Redefinition of theresemagnanite, NaCo4(SO4)(OH)6Cl·6H2O; new data and relationship to 'cobaltogordaite'
Theresemagnanite was originally described from the Cap Garonne mine, Var, France. Its ideal formula was reported as (Co,Zn,Ni)6(SO4)(OH,Cl)10·8H2O; without crystal structure data, only the powder X-ray diffraction pattern was given. Revision of the holotype material revealed that theresemagnanite is...
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| Veröffentlicht in: | Mineralogical magazine 2018-02, Vol.82 (1), p.159-170 |
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| creator | Kasatkin, Anatoly V Plasil, Jakub Skoda, Radek Belakovskiy, Dmitriy I Marty, Joe Meisser, Nicolas Pekov, Igor V |
| description | Theresemagnanite was originally described from the Cap Garonne mine, Var, France. Its ideal formula was reported as (Co,Zn,Ni)6(SO4)(OH,Cl)10·8H2O; without crystal structure data, only the powder X-ray diffraction pattern was given. Revision of the holotype material revealed that theresemagnanite is identical to 'cobaltogordaite' (IMA2014-043), recently described from the Blue Lizard mine, Utah, USA. Theresemagnanite is thus redefined in accordance with the new data obtained for the neotype specimen from Blue Lizard (formerly the holotype specimen of 'cobaltogordaite') and 'cobaltogordaite' has been discredited by the International Mineralogical Association Commission on New Mineral Nomenclature and Classification (IMA CNMNC). Theresemagnanite has the ideal, end-member formula NaCo4(SO4)(OH)6Cl·6H2O. The empirical formulae of the holotype (Cap Garonne) and the neotype (Blue Lizard), both based on microprobe analyses and calculated on the basis of 17 O + Cl atoms per formula unit (with fixed 6 OH groups and 6 H2O molecules; H content is calculated by stoichiometry) are (Na0.64K0.09)Σ0.73(Co2.35Zn1.22Ni0.50)Σ4.07S1.02O3. 98(OH)6 Cl1.02·6H2O and Na1.01(Co1.90Zn1.37Ni0.48Cu0.15Mn0.05)Σ3.95S1.03O4.09 (OH)6Cl 0.91·6H2O, respectively. Theresemagnanite is trigonal, P3 $, a = 8.349(3), c = 13.031(2) Å, V = 786.6(4) Å3 and Z = 2 (neotype). The strongest powder X-ray diffraction lines are [dobs in Å (hkl) (Irel)]: 13.10 (001)(100), 6.53 (002)(8), 4.173 (110)(4), 3.517 (112)(5), 2.975 (104, 104)(4), 2.676 (211)(5) and 2.520 (122)(5) (neotype). Theresemagnanite is a cobalt analogue of gordaite, NaZn4(SO4)(OH)6Cl·6H2O. These minerals represent the gordaite group, accepted by the IMA CNMNC. |
| doi_str_mv | 10.1180/minmag.2017.081.030 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_geosc</sourceid><recordid>TN_cdi_proquest_journals_2210934486</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2210934486</sourcerecordid><originalsourceid>FETCH-LOGICAL-g134t-37422a3fdf3ccaa53658c71c1b2b4d859bfa3f6454a121c68188e5077feafccf3</originalsourceid><addsrcrecordid>eNpNjctKw0AYhQdRsFafwM2Ai7Zo4vxzyxRXEtQKxYAXcFcmk5k0JZ1pk5Q-mnufzEhduDpwzsd3ELoEEgMocruu_FqXMSWQxERBTBg5QgPgCUSKUHqMBoRQGXEJn6forG1XhAAHQQeoerWFdZWvuip4HBzulraxre11XvetvcEvOg18_JbxyTibTWRaf3_JGc3usLd7XOhOY-0L3Nha_zraZbXBXcAjE3Jdd6EMTaF7z-gcnThdt_biL4fo4_HhPZ1F8-zpOb2fRyUw3kUs4ZRq5grHjNFaMCmUScBATnNeKDHNXb9KLrgGCkYqUMoKkiTOameMY0N0dfBumrDd2bZbrMKu8f3lglIgU8a5kj11faBKG1pTWW_sPjR18Q8moBZEcOCC_QDsNWmy</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2210934486</pqid></control><display><type>article</type><title>Redefinition of theresemagnanite, NaCo4(SO4)(OH)6Cl·6H2O; new data and relationship to 'cobaltogordaite'</title><source>Cambridge University Press Journals</source><creator>Kasatkin, Anatoly V ; Plasil, Jakub ; Skoda, Radek ; Belakovskiy, Dmitriy I ; Marty, Joe ; Meisser, Nicolas ; Pekov, Igor V</creator><creatorcontrib>Kasatkin, Anatoly V ; Plasil, Jakub ; Skoda, Radek ; Belakovskiy, Dmitriy I ; Marty, Joe ; Meisser, Nicolas ; Pekov, Igor V</creatorcontrib><description>Theresemagnanite was originally described from the Cap Garonne mine, Var, France. Its ideal formula was reported as (Co,Zn,Ni)6(SO4)(OH,Cl)10·8H2O; without crystal structure data, only the powder X-ray diffraction pattern was given. Revision of the holotype material revealed that theresemagnanite is identical to 'cobaltogordaite' (IMA2014-043), recently described from the Blue Lizard mine, Utah, USA. Theresemagnanite is thus redefined in accordance with the new data obtained for the neotype specimen from Blue Lizard (formerly the holotype specimen of 'cobaltogordaite') and 'cobaltogordaite' has been discredited by the International Mineralogical Association Commission on New Mineral Nomenclature and Classification (IMA CNMNC). Theresemagnanite has the ideal, end-member formula NaCo4(SO4)(OH)6Cl·6H2O. The empirical formulae of the holotype (Cap Garonne) and the neotype (Blue Lizard), both based on microprobe analyses and calculated on the basis of 17 O + Cl atoms per formula unit (with fixed 6 OH groups and 6 H2O molecules; H content is calculated by stoichiometry) are (Na0.64K0.09)Σ0.73(Co2.35Zn1.22Ni0.50)Σ4.07S1.02O3. 98(OH)6 Cl1.02·6H2O and Na1.01(Co1.90Zn1.37Ni0.48Cu0.15Mn0.05)Σ3.95S1.03O4.09 (OH)6Cl 0.91·6H2O, respectively. Theresemagnanite is trigonal, P3 $, a = 8.349(3), c = 13.031(2) Å, V = 786.6(4) Å3 and Z = 2 (neotype). The strongest powder X-ray diffraction lines are [dobs in Å (hkl) (Irel)]: 13.10 (001)(100), 6.53 (002)(8), 4.173 (110)(4), 3.517 (112)(5), 2.975 (104, 104)(4), 2.676 (211)(5) and 2.520 (122)(5) (neotype). Theresemagnanite is a cobalt analogue of gordaite, NaZn4(SO4)(OH)6Cl·6H2O. These minerals represent the gordaite group, accepted by the IMA CNMNC.</description><identifier>ISSN: 0026-461X</identifier><identifier>EISSN: 1471-8022</identifier><identifier>DOI: 10.1180/minmag.2017.081.030</identifier><language>eng</language><publisher>London: Mineralogical Society</publisher><subject>Alpes-Maritimes France ; Blue Lizard Mine ; Cap Garonne Mine ; chemical composition ; Cobalt ; cobalt sulfate ; cobaltogordaite ; copper ores ; crystal structure ; Crystals ; diffractograms ; electron microscopy data ; electron probe data ; Europe ; formula ; France ; gordaite ; metal ores ; Mineralogy ; Museums ; new data ; nomenclature ; nonsilicates ; oxidation zone ; Raman spectra ; SEM data ; spectra ; stoichiometry ; sulfates ; theresemagnatite ; United States ; Utah ; Var France ; Western Europe ; X-ray diffraction ; X-ray diffraction data</subject><ispartof>Mineralogical magazine, 2018-02, Vol.82 (1), p.159-170</ispartof><rights>GeoRef, Copyright 2020, American Geosciences Institute. Reference includes data from GeoScienceWorld @Alexandria, VA @USA @United States. Abstract, Copyright, Mineralogical Society of Great Britain and Ireland</rights><rights>Copyright © Mineralogical Society of Great Britain and Ireland 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kasatkin, Anatoly V</creatorcontrib><creatorcontrib>Plasil, Jakub</creatorcontrib><creatorcontrib>Skoda, Radek</creatorcontrib><creatorcontrib>Belakovskiy, Dmitriy I</creatorcontrib><creatorcontrib>Marty, Joe</creatorcontrib><creatorcontrib>Meisser, Nicolas</creatorcontrib><creatorcontrib>Pekov, Igor V</creatorcontrib><title>Redefinition of