Synthesis and Characterization of Transparent Conducting Film from Abaca Hybrid 7 Cellulose Acetate Blend and Polyaniline
This study dealt with the synthesis and characterization of thin transparent conducting films (TCF) from cellulose acetate (CA) blend and polyaniline (PANI). CA was produced from the pulp of abaca hybrid 7. CA-PANI films with different PANI loadings (0, 0.125, 0.25, 0.50, 1.0 and 2.0%) were produced...
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| Veröffentlicht in: | Key engineering materials 2018-08, Vol.775, p.50-56 |
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| creator | Maguyon-Detras, Monet Concepcion Herrera, Marvin U. Migo, Maria Victoria P. Manalo, Ronniel D. Lumbres, Lara Mae R. |
| description | This study dealt with the synthesis and characterization of thin transparent conducting films (TCF) from cellulose acetate (CA) blend and polyaniline (PANI). CA was produced from the pulp of abaca hybrid 7. CA-PANI films with different PANI loadings (0, 0.125, 0.25, 0.50, 1.0 and 2.0%) were produced using solvent casting method. Chemical transformations were analyzed using Fourier Transform Infrared (FTIR) spectroscopy. The conductivity was measured using the Four-Point Probe Test. Morphological characterization was done using Scanning Electron Microscopy (SEM). The transparency of the films was determined using UV-Vis Spectroscopy. FTIR spectra proved the embedment of PANI in the CA matrix. It was found that increasing the PANI loading increases the conductivity of the films but up to a certain limit. The highest average conductivity at 2.0264 x 10-5 S/m was observed in CA-PANI films with 0.50% PANI loading. SEM images revealed that conductivity is a function of PANI loading by forming networks. Further addition of PANI (1.0 and 2.0%) resulted to decreased conductivity due to agglomeration. Transparency, on the other hand, is negatively affected by PANI loading. |
| doi_str_mv | 10.4028/www.scientific.net/KEM.775.50 |
| format | Article |
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CA was produced from the pulp of abaca hybrid 7. CA-PANI films with different PANI loadings (0, 0.125, 0.25, 0.50, 1.0 and 2.0%) were produced using solvent casting method. Chemical transformations were analyzed using Fourier Transform Infrared (FTIR) spectroscopy. The conductivity was measured using the Four-Point Probe Test. Morphological characterization was done using Scanning Electron Microscopy (SEM). The transparency of the films was determined using UV-Vis Spectroscopy. FTIR spectra proved the embedment of PANI in the CA matrix. It was found that increasing the PANI loading increases the conductivity of the films but up to a certain limit. The highest average conductivity at 2.0264 x 10-5 S/m was observed in CA-PANI films with 0.50% PANI loading. SEM images revealed that conductivity is a function of PANI loading by forming networks. Further addition of PANI (1.0 and 2.0%) resulted to decreased conductivity due to agglomeration. Transparency, on the other hand, is negatively affected by PANI loading.</description><identifier>ISSN: 1013-9826</identifier><identifier>ISSN: 1662-9795</identifier><identifier>EISSN: 1662-9795</identifier><identifier>DOI: 10.4028/www.scientific.net/KEM.775.50</identifier><language>eng</language><publisher>Zurich: Trans Tech Publications Ltd</publisher><subject>Cellulose acetate ; Conductivity ; Fourier transforms ; Infrared analysis ; Infrared spectroscopy ; Morphology ; Organic chemistry ; Polyanilines ; Scanning electron microscopy ; Spectrum analysis ; Synthesis ; Thin films</subject><ispartof>Key engineering materials, 2018-08, Vol.775, p.50-56</ispartof><rights>2018 Trans Tech Publications Ltd</rights><rights>Copyright Trans Tech Publications Ltd. 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Transparency, on the other hand, is negatively affected by PANI loading.</description><subject>Cellulose acetate</subject><subject>Conductivity</subject><subject>Fourier transforms</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Morphology</subject><subject>Organic chemistry</subject><subject>Polyanilines</subject><subject>Scanning electron microscopy</subject><subject>Spectrum analysis</subject><subject>Synthesis</subject><subject>Thin films</subject><issn>1013-9826</issn><issn>1662-9795</issn><issn>1662-9795</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNqNkEtLxDAUhYso-PwPAXHZmqSvdCEyFl-oKDj7kCY3TqSTjEmGof56M4zg1tW9i3O-A1-WXRBcVJiyy81mUwRpwEajjSwsxMun25eibeuixnvZEWkamndtV--nH5My7xhtDrPjED4xLgkj9VE2vU82LiCYgIRVqF8IL2QEb75FNM4ip9HcCxtWwqcd1Dur1jIa-4HuzLhE2rslmg1CCvQwDd4o1KIexnE9ugBoJiGKCOhmhMTe8t_cOAlrRmPhNDvQYgxw9ntPsvnd7bx_yJ9f7x_72XMuacNwrmrMqoqUpeqGgXRDCQOjAgQFAkS2ugHG2EA0KKKaclBV3ZaaakZYRWvFypPsfIddefe1hhD5p1t7mxY5JV1HWoo7mlJXu5T0LgQPmq-8WQo_cYL5VjZPsvmfbJ5k8ySbJ9m8xql_vevHrawIcvE38z_CD4arkiE</recordid><startdate>20180801</startdate><enddate>20180801</enddate><creator>Maguyon-Detras, Monet Concepcion</creator><creator>Herrera, Marvin U.</creator><creator>Migo, Maria Victoria P.</creator><creator>Manalo, Ronniel D.</creator><creator>Lumbres, Lara Mae R.</creator><general>Trans Tech Publications Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20180801</creationdate><title>Synthesis and Characterization of Transparent Conducting Film from Abaca Hybrid 7 Cellulose Acetate Blend and Polyaniline</title><author>Maguyon-Detras, Monet Concepcion ; 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CA was produced from the pulp of abaca hybrid 7. CA-PANI films with different PANI loadings (0, 0.125, 0.25, 0.50, 1.0 and 2.0%) were produced using solvent casting method. Chemical transformations were analyzed using Fourier Transform Infrared (FTIR) spectroscopy. The conductivity was measured using the Four-Point Probe Test. Morphological characterization was done using Scanning Electron Microscopy (SEM). The transparency of the films was determined using UV-Vis Spectroscopy. FTIR spectra proved the embedment of PANI in the CA matrix. It was found that increasing the PANI loading increases the conductivity of the films but up to a certain limit. The highest average conductivity at 2.0264 x 10-5 S/m was observed in CA-PANI films with 0.50% PANI loading. SEM images revealed that conductivity is a function of PANI loading by forming networks. Further addition of PANI (1.0 and 2.0%) resulted to decreased conductivity due to agglomeration. 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| subjects | Cellulose acetate Conductivity Fourier transforms Infrared analysis Infrared spectroscopy Morphology Organic chemistry Polyanilines Scanning electron microscopy Spectrum analysis Synthesis Thin films |
| title | Synthesis and Characterization of Transparent Conducting Film from Abaca Hybrid 7 Cellulose Acetate Blend and Polyaniline |
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