Thermal behaviour of bambus[6]uril and its chloride caviplex
The present paper presents the thermal behaviour of methyl-bambus[6]uril in its anion-free and chlorine-included form. Our study was based on thermogravimetry associated to Fourier-transform infrared spectroscopy and differential scanning calorimetry. The compounds decompose after 300 ∘ C and both f...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2019-05, Vol.136 (3), p.1195-1199 |
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| container_title | Journal of thermal analysis and calorimetry |
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| creator | Cicolani, Renato Salviato Job, Aldo Eloizo Tonin, Fernando Gustavo Correia, Henrique Dias Demets, Grégoire Jean-François |
| description | The present paper presents the thermal behaviour of methyl-bambus[6]uril in its anion-free and chlorine-included form. Our study was based on thermogravimetry associated to Fourier-transform infrared spectroscopy and differential scanning calorimetry. The compounds decompose after
300
∘
C
and both forms of this macrocycle, contain four hydration water molecules. The main decomposition products are
H
2
O
,
CO
2
,
NH
3
and isocyanic acid as we could detect by FTIR spectroscopy. Finally, we verified that the caviplex loses its chloride ion after
270
∘
C
and may produce the anion-free macrocyle upon heating. |
| doi_str_mv | 10.1007/s10973-018-7755-0 |
| format | Article |
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300
∘
C
and both forms of this macrocycle, contain four hydration water molecules. The main decomposition products are
H
2
O
,
CO
2
,
NH
3
and isocyanic acid as we could detect by FTIR spectroscopy. Finally, we verified that the caviplex loses its chloride ion after
270
∘
C
and may produce the anion-free macrocyle upon heating.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-018-7755-0</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Ammonia ; Analytical Chemistry ; Anions ; Chemistry ; Chemistry and Materials Science ; Chloride ions ; Chlorine ; Crystals ; Decomposition ; Fourier transforms ; Inorganic Chemistry ; Measurement Science and Instrumentation ; Physical Chemistry ; Polymer Sciences ; Spectroscopy ; Spectrum analysis ; Thermodynamic properties ; Thermogravimetry ; Water ; Water chemistry</subject><ispartof>Journal of thermal analysis and calorimetry, 2019-05, Vol.136 (3), p.1195-1199</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2018</rights><rights>COPYRIGHT 2019 Springer</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c426t-4e5faabdbb7d6dea39683981e98fa53e7aab64030103d86ec5593bee597bfe723</citedby><cites>FETCH-LOGICAL-c426t-4e5faabdbb7d6dea39683981e98fa53e7aab64030103d86ec5593bee597bfe723</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-018-7755-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-018-7755-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Cicolani, Renato Salviato</creatorcontrib><creatorcontrib>Job, Aldo Eloizo</creatorcontrib><creatorcontrib>Tonin, Fernando Gustavo</creatorcontrib><creatorcontrib>Correia, Henrique Dias</creatorcontrib><creatorcontrib>Demets, Grégoire Jean-François</creatorcontrib><title>Thermal behaviour of bambus[6]uril and its chloride caviplex</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>The present paper presents the thermal behaviour of methyl-bambus[6]uril in its anion-free and chlorine-included form. Our study was based on thermogravimetry associated to Fourier-transform infrared spectroscopy and differential scanning calorimetry. The compounds decompose after
300
∘
C
and both forms of this macrocycle, contain four hydration water molecules. The main decomposition products are
H
2
O
,
CO
2
,
NH
3
and isocyanic acid as we could detect by FTIR spectroscopy. Finally, we verified that the caviplex loses its chloride ion after
270
∘
C