theresemagnanite, NaCo4(SO4)(OH)6Cl·6H2O; new data and relationship to 'cobaltogordaite'</title><title>Mineralogical magazine</title><description>Theresemagnanite was originally described from the Cap Garonne mine, Var, France. Its ideal formula was reported as (Co,Zn,Ni)6(SO4)(OH,Cl)10·8H2O; without crystal structure data, only the powder X-ray diffraction pattern was given. Revision of the holotype material revealed that theresemagnanite is identical to 'cobaltogordaite' (IMA2014-043), recently described from the Blue Lizard mine, Utah, USA. Theresemagnanite is thus redefined in accordance with the new data obtained for the neotype specimen from Blue Lizard (formerly the holotype specimen of 'cobaltogordaite') and 'cobaltogordaite' has been discredited by the International Mineralogical Association Commission on New Mineral Nomenclature and Classification (IMA CNMNC). Theresemagnanite has the ideal, end-member formula NaCo4(SO4)(OH)6Cl·6H2O. The empirical formulae of the holotype (Cap Garonne) and the neotype (Blue Lizard), both based on microprobe analyses and calculated on the basis of 17 O + Cl atoms per formula unit (with fixed 6 OH groups and 6 H2O molecules; H content is calculated by stoichiometry) are (Na0.64K0.09)Σ0.73(Co2.35Zn1.22Ni0.50)Σ4.07S1.02O3. 98(OH)6 Cl1.02·6H2O and Na1.01(Co1.90Zn1.37Ni0.48Cu0.15Mn0.05)Σ3.95S1.03O4.09 (OH)6Cl 0.91·6H2O, respectively. Theresemagnanite is trigonal, P3 $, a = 8.349(3), c = 13.031(2) Å, V = 786.6(4) Å3 and Z = 2 (neotype). The strongest powder X-ray diffraction lines are [dobs in Å (hkl) (Irel)]: 13.10 (001)(100), 6.53 (002)(8), 4.173 (110)(4), 3.517 (112)(5), 2.975 (104, 104)(4), 2.676 (211)(5) and 2.520 (122)(5) (neotype). Theresemagnanite is a cobalt analogue of gordaite, NaZn4(SO4)(OH)6Cl·6H2O. These minerals represent the gordaite group, accepted by the IMA CNMNC.</description><subject>Alpes-Maritimes France</subject><subject>Blue Lizard Mine</subject><subject>Cap Garonne Mine</subject><subject>chemical composition</subject><subject>Cobalt</subject><subject>cobalt sulfate</subject><subject>cobaltogordaite</subject><subject>copper ores</subject><subject>crystal structure</subject><subject>Crystals</subject><subject>diffractograms</subject><subject>electron microscopy data</subject><subject>electron probe data</subject><subject>Europe</subject><subject>formula</subject><subject>France</subject><subject>gordaite</subject><subject>metal ores</subject><subject>Mineralogy</subject><subject>Museums</subject><subject>new data</subject><subject>nomenclature</subject><subject>nonsilicates</subject><subject>oxidation zone</subject><subject>Raman spectra</subject><subject>SEM data</subject><subject>spectra</subject><subject>stoichiometry</subject><subject>sulfates</subject><subject>theresemagnatite</subject><subject>United States</subject><subject>Utah</subject><subject>Var France</subject><subject>Western Europe</subject><subject>X-ray diffraction</subject><subject>X-ray diffraction data</subject><issn>0026-461X</issn><issn>1471-8022</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNpNjctKw0AYhQdRsFafwM2Ai7Zo4vxzyxRXEtQKxYAXcFcmk5k0JZ1pk5Q-mnufzEhduDpwzsd3ELoEEgMocruu_FqXMSWQxERBTBg5QgPgCUSKUHqMBoRQGXEJn6forG1XhAAHQQeoerWFdZWvuip4HBzulraxre11XvetvcEvOg18_JbxyTibTWRaf3_JGc3usLd7XOhOY-0L3Nha_zraZbXBXcAjE3Jdd6EMTaF7z-gcnThdt_biL4fo4_HhPZ1F8-zpOb2fRyUw3kUs4ZRq5grHjNFaMCmUScBATnNeKDHNXb9KLrgGCkYqUMoKkiTOameMY0N0dfBumrDd2bZbrMKu8f3lglIgU8a5kj11faBKG1pTWW_sPjR18Q8moBZEcOCC_QDsNWmy</recordid><startdate>201802</startdate><enddate>201802</enddate><creator>Kasatkin, Anatoly V</creator><creator>Plasil, Jakub</creator><creator>Skoda, Radek</creator><creator>Belakovskiy, Dmitriy I</creator><creator>Marty, Joe</creator><creator>Meisser, Nicolas</creator><creator>Pekov, Igor V</creator><general>Mineralogical Society</general><general>Cambridge University Press</general><scope>3V.