The chemical and electrochemical reduction of heteroligand o-semiquinonato-formazanato cobalt complexes

[Display omitted] •Reduction of heteroligand o-semiquinonato-formazanato cobalt complexes.•1D linear D-A-D-A motif in crystal of [Co(3,6-Cat)(Form)]−[Cp2Co]+ complex.•[Co(3,6-Cat)(Form)]−[Cp2Co]+ has a doublet ground state (S = 1/2).•[Co(3,6-Cat)(3,6-SQ)(Form)]−[Cp2Co]+ (S = 1/2) has a redox isomer...

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Veröffentlicht in:	Inorganica Chimica Acta 2019-04, Vol.489, p.1-7
Hauptverfasser:	Protasenko, Natalia A., Poddel'sky, Andrey I., Bogomyakov, Artem S., Starikov, Andrey G., Smolyaninov, Ivan V., Berberova, Nadezhda T., Fukin, Georgy K., Cherkasov, Vladimir K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Catecholate Chemical reduction Cobalt Cobalt compounds Crystal structure Formazanate ligand Ligands Magnetic permeability Magnetochemistry Molecular structure Organic chemistry Single crystals X ray analysis
Online-Zugang:	Volltext
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