Facile route for green synthesis of N-benzylideneaniline over bimetallic reduced graphene oxide: chemical reactivity of 2,3,4-substituted derivatives of aniline
Mn–Co-decorated reduced graphene oxide (Mn–Co–rGO) was prepared by modified condensation method and characterized through XRD, SEM, EDX, FTIR and BET surface area analysis. The prepared sample was explored for its activity in the synthesis of N -benzylideneaniline ( N -BA) using benzyl alcohol and P...
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| Veröffentlicht in: | Research on chemical intermediates 2019-05, Vol.45 (5), p.2947-2961 |
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| container_title | Research on chemical intermediates |
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| creator | Aman, Razia Sadiq, Saima Ali, Muhammad Sadiq, Muhammad Gul, Jehan Saeed, Khalid Khan, Adnan Ali Shah, Sagheer Hussain |
| description | Mn–Co-decorated reduced graphene oxide (Mn–Co–rGO) was prepared by modified condensation method and characterized through XRD, SEM, EDX, FTIR and BET surface area analysis. The prepared sample was explored for its activity in the synthesis of
N
-benzylideneaniline (
N
-BA) using benzyl alcohol and PhNH
2
as precursors. The catalyst has been used efficiently with high activity and selectivity for oxidation of benzyl alcohol to benzaldehyde in the presence of molecular oxygen, which further react with aniline to produced
N
-BA with sustainable catalytic activity up to five cycles. Furthermore, the effect of the nature and position of the substituent on aniline on the chemical reactivity of the nucleophile was studied theoretically using density functional calculations. |
| doi_str_mv | 10.1007/s11164-019-03772-w |
| format | Article |
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N
-benzylideneaniline (
N
-BA) using benzyl alcohol and PhNH
2
as precursors. The catalyst has been used efficiently with high activity and selectivity for oxidation of benzyl alcohol to benzaldehyde in the presence of molecular oxygen, which further react with aniline to produced
N
-BA with sustainable catalytic activity up to five cycles. Furthermore, the effect of the nature and position of the substituent on aniline on the chemical reactivity of the nucleophile was studied theoretically using density functional calculations.</description><identifier>ISSN: 0922-6168</identifier><identifier>EISSN: 1568-5675</identifier><identifier>DOI: 10.1007/s11164-019-03772-w</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Alcohol ; Aniline ; Benzaldehyde ; Benzyl alcohol ; Bimetals ; Catalysis ; Catalytic activity ; Chemistry ; Chemistry and Materials Science ; Graphene ; Inorganic Chemistry ; Organic chemistry ; Oxidation ; Oxygen ; Physical Chemistry ; Selectivity</subject><ispartof>Research on chemical intermediates, 2019-05, Vol.45 (5), p.2947-2961</ispartof><rights>Springer Nature B.V. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c400t-11effa5671a0d0a46ceab826c6a8275ebfecfdb5ea975a8971d0ef2aac653cb73</citedby><cites>FETCH-LOGICAL-c400t-11effa5671a0d0a46ceab826c6a8275ebfecfdb5ea975a8971d0ef2aac653cb73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11164-019-03772-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11164-019-03772-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Aman, Razia</creatorcontrib><creatorcontrib>Sadiq, Saima</creatorcontrib><creatorcontrib>Ali, Muhammad</creatorcontrib><creatorcontrib>Sadiq, Muhammad</creatorcontrib><creatorcontrib>Gul, Jehan</creatorcontrib><creatorcontrib>Saeed, Khalid</creatorcontrib><creatorcontrib>Khan, Adnan Ali</creatorcontrib><creatorcontrib>Shah, Sagheer Hussain</creatorcontrib><title>Facile route for green synthesis of N-benzylideneaniline over bimetallic reduced graphene oxide: chemical reactivity of 2,3,4-substituted derivatives of aniline</title><title>Research on chemical intermediates</title><addtitle>Res Chem Intermed</addtitle><description>Mn–Co-decorated reduced graphene oxide (Mn–Co–rGO) was prepared by modified condensation method and characterized through XRD, SEM, EDX, FTIR and BET surface area analysis. The prepared sample was explored for its activity in the synthesis of
N
-benzylideneaniline (
N
-BA) using benzyl alcohol and PhNH
2
as precursors. The catalyst has been used efficiently with high activity and selectivity for oxidation of benzyl alcohol to benzaldehyde in the presence of molecular oxygen, which further react with aniline to produced
N
