The Quasi-Binary System CeCoC2-CeNiC2: Crystal Structure and Physical Properties
The crystal structure of phases in the pseudo-binary system CeCo1–хNiхC2 (x = 0, 0.33, 0.5, 0.67, 0.79, 0.80, 0.83, 1) was investigated by means of X-ray powder diffraction. Co richer solid solutions CeCo1–хNiхC2 (0≤ x ≤0.5) crystallize in the monoclinic CeCoC2-type structure; a = 5.3968(2) Å, b =...
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| Veröffentlicht in: | Solid state phenomena 2019-04, Vol.289, p.114-119 |
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| creator | Hembara, Mykola Schumer, Alexander Levytskyy, Volodymyr Michor, Herwig Kotur, Bogdan Babizhetskyy, Volodymyr |
| description | The crystal structure of phases in the pseudo-binary system CeCo1–хNiхC2 (x = 0, 0.33, 0.5, 0.67, 0.79, 0.80, 0.83, 1) was investigated by means of X-ray powder diffraction. Co richer solid solutions CeCo1–хNiхC2 (0≤ x ≤0.5) crystallize in the monoclinic CeCoC2-type structure; a = 5.3968(2) Å, b = 5.4013(3) Å, c = 7.4762(3) Å, β = 102.136(3)°, V = 213.06(3) Å3 for x = 0.5. Ni-rich CeNi1–yCoyC2 (0≤ y ≤0.2) are isotypic with the orthorhombic CeNiC2-type structure, a = 3.8486(2) Å, b = 4.5479(2) Å, c = 6.1531(3) Å, V = 107.70(1) Å3 for y = 0.2. In the intermediate region (0.5< x |
| doi_str_mv | 10.4028/www.scientific.net/SSP.289.114 |
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Co richer solid solutions CeCo1–хNiхC2 (0≤ x ≤0.5) crystallize in the monoclinic CeCoC2-type structure; a = 5.3968(2) Å, b = 5.4013(3) Å, c = 7.4762(3) Å, β = 102.136(3)°, V = 213.06(3) Å3 for x = 0.5. Ni-rich CeNi1–yCoyC2 (0≤ y ≤0.2) are isotypic with the orthorhombic CeNiC2-type structure, a = 3.8486(2) Å, b = 4.5479(2) Å, c = 6.1531(3) Å, V = 107.70(1) Å3 for y = 0.2. In the intermediate region (0.5< x <0.79) both phases, CeCo0.21Ni0.79C2 and CeCo0.5Ni0.5C2, coexist. The non-isoelectronic substitution of Ni by Co in solid solutions CeNi1–yCoyC2 causes a continuous reduction of the Néel temperature and finally, for CeCoC2, results in a paramagnetic Kondo-lattice ground state.</description><identifier>ISSN: 1012-0394</identifier><identifier>ISSN: 1662-9779</identifier><identifier>EISSN: 1662-9779</identifier><identifier>DOI: 10.4028/www.scientific.net/SSP.289.114</identifier><language>eng</language><publisher>Zurich: Trans Tech Publications Ltd</publisher><subject>Binary system ; Crystal structure ; Nickel ; Physical properties ; Solid solutions ; X ray powder diffraction</subject><ispartof>Solid state phenomena, 2019-04, Vol.289, p.114-119</ispartof><rights>2019 Trans Tech Publications Ltd</rights><rights>Copyright Trans Tech Publications Ltd. Apr 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2714-21482c6fd61198b8412d6b3c23290cf6ac84d2346ef247d253c3509623d21b4f3</citedby><cites>FETCH-LOGICAL-c2714-21482c6fd61198b8412d6b3c23290cf6ac84d2346ef247d253c3509623d21b4f3</cites><orcidid>0000-0002-1844-4692</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttps://www.scientific.net/Image/TitleCover/4652?width=600</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Hembara, Mykola</creatorcontrib><creatorcontrib>Schumer, Alexander</creatorcontrib><creatorcontrib>Levytskyy, Volodymyr</creatorcontrib><creatorcontrib>Michor, Herwig</creatorcontrib><creatorcontrib>Kotur, Bogdan</creatorcontrib><creatorcontrib>Babizhetskyy, Volodymyr</creatorcontrib><title>The Quasi-Binary System CeCoC2-CeNiC2: Crystal Structure and Physical Properties</title><title>Solid state phenomena</title><description>The crystal structure of phases in the pseudo-binary system CeCo1–хNiхC2 (x = 0, 0.33, 0.5, 0.67, 0.79, 0.80, 0.83, 1) was investigated by means of X-ray powder diffraction. Co richer solid solutions CeCo1–хNiхC2 (0≤ x ≤0.5) crystallize in the monoclinic CeCoC2-type structure; a = 5.3968(2) Å, b = 5.4013(3) Å, c = 7.4762(3) Å, β = 102.136(3)°, V = 213.06(3) Å3 for x = 0.5. Ni-rich CeNi1–yCoyC2 (0≤ y ≤0.2) are isotypic with the orthorhombic CeNiC2-type structure, a = 3.8486(2) Å, b = 4.5479(2) Å, c = 6.1531(3) Å, V = 107.70(1) Å3 for y = 0.2. In the intermediate region (0.5< x <0.79) both phases, CeCo0.21Ni0.79C2 and CeCo0.5Ni0.5C2, coexist. The non-isoelectronic substitution of Ni by Co in solid solutions CeNi1–yCoyC2 causes a continuous reduction of the Néel temperature and finally, for CeCoC2, results in a paramagnetic Kondo-lattice ground state.