Li+ ion conductor based on NaBr doped with LiBH4
In this work, the guest Li+ conduction properties in NaBr–LiBH4 system were investigated. It was suggested that the guest Li+ ions occupy the Na+ sites and BH4− ions substitute the Br− ions in NaBr. The dominant Li+ conduction in NaBr–LiBH4 system was demonstrated by the combination of electrochemic...
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| Veröffentlicht in: | MRS communications 2019-03, Vol.9 (1), p.304-309 |
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| creator | Miyazaki, Reona Shomura, Masatoshi Miyagawa, Reina Hihara, Takehiko |
| description | In this work, the guest Li+ conduction properties in NaBr–LiBH4 system were investigated. It was suggested that the guest Li+ ions occupy the Na+ sites and BH4− ions substitute the Br− ions in NaBr. The dominant Li+ conduction in NaBr–LiBH4 system was demonstrated by the combination of electrochemical measurements and time-of-flight secondary ion mass spectrometry. The guest Li+ ion conductivity of 15NaBr·LiBH4 was measured to be 1 × 10−7 S/cm at 313 K. The present results indicate that the guest Li+ conductors are not restricted to the previous reported iodides (NaI, KI), but other Li-free compounds have the possibility to become the candidates for the guest Li+ ion conductors. |
| doi_str_mv | 10.1557/mrc.2018.225 |
| format | Article |
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It was suggested that the guest Li+ ions occupy the Na+ sites and BH4− ions substitute the Br− ions in NaBr. The dominant Li+ conduction in NaBr–LiBH4 system was demonstrated by the combination of electrochemical measurements and time-of-flight secondary ion mass spectrometry. The guest Li+ ion conductivity of 15NaBr·LiBH4 was measured to be 1 × 10−7 S/cm at 313 K. The present results indicate that the guest Li+ conductors are not restricted to the previous reported iodides (NaI, KI), but other Li-free compounds have the possibility to become the candidates for the guest Li+ ion conductors.</description><identifier>ISSN: 2159-6859</identifier><identifier>EISSN: 2159-6867</identifier><identifier>DOI: 10.1557/mrc.2018.225</identifier><language>eng</language><publisher>New York, USA: Cambridge University Press</publisher><subject>Biomaterials ; Characterization and Evaluation of Materials ; Conductivity ; Conductors ; Electrolytes ; Glass substrates ; Grain boundaries ; Iodides ; Ions ; Lithium ; Lithium ions ; Materials Engineering ; Materials Science ; Nanotechnology ; Polymer Sciences ; Research Letter ; Research Letters ; Secondary ion mass spectrometry ; Sodium bromides</subject><ispartof>MRS communications, 2019-03, Vol.9 (1), p.304-309</ispartof><rights>Copyright © Materials Research Society 2018</rights><rights>The Materials Research Society 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c270t-1f6079a8febd9a8218d1c0c41ccf82ef961ad46c78854a71899f71695483c1de3</citedby><cites>FETCH-LOGICAL-c270t-1f6079a8febd9a8218d1c0c41ccf82ef961ad46c78854a71899f71695483c1de3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1557/mrc.2018.225$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.cambridge.org/core/product/identifier/S2159685918002252/type/journal_article$$EHTML$$P50$$Gcambridge$$H</linktohtml><link.rule.ids>164,314,776,780,27901,27902,41464,42533,51294,55603</link.rule.ids></links><search><creatorcontrib>Miyazaki, Reona</creatorcontrib><creatorcontrib>Shomura, Masatoshi</creatorcontrib><creatorcontrib>Miyagawa, Reina</creatorcontrib><creatorcontrib>Hihara, Takehiko</creatorcontrib><title>Li+ ion conductor based on NaBr doped with LiBH4</title><title>MRS communications</title><addtitle>MRS Communications</addtitle><addtitle>MRC</addtitle><description>In this work, the guest Li+ conduction properties in NaBr–LiBH4 system were investigated. It was suggested that the guest Li+ ions occupy the Na+ sites and BH4− ions substitute the Br− ions in NaBr. The dominant Li+ conduction in NaBr–LiBH4 system was demonstrated by the combination of electrochemical measurements and time-of-flight secondary ion mass spectrometry. The guest Li+ ion conductivity of 15NaBr·LiBH4 was measured to be 1 × 10−7 S/cm at 313 K. The present results indicate that the guest Li+ conductors are not restricted to the previous reported iodides (NaI, KI), but other Li-free compounds have the possibility to become the candidates for the guest Li+ ion conductors.