The effect of alkyl chain of the imidazolium ring on the poly(o-methoxyaniline)/ionic liquid supercapacitor performance
New materials can be developed using a known compound with enhanced properties modifying and controlling its microstructure, morphology, and density of defects. In this work, a new material was produced by the addition of ionic liquid (IL) to the poly(o-methoxyaniline) (POMA) conductive polymer, in...
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| Veröffentlicht in: | Journal of solid state electrochemistry 2019-04, Vol.23 (4), p.1109-1119 |
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| creator | da Trindade, L. G. Christinelli, W. A. Zanchet, L. Coelho, D. Trench, A. B. Martini, Emilse M. A. Correa, Daniel S. Mattoso, Luiz H. C. Pereira, E. C. |
| description | New materials can be developed using a known compound with enhanced properties modifying and controlling its microstructure, morphology, and density of defects. In this work, a new material was produced by the addition of ionic liquid (IL) to the poly(o-methoxyaniline) (POMA) conductive polymer, in the form of esmeraldine salt. The polymer impregnated with IL was tested as an electrode for use in supercapacitors. The results show that the charge storage properties of the materials are dependent on the length of the alquil substituent of imidazolium ring of ionic liquid cation. The best results, obtained by the addition of 1-butyl-3-methylimidazolium triflate IL to the polymer, improved electrical charge storage and electrochemical stability, making the material a promising electrode for supercapacitor devices. This compound has specific capacitance of 205 F/g, five times larger than pure POMA and was stable for 3000 cycles of charge/discharge experiments carried out at 1.0 A/g.
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| doi_str_mv | 10.1007/s10008-018-04183-4 |
| format | Article |
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Graphical Abstract</description><subject>Analytical Chemistry</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Current carriers</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Energy Storage</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Morphology</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Polymers</subject><subject>Supercapacitors</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9kE1PxCAQhhujievqH_BE4kUPuFAopUez8SvZxMveCUvBZW2hC220_nrZrYk3Q2CYmfedSZ4su8boHiNULmJ6EYcIp0sxJ5CeZDNMCYGoZPz0-M8hp5yfZxcx7hDCJcNoln2utxpoY7TqgTdANh9jA9RWWndI-9S0ra3lt2_s0IJg3Tvw7ljvfDPeetjqfuu_RulsY52-W1jvrAKN3Q-2BnHodFCyk8r2PoCUGB9a6ZS-zM6MbKK--o3zbP30uF6-wNXb8-vyYQUVKVgPzYZWhWQbqSWjppBSK8JUnZeU1YRUptpUmqeDCJc0JwQrLQuCEMtRXZeEzLObaWwX_H7QsRc7PwSXNoo8RwVlOaFFUuWTSgUfY9BGdMG2MowCI3HgKya-IvEVR76CJhOZTLE7YNHhb_Q_rh_C4X_M</recordid><startdate>20190412</startdate><enddate>20190412</enddate><creator>da Trindade, L. 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A.</creatorcontrib><creatorcontrib>Zanchet, L.</creatorcontrib><creatorcontrib>Coelho, D.</creatorcontrib><creatorcontrib>Trench, A. B.</creatorcontrib><creatorcontrib>Martini, Emilse M. A.</creatorcontrib><creatorcontrib>Correa, Daniel S.</creatorcontrib><creatorcontrib>Mattoso, Luiz H. C.</creatorcontrib><creatorcontrib>Pereira, E. C.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>da Trindade, L. G.</au><au>Christinelli, W. A.</au><au>Zanchet, L.</au><au>Coelho, D.</au><au>Trench, A. B.</au><au>Martini, Emilse M. A.</au><au>Correa, Daniel S.</au><au>Mattoso, Luiz H. C.</au><au>Pereira, E. 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The results show that the charge storage properties of the materials are dependent on the length of the alquil substituent of imidazolium ring of ionic liquid cation. The best results, obtained by the addition of 1-butyl-3-methylimidazolium triflate IL to the polymer, improved electrical charge storage and electrochemical stability, making the material a promising electrode for supercapacitor devices. This compound has specific capacitance of 205 F/g, five times larger than pure POMA and was stable for 3000 cycles of charge/discharge experiments carried out at 1.0 A/g.
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| subjects | Analytical Chemistry Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Current carriers Electrochemistry Electrodes Energy Storage Ionic liquids Ions Morphology Original Paper Physical Chemistry Polymers Supercapacitors |
| title | The effect of alkyl chain of the imidazolium ring on the poly(o-methoxyaniline)/ionic liquid supercapacitor performance |
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