Flexible NiCo2O4@carbon/carbon nanofiber electrodes fabricated by a combined electrospray/electrospinning technique for supercapacitors

[Display omitted] •The NiCo2O4@C/CNFs was fabricated by a combined electrospray/electrospinning method.•The core-shell NiCo2O4@C clusters were trapped in the carbon nanofiber net.•The specific capacitance reaches 1586 Fg−1 at 1 Ag−1 and 806 Fg−1 even at 32 Ag−1.•The capacitance retention achieves 92...

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Veröffentlicht in:Materials letters 2019-04, Vol.240, p.21-24
Hauptverfasser: Chang, Liyuan, Li, Cuiyan, Ouyang, Haibo, Huang, Jianfeng, Huang, Qigao, Xu, Zhao
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container_end_page 24
container_issue
container_start_page 21
container_title Materials letters
container_volume 240
creator Chang, Liyuan
Li, Cuiyan
Ouyang, Haibo
Huang, Jianfeng
Huang, Qigao
Xu, Zhao
description [Display omitted] •The NiCo2O4@C/CNFs was fabricated by a combined electrospray/electrospinning method.•The core-shell NiCo2O4@C clusters were trapped in the carbon nanofiber net.•The specific capacitance reaches 1586 Fg−1 at 1 Ag−1 and 806 Fg−1 even at 32 Ag−1.•The capacitance retention achieves 92.5% after 5000 charge-discharge cycles. A flexible NiCo2O4@Carbon/Carbon nanofiber (NiCo2O4@C/CNFs) composite was fabricated by the combined electrospray/electrospinning technique. The NiCo2O4 clusters were coated with an amorphous carbon layer to form NiCo2O4@C core-shell structure and homogeneously trapped in the CNFs net. The NiCo2O4@C/CNFs electrodes exhibited a high specific capacitance (1586 Fg−1 at 1 Ag−1), good rate performance (51% retention even at 32 Ag−1), and superior cycling life (92.5% capacitance retention after 5000 cycles at 10 Ag−1). The combined electrospray/electrospinning technique is a promising method to produce flexible electrodes with enhanced performance.
doi_str_mv 10.1016/j.matlet.2018.12.062
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A flexible NiCo2O4@Carbon/Carbon nanofiber (NiCo2O4@C/CNFs) composite was fabricated by the combined electrospray/electrospinning technique. The NiCo2O4 clusters were coated with an amorphous carbon layer to form NiCo2O4@C core-shell structure and homogeneously trapped in the CNFs net. The NiCo2O4@C/CNFs electrodes exhibited a high specific capacitance (1586 Fg−1 at 1 Ag−1), good rate performance (51% retention even at 32 Ag−1), and superior cycling life (92.5% capacitance retention after 5000 cycles at 10 Ag−1). 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A flexible NiCo2O4@Carbon/Carbon nanofiber (NiCo2O4@C/CNFs) composite was fabricated by the combined electrospray/electrospinning technique. The NiCo2O4 clusters were coated with an amorphous carbon layer to form NiCo2O4@C core-shell structure and homogeneously trapped in the CNFs net. The NiCo2O4@C/CNFs electrodes exhibited a high specific capacitance (1586 Fg−1 at 1 Ag−1), good rate performance (51% retention even at 32 Ag−1), and superior cycling life (92.5% capacitance retention after 5000 cycles at 10 Ag−1). 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A flexible NiCo2O4@Carbon/Carbon nanofiber (NiCo2O4@C/CNFs) composite was fabricated by the combined electrospray/electrospinning technique. The NiCo2O4 clusters were coated with an amorphous carbon layer to form NiCo2O4@C core-shell structure and homogeneously trapped in the CNFs net. The NiCo2O4@C/CNFs electrodes exhibited a high specific capacitance (1586 Fg−1 at 1 Ag−1), good rate performance (51% retention even at 32 Ag−1), and superior cycling life (92.5% capacitance retention after 5000 cycles at 10 Ag−1). The combined electrospray/electrospinning technique is a promising method to produce flexible electrodes with enhanced performance.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.matlet.2018.12.062</doi><tpages>4</tpages></addata></record>
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subjects Capacitance
Carbon fibers
Core-shell structure
Electrodes
Electrospinning
Electrospraying
Energy storage and conversion
Materials science
Nanocomposites
Nanofibers
Nickel compounds
NiCo2O4
Performance enhancement
Supercapacitors
title Flexible NiCo2O4@carbon/carbon nanofiber electrodes fabricated by a combined electrospray/electrospinning technique for supercapacitors
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