependence in the range from 25 to 65°C and some thermodynamic parameters were calculated and analyzed.
Originality/value
– The results shown in this paper are an insight to the understanding of the corrosion resistance and electrochemical behavior of 316 SS in the presence of MBT for future industrial applications and development. It is the first time that corrosion inhibition effects of MBT on 316 SS have been evaluated.</description><identifier>ISSN: 0003-5599</identifier><identifier>EISSN: 1758-4221</identifier><identifier>DOI: 10.1108/ACMM-11-2012-1223</identifier><language>eng</language><publisher>Bradford: Emerald Group Publishing Limited</publisher><subject>Acids ; Adsorption ; Analytical methods ; Austenitic stainless steels ; Corrosion ; Corrosion effects ; Corrosion inhibitors ; Corrosion mechanisms ; Corrosion potential ; Corrosion prevention ; Corrosion resistance ; Corrosion resistant steels ; Efficiency ; Electrochemical analysis ; Electrochemical impedance spectroscopy ; Electrochemistry ; Electrode polarization ; Electrodes ; Engineering ; High temperature ; Industrial applications ; Inhibition ; Inhibitors ; Investigations ; Isotherms ; Mechanical engineering ; Mercaptobenzothiazole ; Physical properties ; Spectrum analysis ; Stainless steel ; Steels ; Studies ; Sulfur ; Surface chemistry ; Temperature dependence ; Weight loss</subject><ispartof>Anti-corrosion methods and materials, 2014-01, Vol.61 (1), p.20-26</ispartof><rights>Emerald Group Publishing Limited</rights><rights>Copyright Emerald Group Publishing Limited 2014</rights><rights>Emerald Group Publishing Limited 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c412t-8b07d1badceffab30421ef7ebea89058190bddfda60d6b80776ea3982d8058f73</citedby><cites>FETCH-LOGICAL-c412t-8b07d1badceffab30421ef7ebea89058190bddfda60d6b80776ea3982d8058f73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.emerald.com/insight/content/doi/10.1108/ACMM-11-2012-1223/full/pdf$$EPDF$$P50$$Gemerald$$H</linktopdf><linktohtml>$$Uhttps://www.emerald.com/insight/content/doi/10.1108/ACMM-11-2012-1223/full/html$$EHTML$$P50$$Gemerald$$H</linktohtml><link.rule.ids>314,777,781,962,11616,21676,27905,27906,52667,52670,53225,53353</link.rule.ids></links><search><creatorcontrib>Goudarzi, Narges</creatorcontrib><creatorcontrib>Farahani, Hadi</creatorcontrib><title>Investigation on 2-mercaptobenzothiazole behavior as corrosion inhibitor for 316-stainless steel in acidic media</title><title>Anti-corrosion methods and materials</title><description>Purpose
– The purpose of this paper is to describe the behavior of 2-mercaptobenzothiazole (MBT) on the corrosion of 316 stainless steel (SS) in acidic media and the mechanism of its action.
Design/methodology/approach
– The inhibitive effect of MBT towards the corrosion of 316 SS in acid solution is studied by means of weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy. The effect of inhibitor concentration and temperature against inhibitor action is investigated. Adsorption isotherm and adsorption mechanism are also discussed.
Findings
– MBT acts as inhibitor for this type of steel in acidic medium. This compound is mixed-type inhibitor and inhibition efficiency increased with increasing inhibitor concentration. MBT retards the rate of both anodic and cathodic corrosion reactions by adsorbing and forming a layer on the steel surface and the adsorption obeys Temkin adsorption isotherms. The inhibition efficiency is temperature dependence in the range from 25 to 65°C and some thermodynamic parameters were calculated and analyzed.
