Homo‐ and Heterobimetallic Complexes Bearing NHC Ligands: Applications in α‐Arylation of Amide, Suzuki–Miyaura Coupling Reactions, and Tandem Catalysis

A heterobimetallic IrIII/PdII complex from a dicarbene donor ligand featuring cyclometalated IrIII and PEPPSI type PdII is presented along with a homodinuclear PEPPSI type PdII complex starting from the same bis‐imidazolium salt. All the PdII complexes are active precatalyst in both α‐arylation and...

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Veröffentlicht in:	European journal of inorganic chemistry 2019-04, Vol.2019 (13), p.1810-1815
Hauptverfasser:	Majumder, Adhir, Naskar, Rajat, Roy, Pallabi, Maity, Ramananda
Format:	Artikel
Sprache:	eng
Schlagworte:	Cascade chemical reactions Catalysis Chemical reactions Coordination compounds Coupling Heterobimetallic complexes Iridium Homogeneous catalysis Inorganic chemistry Intermolecular α‐arylation of amide Ligands Palladium
Online-Zugang:	Volltext
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