Experimental study on the influence of coal oxidation on coal and gas outburst during invasion of magmatic rocks into coal seams

•The change law of outburst risk prediction indexes in the process of coal oxidation was analyzed.•The conditions of original coals transforming into coals with outburst risk in the process of oxidation were determined.•The influence mechanism of magmatic rock invading coal mass on outburst disaster...

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Veröffentlicht in:Process safety and environmental protection 2019-04, Vol.124, p.213-222
Hauptverfasser: Zhou, Buzhuang, Yang, Shengqiang, Wang, Chaojie, Cai, Jiawen, Xu, Qin, Sang, Naiwen
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creator Zhou, Buzhuang
Yang, Shengqiang
Wang, Chaojie
Cai, Jiawen
Xu, Qin
Sang, Naiwen
description •The change law of outburst risk prediction indexes in the process of coal oxidation was analyzed.•The conditions of original coals transforming into coals with outburst risk in the process of oxidation were determined.•The influence mechanism of magmatic rock invading coal mass on outburst disaster was discussed. This research aims to explore the influence mechanism of coal oxidation on the outburst risk of coal seams after a magmatic rock invasion. Hence, the possibility of an outburst risk in coal seams caused by coal oxidation under different oxygen concentrations was evaluated by utilizing multiple indices to predict the outburst risk of coal and gas. By applying the BEL-MAX automatic analyzer for specific surface area (SSA), the change laws of the Brunauer–Emmett–Teller (BET) SSA and pore volume during coal oxidation were analyzed. Moreover, the change in multiple physical parameters during coal oxidation was measured by employing an industrial measurement instrument, gas chromatograph, initial velocity (△P) tester, and hardness tester. The results indicate that with the increasing oxidizing temperature of coal, the contents of moisture and volatiles in the coal declined constantly while the BET SSA and pore volume increased, thus strengthening the capability of coal mass for adsorbing gas. Moreover, the coal strength reduced with the constant development of pores, as shown by the Protodyakonov’s coefficient (f value) of coal mass that decreased constantly and △P of gas diffusion for reflecting the diffusion capability of coal for the gas to increase gradually with increasing oxidizing temperature. With the increasing oxygen concentration in an oxidizing atmosphere, the required oxidizing temperature at which the comprehensive index reflecting the outburst risk of coal mass was larger than the critical value reduced gradually. Thus, the coupling effect of magmatic rock invasion into coal mass, thermal metamorphism, and oxidation reaction led to the increase in gas content and SSA of coal mass, thus improving the capability of coal for adsorbing and storing gas. Correspondingly, the mechanical strength of coal mass reduced and the initial velocity of gas diffusion from coal mass increased significantly. Additionally, owing to the sealing effect of magmatic rock inhibiting the migration of gas in coal mass in the area, the risk level of coal and gas dynamic disasters in the area increased significantly.
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This research aims to explore the influence mechanism of coal oxidation on the outburst risk of coal seams after a magmatic rock invasion. Hence, the possibility of an outburst risk in coal seams caused by coal oxidation under different oxygen concentrations was evaluated by utilizing multiple indices to predict the outburst risk of coal and gas. By applying the BEL-MAX automatic analyzer for specific surface area (SSA), the change laws of the Brunauer–Emmett–Teller (BET) SSA and pore volume during coal oxidation were analyzed. Moreover, the change in multiple physical parameters during coal oxidation was measured by employing an industrial measurement instrument, gas chromatograph, initial velocity (△P) tester, and hardness tester. The results indicate that with the increasing oxidizing temperature of coal, the contents of moisture and volatiles in the coal declined constantly while the BET SSA and pore volume increased, thus strengthening the capability of coal mass for adsorbing gas. Moreover, the coal strength reduced with the constant development of pores, as shown by the Protodyakonov’s coefficient (f value) of coal mass that decreased constantly and △P of gas diffusion for reflecting the diffusion capability of coal for the gas to increase gradually with increasing oxidizing temperature. With the increasing oxygen concentration in an oxidizing atmosphere, the required oxidizing temperature at which the comprehensive index reflecting the outburst risk of coal mass was larger than the critical value reduced gradually. Thus, the coupling effect of magmatic rock invasion into coal mass, thermal metamorphism, and oxidation reaction led to the increase in gas content and SSA of coal mass, thus improving the capability of coal for adsorbing and storing gas. Correspondingly, the mechanical strength of coal mass reduced and the initial velocity of gas diffusion from coal mass increased significantly. Additionally, owing to the sealing effect of magmatic rock inhibiting the migration of gas in coal mass in the area, the risk level of coal and gas dynamic disasters in the area increased significantly.