and may produce the anion-free macrocyle upon heating.</description><subject>Ammonia</subject><subject>Analytical Chemistry</subject><subject>Anions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chloride ions</subject><subject>Chlorine</subject><subject>Crystals</subject><subject>Decomposition</subject><subject>Fourier transforms</subject><subject>Inorganic Chemistry</subject><subject>Measurement Science and Instrumentation</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>Thermodynamic properties</subject><subject>Thermogravimetry</subject><subject>Water</subject><subject>Water chemistry</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kU1Lw0AQhhdRsFZ_gLeAJw-ps9lsdhe8FPGjUBC0nkSWTTLbpqRJ3U2k_nu3RJAeZA4zzDzvzMBLyCWFCQUQN56CEiwGKmMhOI_hiIwolzJOVJIdh5qFOqMcTsmZ92sAUAroiNwuVug2po5yXJmvqu1d1NooN5u89-_ZR--qOjJNGVWdj4pV3bqqxKgI5LbG3Tk5sab2ePGbx-Tt4X5x9xTPnx9nd9N5XKRJ1sUpcmtMXua5KLMSDVOZZEpSVNIazlCEYZYCAwqslBkWnCuWI3IlcosiYWNyNezduvazR9_pdXi0CSd1koCkLGVMBWoyUEtTo64a23bOFCFK3FRF26CtQn_KZUJTRkOMyfWBIDAd7rql6b3Xs9eXQ5YObOFa7x1avXXVxrhvTUHvHdCDAzo4oPcOaAiaZND4wDZLdH9v_y_6AR8Bhzw</recordid><startdate>20190501</startdate><enddate>20190501</enddate><creator>Cicolani, Renato Salviato</creator><creator>Job, Aldo Eloizo</creator><creator>Tonin, Fernando Gustavo</creator><creator>Correia, Henrique Dias</creator><creator>Demets, Grégoire Jean-François</creator><general>Springer International Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20190501</creationdate><title>Thermal behaviour of bambus[6]uril and its chloride caviplex</title><author>Cicolani, Renato Salviato ; Job, Aldo Eloizo ; Tonin, Fernando Gustavo ; Correia, Henrique Dias ; Demets, Grégoire Jean-François</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c426t-4e5faabdbb7d6dea39683981e98fa53e7aab64030103d86ec5593bee597bfe723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Ammonia</topic><topic>Analytical Chemistry</topic><topic>Anions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chloride ions</topic><topic>Chlorine</topic><topic>Crystals</topic><topic>Decomposition</topic><topic>Fourier transforms</topic><topic>Inorganic Chemistry</topic><topic>Measurement Science and Instrumentation</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><topic>Thermodynamic properties</topic><topic>Thermogravimetry</topic><topic>Water</topic><topic>Water chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cicolani, Renato Salviato</creatorcontrib><creatorcontrib>Job, Aldo Eloizo</creatorcontrib><creatorcontrib>Tonin, Fernando Gustavo</creatorcontrib><creatorcontrib>Correia, Henrique Dias</creatorcontrib><creatorcontrib>Demets, Grégoire Jean-François</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cicolani, Renato Salviato</au><au>Job, Aldo Eloizo</au><au>Tonin, Fernando Gustavo</au><au>Correia, Henrique Dias</au><au>Demets, Grégoire Jean-François</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermal behaviour of bambus[6]uril and its chloride caviplex</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2019-05-01</date><risdate>2019</risdate><volume>136</volume><issue>3</issue><spage>1195</spage><epage>1199</epage><pages>1195-1199</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>The present paper presents the thermal behaviour of methyl-bambus[6]uril in its anion-free and chlorine-included form. Our study was based on thermogravimetry associated to Fourier-transform infrared spectroscopy and differential scanning calorimetry. The compounds decompose after
300
∘
C
and both forms of this macrocycle, contain four hydration water molecules. The main decomposition products are
H
2
O
,
CO
2
,
NH
3
and isocyanic acid as we could detect by FTIR spectroscopy. Finally, we verified that the caviplex loses its chloride ion after
270
∘
C
and may produce the anion-free macrocyle upon heating.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10973-018-7755-0</doi><tpages>5</tpages></addata></record> |
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| subjects | Ammonia Analytical Chemistry Anions Chemistry Chemistry and Materials Science Chloride ions Chlorine Crystals Decomposition Fourier transforms Inorganic Chemistry Measurement Science and Instrumentation Physical Chemistry Polymer Sciences Spectroscopy Spectrum analysis Thermodynamic properties Thermogravimetry Water Water chemistry |
| title | Thermal behaviour of bambus[6]uril and its chloride caviplex |
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