-BA with sustainable catalytic activity up to five cycles. Furthermore, the effect of the nature and position of the substituent on aniline on the chemical reactivity of the nucleophile was studied theoretically using density functional calculations.</description><subject>Alcohol</subject><subject>Aniline</subject><subject>Benzaldehyde</subject><subject>Benzyl alcohol</subject><subject>Bimetals</subject><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Graphene</subject><subject>Inorganic Chemistry</subject><subject>Organic chemistry</subject><subject>Oxidation</subject><subject>Oxygen</subject><subject>Physical Chemistry</subject><subject>Selectivity</subject><issn>0922-6168</issn><issn>1568-5675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kUFu2zAQRYmiAeq6vUBXBLo1myFlUVJ3hRGnAYJ0k6yJETWMGciSS1JO3NPkqKXjANllNZv3_sfgM_ZNwg8JUJ1HKaVeCpCNgKKqlHj8wGay1LUodVV-ZDNolBJa6voT-xzjA4As6xpm7HmN1vfEwzgl4m4M_D4QDTwehrSh6CMfHb8RLQ3_Dr3vaCAcfO8H4uOeAm_9lhL2vbc8UDdZ6rKPuw0dgafM_-R2Q1tvsc8A2uT3Ph2OmWpRLJYiTm1MPuXujncU_B4zQS-lrz1f2JnDPtLX1ztnd-uL29Vvcf3n8mr161rYJUASUpJzmJ-VCB3gUlvCtlbaaqxVVVLryLquLQmbqsS6qWQH5BSi1WVh26qYs--n3F0Y_04Uk3kYpzDkSqMUNEUBhVSZUifKhjHGQM7sgt9iOBgJ5riEOS1h8hLmZQnzmKXiJMUMD_cU3qLfsf4Dy4uRCw</recordid><startdate>20190515</startdate><enddate>20190515</enddate><creator>Aman, Razia</creator><creator>Sadiq, Saima</creator><creator>Ali, Muhammad</creator><creator>Sadiq, Muhammad</creator><creator>Gul, Jehan</creator><creator>Saeed, Khalid</creator><creator>Khan, Adnan Ali</creator><creator>Shah, Sagheer Hussain</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20190515</creationdate><title>Facile route for green synthesis of N-benzylideneaniline over bimetallic reduced graphene oxide: chemical reactivity of 2,3,4-substituted derivatives of aniline</title><author>Aman, Razia ; Sadiq, Saima ; Ali, Muhammad ; Sadiq, Muhammad ; Gul, Jehan ; Saeed, Khalid ; Khan, Adnan Ali ; Shah, Sagheer Hussain</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c400t-11effa5671a0d0a46ceab826c6a8275ebfecfdb5ea975a8971d0ef2aac653cb73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alcohol</topic><topic>Aniline</topic><topic>Benzaldehyde</topic><topic>Benzyl alcohol</topic><topic>Bimetals</topic><topic>Catalysis</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Graphene</topic><topic>Inorganic Chemistry</topic><topic>Organic chemistry</topic><topic>Oxidation</topic><topic>Oxygen</topic><topic>Physical Chemistry</topic><topic>Selectivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aman, Razia</creatorcontrib><creatorcontrib>Sadiq, Saima</creatorcontrib><creatorcontrib>Ali, Muhammad</creatorcontrib><creatorcontrib>Sadiq, Muhammad</creatorcontrib><creatorcontrib>Gul, Jehan</creatorcontrib><creatorcontrib>Saeed, Khalid</creatorcontrib><creatorcontrib>Khan, Adnan Ali</creatorcontrib><creatorcontrib>Shah, Sagheer Hussain</creatorcontrib><collection>CrossRef</collection><jtitle>Research on chemical intermediates</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aman, Razia</au><au>Sadiq, Saima</au><au>Ali, Muhammad</au><au>Sadiq, Muhammad</au><au>Gul, Jehan</au><au>Saeed, Khalid</au><au>Khan, Adnan Ali</au><au>Shah, Sagheer Hussain</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile route for green synthesis of N-benzylideneaniline over bimetallic reduced graphene oxide: chemical reactivity of 2,3,4-substituted derivatives of aniline</atitle><jtitle>Research on chemical intermediates</jtitle><stitle>Res Chem Intermed</stitle><date>2019-05-15</date><risdate>2019</risdate><volume>45</volume><issue>5</issue><spage>2947</spage><epage>2961</epage><pages>2947-2961</pages><issn>0922-6168</issn><eissn>1568-5675</eissn><abstract>Mn–Co-decorated reduced graphene oxide (Mn–Co–rGO) was prepared by modified condensation method and characterized through XRD, SEM, EDX, FTIR and BET surface area analysis. The prepared sample was explored for its activity in the synthesis of
N
-benzylideneaniline (
N
-BA) using benzyl alcohol and PhNH
2
as precursors. The catalyst has been used efficiently with high activity and selectivity for oxidation of benzyl alcohol to benzaldehyde in the presence of molecular oxygen, which further react with aniline to produced
N
-BA with sustainable catalytic activity up to five cycles. Furthermore, the effect of the nature and position of the substituent on aniline on the chemical reactivity of the nucleophile was studied theoretically using density functional calculations.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11164-019-03772-w</doi><tpages>15</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Alcohol Aniline Benzaldehyde Benzyl alcohol Bimetals Catalysis Catalytic activity Chemistry Chemistry and Materials Science Graphene Inorganic Chemistry Organic chemistry Oxidation Oxygen Physical Chemistry Selectivity |
| title | Facile route for green synthesis of N-benzylideneaniline over bimetallic reduced graphene oxide: chemical reactivity of 2,3,4-substituted derivatives of aniline |
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