Improvement of carbon nanotube dispersion in electrospun polyacrylonitrile fiber through plasma surface modification
ABSTRACT In this study, surfaces of multiwalled carbon nanotubes (CNTs) were functionalized with poly(hexafluorobutyl acrylate) (PHFBA) thin film using a rotating‐bed plasma‐enhanced chemical vapor deposition (PECVD) method without imparting any defects on their surfaces. Polyacrylonitrile (PAN) ele...
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| Veröffentlicht in: | Journal of applied polymer science 2019-08, Vol.136 (31), p.n/a |
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| creator | Gürsoy, Mehmet Özcan, Fatih Karaman, Mustafa |
| description | ABSTRACT
In this study, surfaces of multiwalled carbon nanotubes (CNTs) were functionalized with poly(hexafluorobutyl acrylate) (PHFBA) thin film using a rotating‐bed plasma‐enhanced chemical vapor deposition (PECVD) method without imparting any defects on their surfaces. Polyacrylonitrile (PAN) electrospun polymer fiber mats and composite fiber mats with CNTs and functionalized CNTs (f‐CNTs) were prepared. The wettability and chemical and morphological properties of the synthesized fiber mats were investigated, and the dispersion of CNTs and f‐CNTs in the polymer matrix was compared according to the contact angle results of electrospun polymer mats. According to the chemical and morphological characterization results, PHFBA‐coated CNTs were dispersed more uniformly in the polymer matrix than the uncoated CNTs. The f‐CNTs/PAN composite fiber mat exhibits a lower surface energy than the pristine CNTs/PAN fiber mat. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47768. |
| doi_str_mv | 10.1002/app.47768 |
| format | Article |
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In this study, surfaces of multiwalled carbon nanotubes (CNTs) were functionalized with poly(hexafluorobutyl acrylate) (PHFBA) thin film using a rotating‐bed plasma‐enhanced chemical vapor deposition (PECVD) method without imparting any defects on their surfaces. Polyacrylonitrile (PAN) electrospun polymer fiber mats and composite fiber mats with CNTs and functionalized CNTs (f‐CNTs) were prepared. The wettability and chemical and morphological properties of the synthesized fiber mats were investigated, and the dispersion of CNTs and f‐CNTs in the polymer matrix was compared according to the contact angle results of electrospun polymer mats. According to the chemical and morphological characterization results, PHFBA‐coated CNTs were dispersed more uniformly in the polymer matrix than the uncoated CNTs. The f‐CNTs/PAN composite fiber mat exhibits a lower surface energy than the pristine CNTs/PAN fiber mat. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47768.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.47768</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Chemical synthesis ; Chemical vapor deposition ; composites ; Contact angle ; Dispersion ; Electrons ; Electrospinning ; Materials science ; Mats ; Morphology ; Multi wall carbon nanotubes ; nanotubes, graphene, and fullerenes ; Organic chemistry ; Polyacrylonitrile ; Polymers ; Rotating plasmas ; Surface energy ; Thin films ; Wettability</subject><ispartof>Journal of applied polymer science, 2019-08, Vol.136 (31), p.n/a</ispartof><rights>2019 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3348-42ba95bb9e4aa78e68ba06309216e291c7ba53dabedb4b0b5281a16419ddb3033</citedby><cites>FETCH-LOGICAL-c3348-42ba95bb9e4aa78e68ba06309216e291c7ba53dabedb4b0b5281a16419ddb3033</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.47768$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.47768$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids></links><search><creatorcontrib>Gürsoy, Mehmet</creatorcontrib><creatorcontrib>Özcan, Fatih</creatorcontrib><creatorcontrib>Karaman, Mustafa</creatorcontrib><title>Improvement of carbon nanotube dispersion in electrospun polyacrylonitrile fiber through plasma surface modification</title><title>Journal of applied polymer science</title><description>ABSTRACT
