Development of Electroorganic Reactions Utilizing Stabilized Reactive Species and Its Application to Organic Energy Storage Materials
Reactive species generated by the oxidation and reduction of organic compounds are generally unstable. To utilize the reactive species as intermediates for organic synthesis and functional materials, it is crucial how to treat them. In this headline, electrochemical reactions utilizing stabilized re...
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| Veröffentlicht in: | Denki kagaku oyobi kōgyō butsuri kagaku 2018/11/05, Vol.86(6), pp.298-302 |
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| container_title | Denki kagaku oyobi kōgyō butsuri kagaku |
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| creator | SHIMIZU, Akihiro |
| description | Reactive species generated by the oxidation and reduction of organic compounds are generally unstable. To utilize the reactive species as intermediates for organic synthesis and functional materials, it is crucial how to treat them. In this headline, electrochemical reactions utilizing stabilized reactive cations, which enabled benzylic C–H/aromatic C–H cross-coupling, aromatic C–H/C–H cross-coupling, and aromatic C–H amination are demonstrated. Furthermore, energy storage materials utilizing stabilized anions, which enabled to develop organic materials for lithium-ion batteries with high voltage of ca. 3 V and solvent-free redox flow batteries with high energy density, are demonstrated. These studies show the usefulness of stabilized reactive species. |
| doi_str_mv | 10.5796/electrochemistry.18-6-E2671 |
| format | Article |
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| ispartof | Electrochemistry, 2018/11/05, Vol.86(6), pp.298-302 |
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| subjects | Amination Anions Batteries Cations Chemical reactions Cross coupling Electrochemical Oxidation Electrochemistry Energy storage Flux density Functional materials High voltage High voltages Intermediates Lithium Lithium-ion batteries Organic Batteries Organic compounds Organic Electrochemistry Organic Electron Transfer Organic materials Oxidation Rechargeable batteries Species |
| title | Development of Electroorganic Reactions Utilizing Stabilized Reactive Species and Its Application to Organic Energy Storage Materials |
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