</description><subject>Biomaterials</subject><subject>Characterization and Evaluation of Materials</subject><subject>Conductivity</subject><subject>Conductors</subject><subject>Electrolytes</subject><subject>Glass substrates</subject><subject>Grain boundaries</subject><subject>Iodides</subject><subject>Ions</subject><subject>Lithium</subject><subject>Lithium ions</subject><subject>Materials Engineering</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Polymer Sciences</subject><subject>Research Letter</subject><subject>Research Letters</subject><subject>Secondary ion mass spectrometry</subject><subject>Sodium bromides</subject><issn>2159-6859</issn><issn>2159-6867</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNqFkE1LAzEQhoMoWGpv_oAFj7prJrv5OtpirbDoRc8hzUfdYjc12SL-e1Na9CTO5Z0ZnnkHXoQuAVdAKb_dRFMRDKIihJ6gEQEqSyYYP_3pqTxHk5TWOBdlhHM6Qrjtrosu9IUJvd2ZIcRiqZOzRV496WksbNjm6bMb3oq2my6aC3Tm9Xtyk6OO0ev8_mW2KNvnh8fZXVsawvFQgmeYSy28W9osBIQFg00DxnhBnJcMtG2Y4ULQRnMQUnoOTNJG1Aasq8fo6uC7jeFj59Kg1mEX-_xSEZA1NFDXPFM3B8rEkFJ0Xm1jt9HxSwFW-1hUjkXtY1E5loyXBzxlrF-5-Gv6B18d7fVmGTu7cv8cfAOvH3BY</recordid><startdate>20190301</startdate><enddate>20190301</enddate><creator>Miyazaki, Reona</creator><creator>Shomura, Masatoshi</creator><creator>Miyagawa, Reina</creator><creator>Hihara, Takehiko</creator><general>Cambridge University Press</general><general>Springer International Publishing</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8AO</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>S0W</scope></search><sort><creationdate>20190301</creationdate><title>Li+ ion conductor based on NaBr doped with LiBH4</title><author>Miyazaki, Reona ; Shomura, Masatoshi ; Miyagawa, Reina ; Hihara, Takehiko</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-1f6079a8febd9a8218d1c0c41ccf82ef961ad46c78854a71899f71695483c1de3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Biomaterials</topic><topic>Characterization and Evaluation of Materials</topic><topic>Conductivity</topic><topic>Conductors</topic><topic>Electrolytes</topic><topic>Glass substrates</topic><topic>Grain boundaries</topic><topic>Iodides</topic><topic>Ions</topic><topic>Lithium</topic><topic>Lithium ions</topic><topic>Materials Engineering</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Polymer Sciences</topic><topic>Research Letter</topic><topic>Research Letters</topic><topic>Secondary ion mass spectrometry</topic><topic>Sodium bromides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Miyazaki, Reona</creatorcontrib><creatorcontrib>Shomura, Masatoshi</creatorcontrib><creatorcontrib>Miyagawa, Reina</creatorcontrib><creatorcontrib>Hihara, Takehiko</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Pharma Collection</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection (ProQuest)</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>MRS communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Miyazaki, Reona</au><au>Shomura, Masatoshi</au><au>Miyagawa, Reina</au><au>Hihara, Takehiko</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Li+ ion conductor based on NaBr doped with LiBH4</atitle><jtitle>MRS communications</jtitle><stitle>MRS Communications</stitle><addtitle>MRC</addtitle><date>2019-03-01</date><risdate>2019</risdate><volume>9</volume><issue>1</issue><spage>304</spage><epage>309</epage><pages>304-309</pages><issn>2159-6859</issn><eissn>2159-6867</eissn><abstract>In this work, the guest Li+ conduction properties in NaBr–LiBH4 system were investigated. It was suggested that the guest Li+ ions occupy the Na+ sites and BH4− ions substitute the Br− ions in NaBr. The dominant Li+ conduction in NaBr–LiBH4 system was demonstrated by the combination of electrochemical measurements and time-of-flight secondary ion mass spectrometry. The guest Li+ ion conductivity of 15NaBr·LiBH4 was measured to be 1 × 10−7 S/cm at 313 K. The present results indicate that the guest Li+ conductors are not restricted to the previous reported iodides (NaI, KI), but other Li-free compounds have the possibility to become the candidates for the guest Li+ ion conductors.</abstract><cop>New York, USA</cop><pub>Cambridge University Press</pub><doi>10.1557/mrc.2018.225</doi><tpages>6</tpages></addata></record> |
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| ispartof | MRS communications, 2019-03, Vol.9 (1), p.304-309 |
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| language | eng |
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| source | SpringerLink Journals; Cambridge University Press Journals Complete |
| subjects | Biomaterials Characterization and Evaluation of Materials Conductivity Conductors Electrolytes Glass substrates Grain boundaries Iodides Ions Lithium Lithium ions Materials Engineering Materials Science Nanotechnology Polymer Sciences Research Letter Research Letters Secondary ion mass spectrometry Sodium bromides |
| title | Li+ ion conductor based on NaBr doped with LiBH4 |
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