Synthesis of (Ti0.5V0.5)3C2 as Novel Electrocatalyst to Modify Carbon Paste Electrode for Measurement of Propranolol in Real Samples
(Ti 0.5 V 0.5 ) 3 AlC 2 is prepared via ball-milling Ti, V, Al, and C precursor powders with mole ratio of 1.5 : 1.5 :1.1 : 1.9 followed by sintering the obtained fine powder at 1400°C for 20 min under argon atmosphere. The morphology and structure of products are characterized by using XRD and SEM...
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| Veröffentlicht in: | Russian journal of electrochemistry 2019, Vol.55 (1), p.52-59 |
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| container_title | Russian journal of electrochemistry |
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| creator | Nateghi, M. R. |
| description | (Ti
0.5
V
0.5
)
3
AlC
2
is prepared via ball-milling Ti, V, Al, and C precursor powders with mole ratio of 1.5 : 1.5 :1.1 : 1.9 followed by sintering the obtained fine powder at 1400°C for 20 min under argon atmosphere. The morphology and structure of products are characterized by using XRD and SEM techniques. Then Al is chemically etched from synthesized (Ti
0.5
V
0.5
)
3
AlC
2
by immersing in 40% HF solution at room temperature for 20 h. The resulting suspension is centrifuged to separate the powder and washed severely with distilled water. Resulting (Ti
0.5
V
0.5
)
3
C
2
is used as a new modifier for preparation of carbon paste electrode. Modified electrode based on (Ti
0.5
V
0.5
)
3
C
2
shows a good performance for measurement of propranolol concentration in pharmaceutical formulation. The detection limit and the relative standard deviation for
n
= 5 are 0.16 μmol/L and 4%, respectively. |
| doi_str_mv | 10.1134/S1023193519010087 |
| format | Article |
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0.5
V
0.5
)
3
AlC
2
is prepared via ball-milling Ti, V, Al, and C precursor powders with mole ratio of 1.5 : 1.5 :1.1 : 1.9 followed by sintering the obtained fine powder at 1400°C for 20 min under argon atmosphere. The morphology and structure of products are characterized by using XRD and SEM techniques. Then Al is chemically etched from synthesized (Ti
0.5
V
0.5
)
3
AlC
2
by immersing in 40% HF solution at room temperature for 20 h. The resulting suspension is centrifuged to separate the powder and washed severely with distilled water. Resulting (Ti
0.5
V
0.5
)
3
C
2
is used as a new modifier for preparation of carbon paste electrode. Modified electrode based on (Ti
0.5
V
0.5
)
3
C
2
shows a good performance for measurement of propranolol concentration in pharmaceutical formulation. The detection limit and the relative standard deviation for
n
= 5 are 0.16 μmol/L and 4%, respectively.</description><identifier>ISSN: 1023-1935</identifier><identifier>EISSN: 1608-3342</identifier><identifier>DOI: 10.1134/S1023193519010087</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Argon ; Ball milling ; Carbon ; Chemistry ; Chemistry and Materials Science ; Distilled water ; Electrochemistry ; Electrodes ; Morphology ; Organic chemistry ; Physical Chemistry ; Sintering (powder metallurgy)</subject><ispartof>Russian journal of electrochemistry, 2019, Vol.55 (1), p.52-59</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2317-d9799d0932a9a95adc54a233ec466206009af8e1348c30cfd86eb10c22c02b8f3</citedby><cites>FETCH-LOGICAL-c2317-d9799d0932a9a95adc54a233ec466206009af8e1348c30cfd86eb10c22c02b8f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1023193519010087$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1023193519010087$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Nateghi, M. R.</creatorcontrib><title>Synthesis of (Ti0.5V0.5)3C2 as Novel Electrocatalyst to Modify Carbon Paste Electrode for Measurement of Propranolol in Real Samples</title><title>Russian journal of electrochemistry</title><addtitle>Russ J Electrochem</addtitle><description>(Ti
0.5
V
0.5
)
3
AlC
2
is prepared via ball-milling Ti, V, Al, and C precursor powders with mole ratio of 1.5 : 1.5 :1.1 : 1.9 followed by sintering the obtained fine powder at 1400°C for 20 min under argon atmosphere. The morphology and structure of products are characterized by using XRD and SEM techniques. Then Al is chemically etched from synthesized (Ti
0.5
V
0.5
)
3
AlC
2