</description><identifier>ISSN: 0957-5820</identifier><identifier>EISSN: 1744-3598</identifier><identifier>DOI: 10.1016/j.psep.2019.02.017</identifier><language>eng</language><publisher>Rugby: Elsevier B.V</publisher><subject>BET specific surface area ; Coal ; Coal gas outbursts ; Coal moisture ; Coal strength ; Diffusion ; Disasters ; Gas chromatography ; Gaseous diffusion ; Low temperature oxidation ; Mechanical properties ; Metamorphism ; Metamorphism (geology) ; Migration ; Outburst prediction index ; Oxidation ; Oxygen ; Physical properties ; Risk ; Rocks ; Temperature effects ; Temperature requirements ; Velocity ; Volatile compounds ; Volatiles</subject><ispartof>Process safety and environmental protection, 2019-04, Vol.124, p.213-222</ispartof><rights>2019 Institution of Chemical Engineers</rights><rights>Copyright Elsevier Science Ltd. 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This research aims to explore the influence mechanism of coal oxidation on the outburst risk of coal seams after a magmatic rock invasion. Hence, the possibility of an outburst risk in coal seams caused by coal oxidation under different oxygen concentrations was evaluated by utilizing multiple indices to predict the outburst risk of coal and gas. By applying the BEL-MAX automatic analyzer for specific surface area (SSA), the change laws of the Brunauer–Emmett–Teller (BET) SSA and pore volume during coal oxidation were analyzed. Moreover, the change in multiple physical parameters during coal oxidation was measured by employing an industrial measurement instrument, gas chromatograph, initial velocity (△P) tester, and hardness tester. The results indicate that with the increasing oxidizing temperature of coal, the contents of moisture and volatiles in the coal declined constantly while the BET SSA and pore volume increased, thus strengthening the capability of coal mass for adsorbing gas. Moreover, the coal strength reduced with the constant development of pores, as shown by the Protodyakonov’s coefficient (f value) of coal mass that decreased constantly and △P of gas diffusion for reflecting the diffusion capability of coal for the gas to increase gradually with increasing oxidizing temperature. With the increasing oxygen concentration in an oxidizing atmosphere, the required oxidizing temperature at which the comprehensive index reflecting the outburst risk of coal mass was larger than the critical value reduced gradually. Thus, the coupling effect of magmatic rock invasion into coal mass, thermal metamorphism, and oxidation reaction led to the increase in gas content and SSA of coal mass, thus improving the capability of coal for adsorbing and storing gas. Correspondingly, the mechanical strength of coal mass reduced and the initial velocity of gas diffusion from coal mass increased significantly. Additionally, owing to the sealing effect of magmatic rock inhibiting the migration of gas in coal mass in the area, the risk level of coal and gas dynamic disasters in the area increased significantly.</description><subject>BET specific surface area</subject><subject>Coal</subject><subject>Coal gas outbursts</subject><subject>Coal moisture</subject><subject>Coal strength</subject><subject>Diffusion</subject><subject>Disasters</subject><subject>Gas chromatography</subject><subject>Gaseous diffusion</subject><subject>Low temperature oxidation</subject><subject>Mechanical properties</subject><subject>Metamorphism</subject><subject>Metamorphism (geology)</subject><subject>Migration</subject><subject>Outburst prediction index</subject><subject>Oxidation</subject><subject>Oxygen</subject><subject>Physical properties</subject><subject>Risk</subject><subject>Rocks</subject><subject>Temperature effects</subject><subject>Temperature requirements</subject><subject>Velocity</subject><subject>Volatile compounds</subject><subject>Volatiles</subject><issn>0957-5820</issn><issn>1744-3598</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kE1r3DAQhkVpoNtN_kBOgp7tzshrW4ZeSth-QKCX5ixkabzRdtdyJXnZ3PLTI2dzDggG9L7PSDyM3SKUCNh83ZdTpKkUgF0JogRsP7AVtptNUdWd_MhW0NVtUUsBn9jnGPcAgKLFFXvenicK7khj0gce02yfuB95eiTuxuEw02iI-4Ebn2N_dlYnl_N8Xm_0aPlOR-7n1M8hJm7n4MZdZk86vhYHftS7Y6YMD978izlK_gJH0sd4za4GfYh08zbX7OHH9u_dr-L-z8_fd9_vC1M1dSo0WRK6bgeqpEDUWtadGPpGGuybzabW2PcwGGzQgpS6B2u6GoUG2zUNNVCt2ZfL3in4_zPFpPZ-DmN-UgmBskJEubTEpWWCjzHQoKYsR4cnhaAW02qvFtNqMa1AqGw6Q98uEOX_nxwFFY1bxFkXyCRlvXsPfwE-MYmU</recordid><startdate>20190401</startdate><enddate>20190401</enddate><creator>Zhou, Buzhuang</creator><creator>Yang, Shengqiang</creator><creator>Wang, Chaojie</creator><creator>Cai, Jiawen</creator><creator>Xu, Qin</creator><creator>Sang, Naiwen</creator><general>Elsevier B.V</general><general>Elsevier Science Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>7TB</scope><scope>7U7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>KR7</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0003-2275-544X</orcidid></search><sort><creationdate>20190401</creationdate><title>Experimental study on the influence of coal oxidation on coal and gas outburst during invasion