Carbon-isotope stratigraphy of the uppermost Cambrian in eastern Laurentia: implications for global correlation

The δ13C profile from an interval of the Martin Point section in western Newfoundland (Canada) spans the upper Furongian (uppermost Cambrian). The interval (~90 m) is a part of the Green Point Formation of the Cow Head Group and consists of the Martin Point (lower) and the Broom Point (upper) member...

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description The δ13C profile from an interval of the Martin Point section in western Newfoundland (Canada) spans the upper Furongian (uppermost Cambrian). The interval (~90 m) is a part of the Green Point Formation of the Cow Head Group and consists of the Martin Point (lower) and the Broom Point (upper) members. It is formed of slope marine carbonates alternating with shales (rhythmites) and conglomeratic interbeds. The preservation of the investigated micritic carbonates was meticulously evaluated by multiple petrographic and geochemical screening tools. The δ13C and δ18O values (−0.5 ± 0.8 ‰VPDB and −7.1 ± 0.3 ‰VPDB, respectively) exhibit insignificant correlation (R2 = 0.002) and similarly the correlation of δ13C values with their Sr and Mn counterparts, which supports the preservation of at least near-primary δ13C signatures that can be utilized to construct a reliable high-resolution carbon-isotope profile for global correlations. The δ13C profile exhibits two main negative excursions, a lower broad excursion (~3 ‰) that reaches its maximum at ~70 m below the Martin Point / Broom Point members boundary and an upper narrow excursion (~2.5 ‰) immediately below the same boundary. The lower excursion can be correlated with the global latest Furongian HERB event (TOCE), which is also recognized in the C-isotope profile of the GSSP boundary section at Green Point whereas the upper excursion matches with that of the Cambrian‒Ordovician boundary in the same section. The peak of the HERB δ13C excursion is correlated with positive shifts on the Th/U and Ni profiles (redox and productivity proxies).
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The interval (~90 m) is a part of the Green Point Formation of the Cow Head Group and consists of the Martin Point (lower) and the Broom Point (upper) members. It is formed of slope marine carbonates alternating with shales (rhythmites) and conglomeratic interbeds. The preservation of the investigated micritic carbonates was meticulously evaluated by multiple petrographic and geochemical screening tools. The δ13C and δ18O values (−0.5 ± 0.8 ‰VPDB and −7.1 ± 0.3 ‰VPDB, respectively) exhibit insignificant correlation (R2 = 0.002) and similarly the correlation of δ13C values with their Sr and Mn counterparts, which supports the preservation of at least near-primary δ13C signatures that can be utilized to construct a reliable high-resolution carbon-isotope profile for global correlations. The δ13C profile exhibits two main negative excursions, a lower broad excursion (~3 ‰) that reaches its maximum at ~70 m below the Martin Point / Broom Point members boundary and an upper narrow excursion (~2.5 ‰) immediately below the same boundary. The lower excursion can be correlated with the global latest Furongian HERB event (TOCE), which is also recognized in the C-isotope profile of the GSSP boundary section at Green Point whereas the upper excursion matches with that of the Cambrian‒Ordovician boundary in the same section. The peak of the HERB δ13C excursion is correlated with positive shifts on the Th/U and Ni profiles (redox and productivity proxies).</description><identifier>ISSN: 0016-7568</identifier><identifier>EISSN: 1469-5081</identifier><identifier>DOI: 10.1017/S001675681800002X</identifier><language>eng</language><publisher>Cambridge, UK: Cambridge University Press</publisher><subject>allochthons ; alteration ; autochthons ; C-13/C-12 ; Cabot Fault ; Cambrian ; Canada ; Carbon ; carbonate rocks ; Carbonates ; chemostratigraphy ; clastic rocks ; Correlation ; Cow Head Group ; diagenesis ; Eastern Canada ; Furongian ; Geochemistry ; Geological time ; global ; Graptolithina ; Green Point Formation ; Hemichordata ; Herbs ; isotope ratios ; Isotopes ; Laurentia ; limestone ; lithostratigraphy ; Long Range Massif ; Manganese ; marine environment ; Martin Point Member ; mudstone ; Newfoundland ; Newfoundland and Labrador ; Ordovician ; Original Articles ; Oxidoreductions ; paleoenvironment ; Paleozoic ; Preservation ; Profiles ; Pterobranchia ; sedimentary rocks ; shale ; shelf environment ; siltstone ; stable isotopes ; Stratigraphy ; Th/U ; Upper Cambrian ; western Newfoundland</subject><ispartof>Geological magazine, 2019-05, Vol.156 (5), p.759-771</ispartof><rights>Copyright © Cambridge University Press 2018</rights><rights>GeoRef, Copyright 2020, American Geosciences Institute. 