Originality/value
– The results shown in this paper are an insight to the understanding of the corrosion resistance and electrochemical behavior of 316 SS in the presence of MBT for future industrial applications and development. It is the first time that corrosion inhibition effects of MBT on 316 SS have been evaluated.</description><subject>Acids</subject><subject>Adsorption</subject><subject>Analytical methods</subject><subject>Austenitic stainless steels</subject><subject>Corrosion</subject><subject>Corrosion effects</subject><subject>Corrosion inhibitors</subject><subject>Corrosion mechanisms</subject><subject>Corrosion potential</subject><subject>Corrosion prevention</subject><subject>Corrosion resistance</subject><subject>Corrosion resistant steels</subject><subject>Efficiency</subject><subject>Electrochemical analysis</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemistry</subject><subject>Electrode polarization</subject><subject>Electrodes</subject><subject>Engineering</subject><subject>High temperature</subject><subject>Industrial applications</subject><subject>Inhibition</subject><subject>Inhibitors</subject><subject>Investigations</subject><subject>Isotherms</subject><subject>Mechanical engineering</subject><subject>Mercaptobenzothiazole</subject><subject>Physical properties</subject><subject>Spectrum analysis</subject><subject>Stainless steel</subject><subject>Steels</subject><subject>Studies</subject><subject>Sulfur</subject><subject>Surface chemistry</subject><subject>Temperature dependence</subject><subject>Weight loss</subject><issn>0003-5599</issn><issn>1758-4221</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kU1r3DAQhkVJoJuPH9CboZde1GgkrSUfw9ImgYRe2rMYWeOsgtfaSt5A8-srs700hMCIGUnPO0jzMvYJxFcAYa-uNw8PHIBLAZKDlOoDW4FZW66lhBO2EkIovl533Ud2VspT3UqpzYrt76ZnKnN8xDmmqakh-Y5yj_s5eZpe0ryN-JJGajxt8Tmm3GBp-pRzKosgTtvo41yPh7oUtLzMGKeRSmnKTDRWosE-htg3OwoRL9jpgGOhy3_5nP36_u3n5pbf_7i521zf816DnLn1wgTwGHoaBvRKaAk0GPKEthNrC53wIQwBWxFab4UxLaHqrAy23g5GnbMvx777nH4f6hfdLpaexhEnSofiQHdagW7Ngn5-hT6lQ57q65yUUhi1kO9RtU1ntdS6rRQcqb4OqGQa3D7HHeY_DoRbnHKLU7Vyi1NucapqxFFDdfI4hjcl_5mr_gLMH5U2</recordid><startdate>20140101</startdate><enddate>20140101</enddate><creator>Goudarzi, Narges</creator><creator>Farahani, Hadi</creator><general>Emerald Group Publishing Limited</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SE</scope><scope>7SR</scope><scope>7WY</scope><scope>7XB</scope><scope>8AF</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F1W</scope><scope>F28</scope><scope>FR3</scope><scope>GNUQQ</scope><scope>H96</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K6~</scope><scope>KB.</scope><scope>L.-</scope><scope>L.G</scope><scope>L6V</scope><scope>M0F</scope><scope>M2P</scope><scope>M7S</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQBIZ</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope><scope>Q9U</scope></search><sort><creationdate>20140101</creationdate><title>Investigation on 2-mercaptobenzothiazole behavior as corrosion inhibitor for 316-stainless steel in acidic media</title><author>Goudarzi, Narges ; Farahani, Hadi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c412t-8b07d1badceffab30421ef7ebea89058190bddfda60d6b80776ea3982d8058f73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Acids</topic><topic>Adsorption</topic><topic>Analytical methods</topic><topic>Austenitic stainless steels</topic><topic>Corrosion</topic><topic>Corrosion effects</topic><topic>Corrosion inhibitors</topic><topic>Corrosion mechanisms</topic><topic>Corrosion potential</topic><topic>Corrosion prevention</topic><topic>Corrosion resistance</topic><topic>Corrosion resistant steels</topic><topic>Efficiency</topic><topic>Electrochemical analysis</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemistry</topic><topic>Electrode polarization</topic><topic>Electrodes</topic><topic>Engineering</topic><topic>High temperature</topic><topic>Industrial applications</topic><topic>Inhibition</topic><topic>Inhibitors</topic><topic>Investigations</topic><topic>Isotherms</topic><topic>Mechanical engineering</topic><topic>Mercaptobenzothiazole</topic><topic>Physical properties</topic><topic>Spectrum analysis</topic><topic>Stainless