of magmatic rocks into coal seams</title><author>Zhou, Buzhuang ; Yang, Shengqiang ; Wang, Chaojie ; Cai, Jiawen ; Xu, Qin ; Sang, Naiwen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c365t-aede2a57fe38211aa8592fb68c1b6445a1bb0fc161d088ab0dc9512a0d966e603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>BET specific surface area</topic><topic>Coal</topic><topic>Coal gas outbursts</topic><topic>Coal moisture</topic><topic>Coal strength</topic><topic>Diffusion</topic><topic>Disasters</topic><topic>Gas chromatography</topic><topic>Gaseous diffusion</topic><topic>Low temperature oxidation</topic><topic>Mechanical properties</topic><topic>Metamorphism</topic><topic>Metamorphism (geology)</topic><topic>Migration</topic><topic>Outburst prediction index</topic><topic>Oxidation</topic><topic>Oxygen</topic><topic>Physical properties</topic><topic>Risk</topic><topic>Rocks</topic><topic>Temperature effects</topic><topic>Temperature requirements</topic><topic>Velocity</topic><topic>Volatile compounds</topic><topic>Volatiles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Buzhuang</creatorcontrib><creatorcontrib>Yang, Shengqiang</creatorcontrib><creatorcontrib>Wang, Chaojie</creatorcontrib><creatorcontrib>Cai, Jiawen</creatorcontrib><creatorcontrib>Xu, Qin</creatorcontrib><creatorcontrib>Sang, Naiwen</creatorcontrib><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Process safety and environmental protection</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Buzhuang</au><au>Yang, Shengqiang</au><au>Wang, Chaojie</au><au>Cai, Jiawen</au><au>Xu, Qin</au><au>Sang, Naiwen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental study on the influence of coal oxidation on coal and gas outburst during invasion of magmatic rocks into coal seams</atitle><jtitle>Process safety and environmental protection</jtitle><date>2019-04-01</date><risdate>2019</risdate><volume>124</volume><spage>213</spage><epage>222</epage><pages>213-222</pages><issn>0957-5820</issn><eissn>1744-3598</eissn><abstract>•The change law of outburst risk prediction indexes in the process of coal oxidation was analyzed.•The conditions of original coals transforming into coals with outburst risk in the process of oxidation were determined.•The influence mechanism of magmatic rock invading coal mass on outburst disaster was discussed. This research aims to explore the influence mechanism of coal oxidation on the outburst risk of coal seams after a magmatic rock invasion. Hence, the possibility of an outburst risk in coal seams caused by coal oxidation under different oxygen concentrations was evaluated by utilizing multiple indices to predict the outburst risk of coal and gas. By applying the BEL-MAX automatic analyzer for specific surface area (SSA), the change laws of the Brunauer–Emmett–Teller (BET) SSA and pore volume during coal oxidation were analyzed. Moreover, the change in multiple physical parameters during coal oxidation was measured by employing an industrial measurement instrument, gas chromatograph, initial velocity (△P) tester, and hardness tester. The results indicate that with the increasing oxidizing temperature of coal, the contents of moisture and volatiles in the coal declined constantly while the BET SSA and pore volume increased, thus strengthening the capability of coal mass for adsorbing gas. Moreover, the coal strength reduced with the constant development of pores, as shown by the Protodyakonov’s coefficient (f value) of coal mass that decreased constantly and △P of gas diffusion for reflecting the diffusion capability of coal for the gas to increase gradually with increasing oxidizing temperature. With the increasing oxygen concentration in an oxidizing atmosphere, the required oxidizing temperature at which the comprehensive index reflecting the outburst risk of coal mass was larger than the critical value reduced gradually. Thus, the coupling effect of magmatic rock invasion into coal mass, thermal metamorphism, and oxidation reaction led to the increase in gas content and SSA of coal mass, thus improving the capability of coal for adsorbing and storing gas. Correspondingly, the mechanical strength of coal mass reduced and the initial velocity of gas diffusion from coal mass increased significantly. Additionally, owing to the sealing effect of magmatic rock inhibiting the migration of gas in coal mass in the area, the risk level of coal and gas dynamic disasters in the area increased significantly.</abstract><cop>Rugby</cop><pub>Elsevier B.V</pub><doi>10.1016/j.psep.2019.02.017</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-2275-544X</orcidid></addata></record>
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subjects BET specific surface area
Coal
Coal gas outbursts
Coal moisture
Coal strength
Diffusion
Disasters
Gas chromatography
Gaseous diffusion
Low temperature oxidation
Mechanical properties
Metamorphism
Metamorphism (geology)
Migration
Outburst prediction index
Oxidation
Oxygen
Physical properties
Risk
Rocks
Temperature effects
Temperature requirements
Velocity
Volatile compounds
Volatiles
title Experimental study on the influence of coal oxidation on coal and gas outburst during invasion of magmatic rocks into coal seams
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