</scope><scope>7RQ</scope><scope>7XB</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>M2O</scope><scope>MBDVC</scope><scope>PCBAR</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>U9A</scope></search><sort><creationdate>201802</creationdate><title>Redefinition of theresemagnanite, NaCo4(SO4)(OH)6Cl·6H2O; 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new data and relationship to 'cobaltogordaite'</atitle><jtitle>Mineralogical magazine</jtitle><date>2018-02</date><risdate>2018</risdate><volume>82</volume><issue>1</issue><spage>159</spage><epage>170</epage><pages>159-170</pages><issn>0026-461X</issn><eissn>1471-8022</eissn><abstract>Theresemagnanite was originally described from the Cap Garonne mine, Var, France. Its ideal formula was reported as (Co,Zn,Ni)6(SO4)(OH,Cl)10·8H2O; without crystal structure data, only the powder X-ray diffraction pattern was given. Revision of the holotype material revealed that theresemagnanite is identical to 'cobaltogordaite' (IMA2014-043), recently described from the Blue Lizard mine, Utah, USA. Theresemagnanite is thus redefined in accordance with the new data obtained for the neotype specimen from Blue Lizard (formerly the holotype specimen of 'cobaltogordaite') and 'cobaltogordaite' has been discredited by the International Mineralogical Association Commission on New Mineral Nomenclature and Classification (IMA CNMNC). Theresemagnanite has the ideal, end-member formula NaCo4(SO4)(OH)6Cl·6H2O. The empirical formulae of the holotype (Cap Garonne) and the neotype (Blue Lizard), both based on microprobe analyses and calculated on the basis of 17 O + Cl atoms per formula unit (with fixed 6 OH groups and 6 H2O molecules; H content is calculated by stoichiometry) are (Na0.64K0.09)Σ0.73(Co2.35Zn1.22Ni0.50)Σ4.07S1.02O3. 98(OH)6 Cl1.02·6H2O and Na1.01(Co1.90Zn1.37Ni0.48Cu0.15Mn0.05)Σ3.95S1.03O4.09 (OH)6Cl 0.91·6H2O, respectively. Theresemagnanite is trigonal, P3 $, a = 8.349(3), c = 13.031(2) Å, V = 786.6(4) Å3 and Z = 2 (neotype). The strongest powder X-ray diffraction lines are [dobs in Å (hkl) (Irel)]: 13.10 (001)(100), 6.53 (002)(8), 4.173 (110)(4), 3.517 (112)(5), 2.975 (104, 104)(4), 2.676 (211)(5) and 2.520 (122)(5) (neotype). Theresemagnanite is a cobalt analogue of gordaite, NaZn4(SO4)(OH)6Cl·6H2O. These minerals represent the gordaite group, accepted by the IMA CNMNC.</abstract><cop>London</cop><pub>Mineralogical Society</pub><doi>10.1180/minmag.2017.081.030</doi><tpages>12</tpages></addata></record> |
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| subjects | Alpes-Maritimes France Blue Lizard Mine Cap Garonne Mine chemical composition Cobalt cobalt sulfate cobaltogordaite copper ores crystal structure Crystals diffractograms electron microscopy data electron probe data Europe formula France gordaite metal ores Mineralogy Museums new data nomenclature nonsilicates oxidation zone Raman spectra SEM data spectra stoichiometry sulfates theresemagnatite United States Utah Var France Western Europe X-ray diffraction X-ray diffraction data |
| title | Redefinition of theresemagnanite, NaCo4(SO4)(OH)6Cl·6H2O; new data and relationship to 'cobaltogordaite' |
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