steel</topic><topic>Steels</topic><topic>Studies</topic><topic>Sulfur</topic><topic>Surface chemistry</topic><topic>Temperature dependence</topic><topic>Weight loss</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Goudarzi, Narges</creatorcontrib><creatorcontrib>Farahani, Hadi</creatorcontrib><collection>CrossRef</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>STEM Database</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>ProQuest Central Student</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Business Collection</collection><collection>Materials Science Database</collection><collection>ABI/INFORM Professional Advanced</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>ProQuest Engineering Collection</collection><collection>ABI/INFORM Trade & Industry</collection><collection>Science Database</collection><collection>Engineering Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Business</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><collection>ProQuest Central Basic</collection><jtitle>Anti-corrosion methods and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Goudarzi, Narges</au><au>Farahani, Hadi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation on 2-mercaptobenzothiazole behavior as corrosion inhibitor for 316-stainless steel in acidic media</atitle><jtitle>Anti-corrosion methods and materials</jtitle><date>2014-01-01</date><risdate>2014</risdate><volume>61</volume><issue>1</issue><spage>20</spage><epage>26</epage><pages>20-26</pages><issn>0003-5599</issn><eissn>1758-4221</eissn><abstract>Purpose
– The purpose of this paper is to describe the behavior of 2-mercaptobenzothiazole (MBT) on the corrosion of 316 stainless steel (SS) in acidic media and the mechanism of its action.
Design/methodology/approach
– The inhibitive effect of MBT towards the corrosion of 316 SS in acid solution is studied by means of weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy. The effect of inhibitor concentration and temperature against inhibitor action is investigated. Adsorption isotherm and adsorption mechanism are also discussed.
Findings
– MBT acts as inhibitor for this type of steel in acidic medium. This compound is mixed-type inhibitor and inhibition efficiency increased with increasing inhibitor concentration. MBT retards the rate of both anodic and cathodic corrosion reactions by adsorbing and forming a layer on the steel surface and the adsorption obeys Temkin adsorption isotherms. The inhibition efficiency is temperature dependence in the range from 25 to 65°C and some thermodynamic parameters were calculated and analyzed.
Originality/value
– The results shown in this paper are an insight to the understanding of the corrosion resistance and electrochemical behavior of 316 SS in the presence of MBT for future industrial applications and development. It is the first time that corrosion inhibition effects of MBT on 316 SS have been evaluated.</abstract><cop>Bradford</cop><pub>Emerald Group Publishing Limited</pub><doi>10.1108/ACMM-11-2012-1223</doi><tpages>7</tpages></addata></record> |
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ispartof | Anti-corrosion methods and materials, 2014-01, Vol.61 (1), p.20-26 |
issn | 0003-5599 1758-4221 |
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source | Emerald Journals; Standard: Emerald eJournal Premier Collection |
subjects | Acids Adsorption Analytical methods Austenitic stainless steels Corrosion Corrosion effects Corrosion inhibitors Corrosion mechanisms Corrosion potential Corrosion prevention Corrosion resistance Corrosion resistant steels Efficiency Electrochemical analysis Electrochemical impedance spectroscopy Electrochemistry Electrode polarization Electrodes Engineering High temperature Industrial applications Inhibition Inhibitors Investigations Isotherms Mechanical engineering Mercaptobenzothiazole Physical properties Spectrum analysis Stainless steel Steels Studies Sulfur Surface chemistry Temperature dependence Weight loss |
title | Investigation on 2-mercaptobenzothiazole behavior as corrosion inhibitor for 316-stainless steel in acidic media |
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