In this study, surfaces of multiwalled carbon nanotubes (CNTs) were functionalized with poly(hexafluorobutyl acrylate) (PHFBA) thin film using a rotating‐bed plasma‐enhanced chemical vapor deposition (PECVD) method without imparting any defects on their surfaces. Polyacrylonitrile (PAN) electrospun polymer fiber mats and composite fiber mats with CNTs and functionalized CNTs (f‐CNTs) were prepared. The wettability and chemical and morphological properties of the synthesized fiber mats were investigated, and the dispersion of CNTs and f‐CNTs in the polymer matrix was compared according to the contact angle results of electrospun polymer mats. According to the chemical and morphological characterization results, PHFBA‐coated CNTs were dispersed more uniformly in the polymer matrix than the uncoated CNTs. The f‐CNTs/PAN composite fiber mat exhibits a lower surface energy than the pristine CNTs/PAN fiber mat. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47768.</description><subject>Chemical synthesis</subject><subject>Chemical vapor deposition</subject><subject>composites</subject><subject>Contact angle</subject><subject>Dispersion</subject><subject>Electrons</subject><subject>Electrospinning</subject><subject>Materials science</subject><subject>Mats</subject><subject>Morphology</subject><subject>Multi wall carbon nanotubes</subject><subject>nanotubes, graphene, and fullerenes</subject><subject>Organic chemistry</subject><subject>Polyacrylonitrile</subject><subject>Polymers</subject><subject>Rotating plasmas</subject><subject>Surface energy</subject><subject>Thin films</subject><subject>Wettability</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kM1OwzAQhC0EEqVw4A0sceKQ1nYSJzlWFT-VKtEDnK2141BXSRxsB5S3xxCunFba_WZWMwjdUrKihLA1DMMqKwpenqEFJVWRZJyV52gRbzQpqyq_RFfenwihNCd8gcKuG5z91J3uA7YNVuCk7XEPvQ2j1Lg2ftDOm7gzPdatVsFZP4w9Hmw7gXJTa3sTnGk1bozUDoejs-P7EQ8t-A6wH10DSuPO1qYxCkK0ukYXDbRe3_zNJXp7fHjdPif7l6fddrNPVJpmZZIxCVUuZaUzgKLUvJRAeEoqRrlmFVWFhDytQepaZpLInJUUKM9oVdcyJWm6RHezb4z4MWofxMmOro8vBWO0ZDnn0W-J7mdKxWTe6UYMznTgJkGJ-ClVxFLFb6mRXc_sVww8_Q-KzeEwK74B2tl8Iw</recordid><startdate>20190815</startdate><enddate>20190815</enddate><creator>Gürsoy, Mehmet</creator><creator>Özcan, Fatih</creator><creator>Karaman, Mustafa</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20190815</creationdate><title>Improvement of carbon nanotube dispersion in electrospun polyacrylonitrile fiber through plasma surface modification</title><author>Gürsoy, Mehmet ; Özcan, Fatih ; Karaman, Mustafa</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3348-42ba95bb9e4aa78e68ba06309216e291c7ba53dabedb4b0b5281a16419ddb3033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Chemical synthesis</topic><topic>Chemical vapor deposition</topic><topic>composites</topic><topic>Contact angle</topic><topic>Dispersion</topic><topic>Electrons</topic><topic>Electrospinning</topic><topic>Materials science</topic><topic>Mats</topic><topic>Morphology</topic><topic>Multi wall carbon nanotubes</topic><topic>nanotubes, graphene, and fullerenes</topic><topic>Organic chemistry</topic><topic>Polyacrylonitrile</topic><topic>Polymers</topic><topic>Rotating plasmas</topic><topic>Surface energy</topic><topic>Thin films</topic><topic>Wettability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gürsoy, Mehmet</creatorcontrib><creatorcontrib>Özcan, Fatih</creatorcontrib><creatorcontrib>Karaman, Mustafa</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gürsoy, Mehmet</au><au>Özcan, Fatih</au><au>Karaman, Mustafa</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improvement of carbon nanotube dispersion in electrospun polyacrylonitrile fiber through plasma surface modification</atitle><jtitle>Journal of applied polymer science</jtitle><date>2019-08-15</date><risdate>2019</risdate><volume>136</volume><issue>31</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>ABSTRACT
In this study, surfaces of multiwalled carbon nanotubes (CNTs) were functionalized with poly(hexafluorobutyl acrylate) (PHFBA) thin film using a rotating‐bed plasma‐enhanced chemical vapor deposition (PECVD) method without imparting any defects on their surfaces. Polyacrylonitrile (PAN) electrospun polymer fiber mats and composite fiber mats with CNTs and functionalized CNTs (f‐CNTs) were prepared. The wettability and chemical and morphological properties of the synthesized fiber mats were investigated, and the dispersion of CNTs and f‐CNTs in the polymer matrix was compared according to the contact angle results of electrospun polymer mats. According to the chemical and morphological characterization results, PHFBA‐coated CNTs were dispersed more uniformly in the polymer matrix than the uncoated CNTs. The f‐CNTs/PAN composite fiber mat exhibits a lower surface energy than the pristine CNTs/PAN fiber mat. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47768.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.47768</doi><tpages>6</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Chemical synthesis Chemical vapor deposition composites Contact angle Dispersion Electrons Electrospinning Materials science Mats Morphology Multi wall carbon nanotubes nanotubes, graphene, and fullerenes Organic chemistry Polyacrylonitrile Polymers Rotating plasmas Surface energy Thin films Wettability |
| title | Improvement of carbon nanotube dispersion in electrospun polyacrylonitrile fiber through plasma surface modification |
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