by immersing in 40% HF solution at room temperature for 20 h. The resulting suspension is centrifuged to separate the powder and washed severely with distilled water. Resulting (Ti
0.5
V
0.5
)
3
C
2
is used as a new modifier for preparation of carbon paste electrode. Modified electrode based on (Ti
0.5
V
0.5
)
3
C
2
shows a good performance for measurement of propranolol concentration in pharmaceutical formulation. The detection limit and the relative standard deviation for
n
= 5 are 0.16 μmol/L and 4%, respectively.</description><subject>Argon</subject><subject>Ball milling</subject><subject>Carbon</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Distilled water</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Morphology</subject><subject>Organic chemistry</subject><subject>Physical Chemistry</subject><subject>Sintering (powder metallurgy)</subject><issn>1023-1935</issn><issn>1608-3342</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LAzEQhoMoWKs_wFvAix625mN3uzlK8QtaLbZ6XdLsRLekmzVJhb37w81SxYN4GGZgnvcd5kXolJIRpTy9XFDCOBU8o4JQQorxHhrQnBQJ5ynbj3NcJ_3-EB15vyY9QsUAfS66JryBrz22Gp8vazLKXmJd8AnD0uMH-wEGXxtQwVklgzSdDzhYPLNVrTs8kW5lGzyXPsAPVgHW1uEZSL91sIEm9N5zZ1snG2uswXWDn0AavJCb1oA_RgdaGg8n332Inm-ul5O7ZPp4ez-5miYq_jZOKjEWoiKCMymkyGSlslQyzkGlec5IToiQuoAYR6E4UboqclhRohhThK0KzYfobOfbOvu-BR_Ktd26Jp4sGaNZtEhzHim6o5Sz3jvQZevqjXRdSUnZh13-CTtq2E7jI9u8gvt1_l_0Be39fz4</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Nateghi, M. R.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2019</creationdate><title>Synthesis of (Ti0.5V0.5)3C2 as Novel Electrocatalyst to Modify Carbon Paste Electrode for Measurement of Propranolol in Real Samples</title><author>Nateghi, M. R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2317-d9799d0932a9a95adc54a233ec466206009af8e1348c30cfd86eb10c22c02b8f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Argon</topic><topic>Ball milling</topic><topic>Carbon</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Distilled water</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Morphology</topic><topic>Organic chemistry</topic><topic>Physical Chemistry</topic><topic>Sintering (powder metallurgy)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nateghi, M. R.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nateghi, M. R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of (Ti0.5V0.5)3C2 as Novel Electrocatalyst to Modify Carbon Paste Electrode for Measurement of Propranolol in Real Samples</atitle><jtitle>Russian journal of electrochemistry</jtitle><stitle>Russ J Electrochem</stitle><date>2019</date><risdate>2019</risdate><volume>55</volume><issue>1</issue><spage>52</spage><epage>59</epage><pages>52-59</pages><issn>1023-1935</issn><eissn>1608-3342</eissn><abstract>(Ti
0.5
V
0.5
)
3
AlC
2
is prepared via ball-milling Ti, V, Al, and C precursor powders with mole ratio of 1.5 : 1.5 :1.1 : 1.9 followed by sintering the obtained fine powder at 1400°C for 20 min under argon atmosphere. The morphology and structure of products are characterized by using XRD and SEM techniques. Then Al is chemically etched from synthesized (Ti
0.5
V
0.5
)
3
AlC
2
by immersing in 40% HF solution at room temperature for 20 h. The resulting suspension is centrifuged to separate the powder and washed severely with distilled water. Resulting (Ti
0.5
V
0.5
)
3
C
2
is used as a new modifier for preparation of carbon paste electrode. Modified electrode based on (Ti
0.5
V
0.5
)
3
C
2
shows a good performance for measurement of propranolol concentration in pharmaceutical formulation. The detection limit and the relative standard deviation for
n
= 5 are 0.16 μmol/L and 4%, respectively.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1023193519010087</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1023-1935 |
| ispartof | Russian journal of electrochemistry, 2019, Vol.55 (1), p.52-59 |
| issn | 1023-1935 1608-3342 |
| language | eng |
| recordid | cdi_proquest_journals_2215206463 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Argon Ball milling Carbon Chemistry Chemistry and Materials Science Distilled water Electrochemistry Electrodes Morphology Organic chemistry Physical Chemistry Sintering (powder metallurgy) |
| title | Synthesis of (Ti0.5V0.5)3C2 as Novel Electrocatalyst to Modify Carbon Paste Electrode for Measurement of Propranolol in Real Samples |
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