High-quality fuel distillates produced from oligomerization of light olefin over supported phosphoric acid on H-Zeolite-Y
Oligomerization of isobutene to produce high-quality fuel distillates in the range of gasoline, jet fuel and diesel free of sulfur, nitrogen and aromatic hydrocarbons has been investigated over a new environmental-friendly, clean and long-lifetime supported phosphoric acid on H-Zeolite-Y catalyst wi...
Gespeichert in:
| Veröffentlicht in: | Applied petrochemical research 2019-03, Vol.9 (1), p.35-45 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 45 |
|---|---|
| container_issue | 1 |
| container_start_page | 35 |
| container_title | Applied petrochemical research |
| container_volume | 9 |
| creator | Al-Kinany, Mohammed C. Al-Drees, Saud A. Al -Megren, Hamid A. Alshihri, Saeed M. Alghilan, Eyad A. Al-Shehri, Feras A. Al-Hamdan, Abdulmohsin S. Alghamdi, Abdullah J. Al-Dress, Sami D. |
| description | Oligomerization of isobutene to produce high-quality fuel distillates in the range of gasoline, jet fuel and diesel free of sulfur, nitrogen and aromatic hydrocarbons has been investigated over a new environmental-friendly, clean and long-lifetime supported phosphoric acid on H-Zeolite-Y catalyst with SiO
2
/Al
2
O
3 mol
ratio of 60. The catalyst was obtained by acid impregnation and ultrasonic vibration technique with successive heating at different temperatures and under atmospheric pressure. The catalysts were characterized by several techniques (BET, SEM, XRD, TDA, TGA and XPS). The oligomerization reactions were carried out in a gas phase using fixed-bed flow reactor at variable temperature ranges between 50 and 100 °C under atmospheric pressure with a space velocity (WHSV) of 176 h
−1
.The fuel distillates were identified by GC/MS and quantified by gas chromatography. The results showed that the conversion of isobutene into distillates ranges between 97 and 100%. The maximum selectivity to C
8
=
isomers is about 65%, and a flow rate of isobutene 5.0 ml/min. and temperature 50 °C were obtained. Research octane number under the above-mentioned conditions ranges between 85 and 96, and Reid pressure ranges between 27 and 125 Pa. |
| doi_str_mv | 10.1007/s13203-019-0225-1 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2201460441</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A582798245</galeid><sourcerecordid>A582798245</sourcerecordid><originalsourceid>FETCH-LOGICAL-c362t-9735c1be829bd5f0ea89db88f85721cf698594affbe05d37927e4125b4f09e703</originalsourceid><addsrcrecordid>eNp1kUFrHSEQx5fSQkOSD9Cb0FMPpuquTz2G0PYFAoG0PSQXcXfHfYZ960bdktdP33lsoM2hiqjj7z_O8K-qD5xdcMbU58xrwWrKuKFMCEn5m-pEcMOolEK-_ef8vjrP-ZHhkMoYpU-qwzYMO_q0uDGUA_ELjKQPuYRxdAUymVPslw564lPckziGIe4hhd-uhDiR6AlGdgUfwAe8_4JE8jLPMRXUzLuYcaXQEdeFnqBiSx8AsxSg92fVO-_GDOcv-2n18-uXH1dbenP77frq8oZ29UYUalQtO96CFqbtpWfgtOlbrb2WSvDOb4yWpnHet8BkXysjFDRcyLbxzIBi9Wn1cc2LvTwtkIt9jEua8EsrBOPNhjUNR-pipQY3gg2TjyW5DmcP-9DFCfvD-KXUQhktGomCT68EyBR4LoNbcrbX3-9es3xluxRzTuDtnMLepYPlzB4dtKuDFh20RwftsSCxajKy0wDpb9n_F_0Bs4qePA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2201460441</pqid></control><display><type>article</type><title>High-quality fuel distillates produced from oligomerization of light olefin over supported phosphoric acid on H-Zeolite-Y</title><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>Springer Nature OA Free Journals</source><source>Free Full-Text Journals in Chemistry</source><creator>Al-Kinany, Mohammed C. ; Al-Drees, Saud A. ; Al -Megren, Hamid A. ; Alshihri, Saeed M. ; Alghilan, Eyad A. ; Al-Shehri, Feras A. ; Al-Hamdan, Abdulmohsin S. ; Alghamdi, Abdullah J. ; Al-Dress, Sami D.</creator><creatorcontrib>Al-Kinany, Mohammed C. ; Al-Drees, Saud A. ; Al -Megren, Hamid A. ; Alshihri, Saeed M. ; Alghilan, Eyad A. ; Al-Shehri, Feras A. ; Al-Hamdan, Abdulmohsin S. ; Alghamdi, Abdullah J. ; Al-Dress, Sami D.</creatorcontrib><description>Oligomerization of isobutene to produce high-quality fuel distillates in the range of gasoline, jet fuel and diesel free of sulfur, nitrogen and aromatic hydrocarbons has been investigated over a new environmental-friendly, clean and long-lifetime supported phosphoric acid on H-Zeolite-Y catalyst with SiO
2
/Al
2
O
3 mol
