Synthesis of aryl and heteroaryl tetrafluoro-λ6-sulfanyl chlorides from diaryl disulfides using trichloroisocyanuric acid and potassium fluoride

We present a catalyst-free method for the synthesis of aryl and heteroaryl tetrafluoro-λ6-sulfanyl chlorides (Ar-SF4Cl) by using trichloroisocyanuric acid and potassium fluoride in acetonitrile. The method has wide substrate generality and proceeded well with high yields even in the absence of acid...

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Veröffentlicht in:	Organic chemistry frontiers an international journal of organic chemistry 2019-01, Vol.6 (8), p.1157-1161
Hauptverfasser:	Saidalimu, Ibrayim, Liang, Yumeng, Kiyoteru Niina, Tanagawa, Kazuhiro, Saito, Norimichi, Shibata, Norio
Format:	Artikel
Sprache:	eng ; jpn
Schlagworte:	Acetonitrile Acids Aromatic compounds Catalysis Catalysts Chemical synthesis Chlorides Fluorides Organic chemistry Potassium Potassium fluoride Pyridines Substrates
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