Efficient method for the synthesis of 1,3-unsubstituted 2-imino-5-oxooctahydroimidazo[4,5-d]imidazolium iodides based on thioglycolurils
A facile and efficient two-step synthetic route to previously inaccessible 1,3-unsubstituted 2-imino-5-oxooctahydroimidazo[4,5- d ]-imidazol-1-ium iodides has been developed using easily accessible thioglycolurils, MeI, and various primary amines, morpholine, or ethylene diamine. The structure of re...
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Veröffentlicht in: | Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2019-02, Vol.55 (2), p.160-166 |
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container_title | Chemistry of heterocyclic compounds (New York, N.Y. 1965) |
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creator | Baranov, Vladimir V. Yatsenko, Evgeniya L. Melnikova, Elizaveta K. Nelyubina, Yulia V. Kravchenko, Angelina N. |
description | A facile and efficient two-step synthetic route to previously inaccessible 1,3-unsubstituted 2-imino-5-oxooctahydroimidazo[4,5-
d
]-imidazol-1-ium iodides has been developed using easily accessible thioglycolurils, MeI, and various primary amines, morpholine, or ethylene diamine. The structure of representative products and hydrogen-bonding pattern in their crystals have been investigated by X-ray diffraction. |
doi_str_mv | 10.1007/s10593-019-02433-5 |
format | Article |
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subjects | Amines Analysis Chemistry Chemistry and Materials Science Crystal structure Crystals Diamines Diffraction patterns Ethylenediamines Hydrogen Hydrogen bonding Hydrogen bonds Iodides Methods Morpholine Organic Chemistry Pharmacy Technology X-ray diffraction |
title | Efficient method for the synthesis of 1,3-unsubstituted 2-imino-5-oxooctahydroimidazo[4,5-d]imidazolium iodides based on thioglycolurils |
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