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Mag</addtitle><description>The δ13C profile from an interval of the Martin Point section in western Newfoundland (Canada) spans the upper Furongian (uppermost Cambrian). The interval (~90 m) is a part of the Green Point Formation of the Cow Head Group and consists of the Martin Point (lower) and the Broom Point (upper) members. It is formed of slope marine carbonates alternating with shales (rhythmites) and conglomeratic interbeds. The preservation of the investigated micritic carbonates was meticulously evaluated by multiple petrographic and geochemical screening tools. The δ13C and δ18O values (−0.5 ± 0.8 ‰VPDB and −7.1 ± 0.3 ‰VPDB, respectively) exhibit insignificant correlation (R2 = 0.002) and similarly the correlation of δ13C values with their Sr and Mn counterparts, which supports the preservation of at least near-primary δ13C signatures that can be utilized to construct a reliable high-resolution carbon-isotope profile for global correlations. The δ13C profile exhibits two main negative excursions, a lower broad excursion (~3 ‰) that reaches its maximum at ~70 m below the Martin Point / Broom Point members boundary and an upper narrow excursion (~2.5 ‰) immediately below the same boundary. The lower excursion can be correlated with the global latest Furongian HERB event (TOCE), which is also recognized in the C-isotope profile of the GSSP boundary section at Green Point whereas the upper excursion matches with that of the Cambrian‒Ordovician boundary in the same section. 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ratios</subject><subject>Isotopes</subject><subject>Laurentia</subject><subject>limestone</subject><subject>lithostratigraphy</subject><subject>Long Range Massif</subject><subject>Manganese</subject><subject>marine environment</subject><subject>Martin Point Member</subject><subject>mudstone</subject><subject>Newfoundland</subject><subject>Newfoundland and Labrador</subject><subject>Ordovician</subject><subject>Original Articles</subject><subject>Oxidoreductions</subject><subject>paleoenvironment</subject><subject>Paleozoic</subject><subject>Preservation</subject><subject>Profiles</subject><subject>Pterobranchia</subject><subject>sedimentary rocks</subject><subject>shale</subject><subject>shelf environment</subject><subject>siltstone</subject><subject>stable isotopes</subject><subject>Stratigraphy</subject><subject>Th/U</subject><subject>Upper Cambrian</subject><subject>western 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Mag</addtitle><date>2019-05</date><risdate>2019</risdate><volume>156</volume><issue>5</issue><spage>759</spage><epage>771</epage><pages>759-771</pages><issn>0016-7568</issn><eissn>1469-5081</eissn><abstract>The δ13C profile from an interval of the Martin Point section in western Newfoundland (Canada) spans the upper Furongian (uppermost Cambrian). The interval (~90 m) is a part of the Green Point Formation of the Cow Head Group and consists of the Martin Point (lower) and the Broom Point (upper) members. It is formed of slope marine carbonates alternating with shales (rhythmites) and conglomeratic interbeds. The preservation of the investigated micritic carbonates was meticulously evaluated by multiple petrographic and geochemical screening tools. The δ13C and δ18O values (−0.5 ± 0.8 ‰VPDB and −7.1 ± 0.3 ‰VPDB, respectively) exhibit insignificant correlation (R2 = 0.002) and similarly the correlation of δ13C values with their Sr and Mn counterparts, which supports the preservation of at least near-primary δ13C signatures that can be utilized to construct a reliable high-resolution carbon-isotope profile for global correlations. The δ13C profile exhibits two main negative excursions, a lower broad excursion (~3 ‰) that reaches its maximum at ~70 m below the Martin Point / Broom Point members boundary and an upper narrow excursion (~2.5 ‰) immediately below the same boundary. The lower excursion can be correlated with the global latest Furongian HERB event (TOCE), which is also recognized in the C-isotope profile of the GSSP boundary section at Green Point whereas the upper excursion matches with that of the Cambrian‒Ordovician boundary in the same section. The peak of the HERB δ13C excursion is correlated with positive shifts on the Th/U and Ni profiles (redox and productivity proxies).</abstract><cop>Cambridge, UK</cop><pub>Cambridge University Press</pub><doi>10.1017/S001675681800002X</doi><tpages>13</tpages></addata></record>
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source Cambridge Journals
subjects allochthons
alteration
autochthons
C-13/C-12
Cabot Fault
Cambrian
Canada
Carbon
carbonate rocks
Carbonates
chemostratigraphy
clastic rocks
Correlation
Cow Head Group
diagenesis
Eastern Canada
Furongian
Geochemistry
Geological time
global
Graptolithina
Green Point Formation
Hemichordata
Herbs
isotope ratios
Isotopes
Laurentia
limestone
lithostratigraphy
Long Range Massif
Manganese
marine environment
Martin Point Member
mudstone
Newfoundland
Newfoundland and Labrador
Ordovician
Original Articles
Oxidoreductions
paleoenvironment
Paleozoic
Preservation
Profiles
Pterobranchia
sedimentary rocks
shale
shelf environment
siltstone
stable isotopes
Stratigraphy
Th/U
Upper Cambrian
western Newfoundland
title Carbon-isotope stratigraphy of the uppermost Cambrian in eastern Laurentia: implications for global correlation
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