ratio of 60. The catalyst was obtained by acid impregnation and ultrasonic vibration technique with successive heating at different temperatures and under atmospheric pressure. The catalysts were characterized by several techniques (BET, SEM, XRD, TDA, TGA and XPS). The oligomerization reactions were carried out in a gas phase using fixed-bed flow reactor at variable temperature ranges between 50 and 100 °C under atmospheric pressure with a space velocity (WHSV) of 176 h
−1
.The fuel distillates were identified by GC/MS and quantified by gas chromatography. The results showed that the conversion of isobutene into distillates ranges between 97 and 100%. The maximum selectivity to C
8
=
isomers is about 65%, and a flow rate of isobutene 5.0 ml/min. and temperature 50 °C were obtained. Research octane number under the above-mentioned conditions ranges between 85 and 96, and Reid pressure ranges between 27 and 125 Pa.</description><identifier>ISSN: 2190-5525</identifier><identifier>EISSN: 2190-5525</identifier><identifier>EISSN: 2190-5533</identifier><identifier>DOI: 10.1007/s13203-019-0225-1</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Aluminum oxide ; Aromatic hydrocarbons ; Atmospheric pressure ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Diesel fuels ; Distillates ; Energy Systems ; Flow rates ; Flow velocity ; Gas chromatography ; Gasoline ; Industrial Chemistry/Chemical Engineering ; Isomers ; Jet engine fuels ; Nanochemistry ; Nanotechnology and Microengineering ; Nuclear fuels ; Octane number ; Olefins ; Oligomerization ; Oligomers ; Original Article ; Phosphates ; Phosphoric acid ; Selectivity ; Silicon dioxide ; Sulfur ; Sulfur compounds ; Ultrasonic vibration ; Vapor phases ; X ray photoelectron spectroscopy ; Zeolites</subject><ispartof>Applied petrochemical research, 2019-03, Vol.9 (1), p.35-45</ispartof><rights>The Author(s) 2019</rights><rights>COPYRIGHT 2019 Springer</rights><rights>Applied Petrochemical Research is a copyright of Springer, (2019). All Rights Reserved. © 2019. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c362t-9735c1be829bd5f0ea89db88f85721cf698594affbe05d37927e4125b4f09e703</citedby><cites>FETCH-LOGICAL-c362t-9735c1be829bd5f0ea89db88f85721cf698594affbe05d37927e4125b4f09e703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13203-019-0225-1$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://doi.org/10.1007/s13203-019-0225-1$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,27924,27925,41120,42189,51576</link.rule.ids></links><search><creatorcontrib>Al-Kinany, Mohammed C.</creatorcontrib><creatorcontrib>Al-Drees, Saud A.</creatorcontrib><creatorcontrib>Al -Megren, Hamid A.</creatorcontrib><creatorcontrib>Alshihri, Saeed M.</creatorcontrib><creatorcontrib>Alghilan, Eyad A.</creatorcontrib><creatorcontrib>Al-Shehri, Feras A.</creatorcontrib><creatorcontrib>Al-Hamdan, Abdulmohsin S.</creatorcontrib><creatorcontrib>Alghamdi, Abdullah J.</creatorcontrib><creatorcontrib>Al-Dress, Sami D.</creatorcontrib><title>High-quality fuel distillates produced from oligomerization of light olefin over supported phosphoric acid on H-Zeolite-Y</title><title>Applied petrochemical research</title><addtitle>Appl Petrochem Res</addtitle><description>Oligomerization of isobutene to produce high-quality fuel distillates in the range of gasoline, jet fuel and diesel free of sulfur, nitrogen and aromatic hydrocarbons has been investigated over a new environmental-friendly, clean and long-lifetime supported phosphoric acid on H-Zeolite-Y catalyst with SiO
2
/Al
2
O
3 mol
ratio of 60. The catalyst was obtained by acid impregnation and ultrasonic vibration technique with successive heating at different temperatures and under atmospheric pressure. The catalysts were characterized by several techniques (BET, SEM, XRD, TDA, TGA and XPS). The oligomerization reactions were carried out in a gas phase using fixed-bed flow reactor at variable temperature ranges between 50 and 100 °C under atmospheric pressure with a space velocity (WHSV) of 176 h
−1
.The fuel distillates were identified by GC/MS and quantified by gas chromatography. The results showed that the conversion of isobutene into distillates ranges between 97 and 100%. The maximum selectivity to C
8
=
