DC plasma electrolytic oxidation treatment of gum metal for dental implants

Vanadium- and aluminium-free biomedical Ti alloys are getting more and more attention because of the harmful character of these alloying elements. For this reason, it was proposed to substitute them with more biocompatible elements such as Ta, Nb and Zr. So-called gum metal alloys (Ti-Nb-Zr-Ta systems) belong to β-type Ti alloys which are characterized by excellent biocompatibility and possess the modulus of elasticity more closely related to that of a human bone. The present study aims at elucidating the process stages during DC plasma electrolytic oxidation (PEO) of gum metal (Ti-36Nb-3Zr-2Ta alloy) in calcium hypophosphite-based electrolyte system. The effect of the stages on the surface characteristics of the obtained oxide coatings was also determined. The coatings were characterized using SEM/EDS, XPS and contact angle measurements. It was found that the process comprised at least five different stages. The initiation of relatively strong B-type sparks in the third stage of the treatment was necessary to induce significant incorporation of electrolyte components into the oxide coatings. As the treatment continued beyond that point, the composition of the oxide films was getting more similar to that of hydroxyapatite as it was determined from the valence band XPS spectra. The surface morphology of the films was also closely related to the process stage at which the further growth of the oxide was halted. The composition of the electrolyte (regarding the salts used and their concentration) had a tremendous influence on the duration of the process stages and the surface characteristics of the obtained films. The process was also tested for its usefulness in coating gum metal dental implants in order to form bioactive interfaces. Keeping the voltage below a certain limit (before the onset of more powerful surface sparks) was crucial to obtaining good-quality coatings. [Display omitted] •Plasma electrolytic oxidation of β-type Ti-36Nb-3Zr-2Ta alloy was studied.•Ca(H2PO2)2-based solutions with the addition of Ca(HCOO)2 or Mg(CH3COO)2 were used.•Specific steps of the PEO and their effect on surface characteristic were analyzed.•Surface analysis was included SEM/EDS, XPS and contact angle measurements.•Dental implants fashioned from gum metal were also subjected to the PEO process.