CuCl2-Mediated Hydroxylation of 2,3-Dimethyl-5-hydroxy-6-aminopyrimidine-4(3H)-one with Molecular Oxygen in Aqueous and Non-Aqueous Solutions

The catalytic hydroxylation of 2,3-dimethyl-5-hydroxy-6-aminopyrimidine-4(3 H )-one in an aqueous solution in the presence of copper(II) ions and oxygen proceeds with the formation of 2,3-dimethyl-5,5,6-trihydroxy-6-aminopyrimidine-4-(3 H )-one.

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Veröffentlicht in:Russian journal of general chemistry 2019-03, Vol.89 (3), p.405-408
Hauptverfasser: Mishinkin, V. Yu, Grabovskii, S. A., Kabal’nova, N. N., Murinov, Yu. I.
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Sprache:eng
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Zusammenfassung:The catalytic hydroxylation of 2,3-dimethyl-5-hydroxy-6-aminopyrimidine-4(3 H )-one in an aqueous solution in the presence of copper(II) ions and oxygen proceeds with the formation of 2,3-dimethyl-5,5,6-trihydroxy-6-aminopyrimidine-4-(3 H )-one.
ISSN:1070-3632
1608-3350
DOI:10.1134/S107036321903006X