isomers is about 65%, and a flow rate of isobutene 5.0 ml/min. and temperature 50 °C were obtained. Research octane number under the above-mentioned conditions ranges between 85 and 96, and Reid pressure ranges between 27 and 125 Pa.</description><subject>Aluminum oxide</subject><subject>Aromatic hydrocarbons</subject><subject>Atmospheric pressure</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Diesel fuels</subject><subject>Distillates</subject><subject>Energy Systems</subject><subject>Flow rates</subject><subject>Flow velocity</subject><subject>Gas chromatography</subject><subject>Gasoline</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Isomers</subject><subject>Jet engine fuels</subject><subject>Nanochemistry</subject><subject>Nanotechnology and Microengineering</subject><subject>Nuclear fuels</subject><subject>Octane number</subject><subject>Olefins</subject><subject>Oligomerization</subject><subject>Oligomers</subject><subject>Original Article</subject><subject>Phosphates</subject><subject>Phosphoric acid</subject><subject>Selectivity</subject><subject>Silicon dioxide</subject><subject>Sulfur</subject><subject>Sulfur compounds</subject><subject>Ultrasonic vibration</subject><subject>Vapor phases</subject><subject>X ray photoelectron spectroscopy</subject><subject>Zeolites</subject><issn>2190-5525</issn><issn>2190-5525</issn><issn>2190-5533</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kUFrHSEQx5fSQkOSD9Cb0FMPpuquTz2G0PYFAoG0PSQXcXfHfYZ960bdktdP33lsoM2hiqjj7z_O8K-qD5xdcMbU58xrwWrKuKFMCEn5m-pEcMOolEK-_ef8vjrP-ZHhkMoYpU-qwzYMO_q0uDGUA_ELjKQPuYRxdAUymVPslw564lPckziGIe4hhd-uhDiR6AlGdgUfwAe8_4JE8jLPMRXUzLuYcaXQEdeFnqBiSx8AsxSg92fVO-_GDOcv-2n18-uXH1dbenP77frq8oZ29UYUalQtO96CFqbtpWfgtOlbrb2WSvDOb4yWpnHet8BkXysjFDRcyLbxzIBi9Wn1cc2LvTwtkIt9jEua8EsrBOPNhjUNR-pipQY3gg2TjyW5DmcP-9DFCfvD-KXUQhktGomCT68EyBR4LoNbcrbX3-9es3xluxRzTuDtnMLepYPlzB4dtKuDFh20RwftsSCxajKy0wDpb9n_F_0Bs4qePA</recordid><startdate>20190301</startdate><enddate>20190301</enddate><creator>Al-Kinany, Mohammed C.</creator><creator>Al-Drees, Saud A.</creator><creator>Al -Megren, Hamid A.</creator><creator>Alshihri, Saeed M.</creator><creator>Alghilan, Eyad A.</creator><creator>Al-Shehri, Feras A.</creator><creator>Al-Hamdan, Abdulmohsin S.</creator><creator>Alghamdi, Abdullah J.</creator><creator>Al-Dress, Sami D.</creator><general>Springer International Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M7S</scope><scope>PCBAR</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PTHSS</scope></search><sort><creationdate>20190301</creationdate><title>High-quality fuel distillates produced from oligomerization of light olefin over supported phosphoric acid on H-Zeolite-Y</title><author>Al-Kinany, Mohammed C. ; Al-Drees, Saud A. ; Al -Megren, Hamid A. ; Alshihri, Saeed M. ; Alghilan, Eyad A. ; Al-Shehri, Feras A. ; Al-Hamdan, Abdulmohsin S. ; Alghamdi, Abdullah J. ; Al-Dress, Sami D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c362t-9735c1be829bd5f0ea89db88f85721cf698594affbe05d37927e4125b4f09e703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aluminum oxide</topic><topic>Aromatic hydrocarbons</topic><topic>Atmospheric pressure</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Diesel fuels</topic><topic>Distillates</topic><topic>Energy Systems</topic><topic>Flow rates</topic><topic>Flow velocity</topic><topic>Gas chromatography</topic><topic>Gasoline</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Isomers</topic><topic>Jet engine fuels</topic><topic>Nanochemistry</topic><topic>Nanotechnology and Microengineering</topic><topic>Nuclear fuels</topic><topic>Octane number</topic><topic>Olefins</topic><topic>Oligomerization</topic><topic>Oligomers</topic><topic>Original Article</topic><topic>Phosphates</topic><topic>Phosphoric acid</topic><topic>Selectivity</topic><topic>Silicon dioxide</topic><topic>Sulfur</topic><topic>Sulfur compounds</topic><topic>Ultrasonic vibration</topic><topic>Vapor phases</topic><topic>X ray photoelectron spectroscopy</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Al-Kinany, Mohammed C.</creatorcontrib><creatorcontrib>Al-Drees, Saud A.</creatorcontrib><creatorcontrib>Al -Megren, Hamid A.</creatorcontrib><creatorcontrib>Alshihri, Saeed M.</creatorcontrib><creatorcontrib>Alghilan, Eyad A.