A Ni-containing decaniobate incorporating organic ligands: synthesis, structure, and catalysis for allylic alcohol epoxidation

An organic–inorganic hybrid polyoxoniobate, Na 8 {Ni[Ni(en)] 2 Nb 10 O 32 }·28H 2 O ( 1 ) (en = ethanediamine), has been synthesized and characterized. It represents the first example of a trinuclear nickel-containing polyoxoniobate. The catalysis of 1 for allylic alcohol epoxidation was investigate...

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Veröffentlicht in:	RSC advances 2017, Vol.7 (46), p.28696-28701
Hauptverfasser:	Li, Li, Niu, Yanjun, Dong, Kaili, Ma, Pengtao, Zhang, Chao, Niu, Jingyang, Wang, Jingping
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Aqueous solutions Catalysis Chemical synthesis Crystallography Epoxidation Ferromagnetism Magnetic measurement Nickel Selectivity Tables
Online-Zugang:	Volltext
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