</description><subject>Binary system</subject><subject>Crystal structure</subject><subject>Nickel</subject><subject>Physical properties</subject><subject>Solid solutions</subject><subject>X ray powder diffraction</subject><issn>1012-0394</issn><issn>1662-9779</issn><issn>1662-9779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqNkF1LwzAUhoMoOKf_oSB41y45ydLUC1GDXzC00nkdujRlGVs7k5Sxf29kwm69OofDy_NyHoRuCM4YBjHZ7XaZ19Z0wbZWZ50Jk6oqMxBFRgg7QSPCOaRFnhencccEUkwLdo4uvF9hTIkgYoTK-dIkn0Ptbfpou9rtk2rvg9kk0sheQirNu5Vwm0gXz_U6qYIbdBicSequScrl3lsdz6Xrt8YFa_wlOmvrtTdXf3OMvp6f5vI1nX28vMmHWaohJywFwgRo3jackEIsBCPQ8AXVQKHAuuW1FqwByrhpgeUNTKmmU1xwoA2QBWvpGF0fuFvXfw_GB7XqB9fFSgWABeWMCIipu0NKu957Z1q1dXYT31QEq1-LKlpUR4sqWlTRoooWVbQYAfcHQHB1F8Xo5bHnn4gfJSaB7w</recordid><startdate>20190401</startdate><enddate>20190401</enddate><creator>Hembara, Mykola</creator><creator>Schumer, Alexander</creator><creator>Levytskyy, Volodymyr</creator><creator>Michor, Herwig</creator><creator>Kotur, Bogdan</creator><creator>Babizhetskyy, Volodymyr</creator><general>Trans Tech Publications Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><orcidid>https://orcid.org/0000-0002-1844-4692</orcidid></search><sort><creationdate>20190401</creationdate><title>The Quasi-Binary System CeCoC2-CeNiC2: Crystal Structure and Physical Properties</title><author>Hembara, Mykola ; Schumer, Alexander ; Levytskyy, Volodymyr ; Michor, Herwig ; Kotur, Bogdan ; Babizhetskyy, Volodymyr</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2714-21482c6fd61198b8412d6b3c23290cf6ac84d2346ef247d253c3509623d21b4f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Binary system</topic><topic>Crystal structure</topic><topic>Nickel</topic><topic>Physical properties</topic><topic>Solid solutions</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hembara, Mykola</creatorcontrib><creatorcontrib>Schumer, Alexander</creatorcontrib><creatorcontrib>Levytskyy, Volodymyr</creatorcontrib><creatorcontrib>Michor, Herwig</creatorcontrib><creatorcontrib>Kotur, Bogdan</creatorcontrib><creatorcontrib>Babizhetskyy, Volodymyr</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><jtitle>Solid state phenomena</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hembara, Mykola</au><au>Schumer, Alexander</au><au>Levytskyy, Volodymyr</au><au>Michor, Herwig</au><au>Kotur, Bogdan</au><au>Babizhetskyy, Volodymyr</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The Quasi-Binary System CeCoC2-CeNiC2: Crystal Structure and Physical Properties</atitle><jtitle>Solid state phenomena</jtitle><date>2019-04-01</date><risdate>2019</risdate><volume>289</volume><spage>114</spage><epage>119</epage><pages>114-119</pages><issn>1012-0394</issn><issn>1662-9779</issn><eissn>1662-9779</eissn><abstract>The crystal structure of phases in the pseudo-binary system CeCo1–хNiхC2 (x = 0, 0.33, 0.5, 0.67, 0.79, 0.80, 0.83, 1) was investigated by means of X-ray powder diffraction. Co richer solid solutions CeCo1–хNiхC2 (0≤ x ≤0.5) crystallize in the monoclinic CeCoC2-type structure; a = 5.3968(2) Å, b = 5.4013(3) Å, c = 7.4762(3) Å, β = 102.136(3)°, V = 213.06(3) Å3 for x = 0.5. Ni-rich CeNi1–yCoyC2 (0≤ y ≤0.2) are isotypic with the orthorhombic CeNiC2-type structure, a = 3.8486(2) Å, b = 4.5479(2) Å, c = 6.1531(3) Å, V = 107.70(1) Å3 for y = 0.2. In the intermediate region (0.5< x <0.79) both phases, CeCo0.21Ni0.79C2 and CeCo0.5Ni0.5C2, coexist. The non-isoelectronic substitution of Ni by Co in solid solutions CeNi1–yCoyC2 causes a continuous reduction of the Néel temperature and finally, for CeCoC2, results in a paramagnetic Kondo-lattice ground state.</abstract><cop>Zurich</cop><pub>Trans Tech Publications Ltd</pub><doi>10.4028/www.scientific.net/SSP.289.114</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-1844-4692</orcidid></addata></record> |
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| subjects | Binary system Crystal structure Nickel Physical properties Solid solutions X ray powder diffraction |
| title | The Quasi-Binary System CeCoC2-CeNiC2: Crystal Structure and Physical Properties |
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