</creatorcontrib><creatorcontrib>Al-Shehri, Feras A.</creatorcontrib><creatorcontrib>Al-Hamdan, Abdulmohsin S.</creatorcontrib><creatorcontrib>Alghamdi, Abdullah J.</creatorcontrib><creatorcontrib>Al-Dress, Sami D.</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Engineering Collection</collection><jtitle>Applied petrochemical research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Al-Kinany, Mohammed C.</au><au>Al-Drees, Saud A.</au><au>Al -Megren, Hamid A.</au><au>Alshihri, Saeed M.</au><au>Alghilan, Eyad A.</au><au>Al-Shehri, Feras A.</au><au>Al-Hamdan, Abdulmohsin S.</au><au>Alghamdi, Abdullah J.</au><au>Al-Dress, Sami D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-quality fuel distillates produced from oligomerization of light olefin over supported phosphoric acid on H-Zeolite-Y</atitle><jtitle>Applied petrochemical research</jtitle><stitle>Appl Petrochem Res</stitle><date>2019-03-01</date><risdate>2019</risdate><volume>9</volume><issue>1</issue><spage>35</spage><epage>45</epage><pages>35-45</pages><issn>2190-5525</issn><eissn>2190-5525</eissn><eissn>2190-5533</eissn><abstract>Oligomerization of isobutene to produce high-quality fuel distillates in the range of gasoline, jet fuel and diesel free of sulfur, nitrogen and aromatic hydrocarbons has been investigated over a new environmental-friendly, clean and long-lifetime supported phosphoric acid on H-Zeolite-Y catalyst with SiO
2
/Al
2
O
3 mol
ratio of 60. The catalyst was obtained by acid impregnation and ultrasonic vibration technique with successive heating at different temperatures and under atmospheric pressure. The catalysts were characterized by several techniques (BET, SEM, XRD, TDA, TGA and XPS). The oligomerization reactions were carried out in a gas phase using fixed-bed flow reactor at variable temperature ranges between 50 and 100 °C under atmospheric pressure with a space velocity (WHSV) of 176 h
−1
.The fuel distillates were identified by GC/MS and quantified by gas chromatography. The results showed that the conversion of isobutene into distillates ranges between 97 and 100%. The maximum selectivity to C
8
=
isomers is about 65%, and a flow rate of isobutene 5.0 ml/min. and temperature 50 °C were obtained. Research octane number under the above-mentioned conditions ranges between 85 and 96, and Reid pressure ranges between 27 and 125 Pa.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s13203-019-0225-1</doi><tpages>11</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2190-5525 |
| ispartof | Applied petrochemical research, 2019-03, Vol.9 (1), p.35-45 |
| issn | 2190-5525 2190-5525 2190-5533 |
| language | eng |
| recordid | cdi_proquest_journals_2201460441 |
| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Springer Nature OA Free Journals; Free Full-Text Journals in Chemistry |
| subjects | Aluminum oxide Aromatic hydrocarbons Atmospheric pressure Catalysis Catalysts Chemistry Chemistry and Materials Science Diesel fuels Distillates Energy Systems Flow rates Flow velocity Gas chromatography Gasoline Industrial Chemistry/Chemical Engineering Isomers Jet engine fuels Nanochemistry Nanotechnology and Microengineering Nuclear fuels Octane number Olefins Oligomerization Oligomers Original Article Phosphates Phosphoric acid Selectivity Silicon dioxide Sulfur Sulfur compounds Ultrasonic vibration Vapor phases X ray photoelectron spectroscopy Zeolites |
| title | High-quality fuel distillates produced from oligomerization of light olefin over supported phosphoric acid on H-Zeolite-Y |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T20%3A56%3A14IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_proqu&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=High-quality%20fuel%20distillates%20produced%20from%20oligomerization%20of%20light%20olefin%20over%20supported%20phosphoric%20acid%20on%20H-Zeolite-Y&rft.jtitle=Applied%20petrochemical%20research&rft.au=Al-Kinany,%20Mohammed%20C.&rft.date=2019-03-01&rft.volume=9&rft.issue=1&rft.spage=35&rft.epage=45&rft.pages=35-45&rft.issn=2190-5525&rft.eissn=2190-5525&rft_id=info:doi/10.1007/s13203-019-0225-1&rft_dat=%3Cgale_proqu%3EA582798245%3C/gale_proqu%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2201460441&rft_id=info:pmid/&rft_galeid=A582798245&rfr_iscdi=true |