Structure and microwave dielectric behaviour of low-temperature-fired Li2Zn1−xCoxTi3O8 (x = 0–0.07) ceramics for low temperature co-fired ceramic applications
Low-temperature-fired Li 2 Zn 1−x Co x Ti 3 O 8 (x = 0, 0.03, 0.04, 0.05, 0.06, 0.07) ceramics with 1.5 wt% Li 2 O–B 2 O 3 –SiO 2 –CaO–Al 2 O 3 (LBSCA) glass as sintering aid were attained through a traditional solid-state-reaction method, and the relationship between their structures and microwave...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2019-04, Vol.30 (8), p.7711-7716 |
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| creator | Jing, Xiaolin Su, Hua Jing, Yulan Li, Yuanxun Tang, Xiaoli |
| description | Low-temperature-fired Li
2
Zn
1−x
Co
x
Ti
3
O
8
(x = 0, 0.03, 0.04, 0.05, 0.06, 0.07) ceramics with 1.5 wt% Li
2
O–B
2
O
3
–SiO
2
–CaO–Al
2
O
3
(LBSCA) glass as sintering aid were attained through a traditional solid-state-reaction method, and the relationship between their structures and microwave dielectric properties were thoroughly investigated. X-ray diffraction patterns revealed that the solid solutions composed of Li
2
ZnTi
3
O
8
and Li
2
CoTi
3
O
8
were produced. The main peaks were identified with the cubic spinel phase of the Li
2
(Zn,Co)Ti
3
O
8
. Co substitution successfully lowered the sintering temperature of Li
2
ZnTi
3
O
8
to approximately 900 °C and accelerated its densification when LBSCA glass was used as the sintering aid. The cobalt content considerably influenced grain homogeneity, grain size and dielectric polarizability, as well as the variation in relative permittivity (ε
r
) and quality factor (
Q
×
f
). When x = 0.04, Li
2
Zn
0.96
Co
0.04
Ti
3
O
8
ceramic sintered at 900 °C had the most uniform grain size and exhibited optimum microwave dielectric properties, having a relative permittivity of 21.61,
Q
×
f
of 79,100 GHz and temperature coefficient of resonance frequency (τ
f
) of − 12.3 ppm/°C. Thus, it showed potential for low temperature co-fired ceramic applications. |
| doi_str_mv | 10.1007/s10854-019-01087-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2190269644</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2190269644</sourcerecordid><originalsourceid>FETCH-LOGICAL-c249t-b03eb828ee8cce29677960e0978cbd2df0090e113941e5683a30f28fad66590c3</originalsourceid><addsrcrecordid>eNp9kb9uUzEUhy1UJNLCCzBZYqGD22P7_rEHhioqpVKkDAQJsViO77ngKrm-2Ddp2DqWtbxDHyxPgkMilanDkZff9x35_Ah5y-GMA9TniYMqCwZc5wFVs_IFGfGylqxQ4usRGYEua1aUQrwixyndAEBVSDUij5-HuHLDKiK1XUOX3sVwa9dIG48LdEP0js7xh137sIo0tHQRbtmAyx6j3VGs9REbOvHiW8e39w-bcdjMvJwq-n6zvfv9IQ9s7_7AGdSn1GUob0i0DXEnov-JqAsH1yFFbd8vvLODD116TV62dpHwzeE9IV8-Xs7Gn9hkenU9vpgwJwo9sDlInCuhEJVzKHRV17oCBF0rN29E0wJoQM6lLjiWlZJWQitUa5uqKjU4eULe7b19DD9XmAZzk__d5ZVGcA2i0lVR5JTYp_KxUorYmj76pY2_DAez68Ps-zC5D_OvD1NmSO6hlMPdd4xP6meovxAbkyE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2190269644</pqid></control><display><type>article</type><title>Structure and microwave dielectric behaviour of low-temperature-fired Li2Zn1−xCoxTi3O8 (x = 0–0.07) ceramics for low temperature co-fired ceramic applications</title><source>SpringerLink Journals - AutoHoldings</source><creator>Jing, Xiaolin ; Su, Hua ; Jing, Yulan ; Li, Yuanxun ; Tang, Xiaoli</creator><creatorcontrib>Jing, Xiaolin ; Su, Hua ; Jing, Yulan ; Li, Yuanxun ; Tang, Xiaoli</creatorcontrib><description>Low-temperature-fired Li
2
Zn
1−x
Co
x
Ti
3
O
8
(x = 0, 0.03, 0.04, 0.05, 0.06, 0.07) ceramics with 1.5 wt% Li
2
O–B
2
O
3
–SiO
2
–CaO–Al
2
O
3
(LBSCA) glass as sintering aid were attained through a traditional solid-state-reaction method, and the relationship between their structures and microwave dielectric properties were thoroughly investigated. X-ray diffraction patterns revealed that the solid solutions composed of Li
2
ZnTi
3
O
8
and Li
2
CoTi
3
O
8
were produced. The main peaks were identified with the cubic spinel phase of the Li
2
(Zn,Co)Ti
3
O
8
. Co substitution successfully lowered the sintering temperature of Li
2
ZnTi
3
O
8
to approximately 900 °C and accelerated its densification when LBSCA glass was used as the sintering aid. The cobalt content considerably influenced grain homogeneity, grain size and dielectric polarizability, as well as the variation in relative permittivity (ε
r
) and quality factor (
Q
×
f
). When x = 0.04, Li
2
Zn
0.96
Co
0.04
Ti
3
O
8
ceramic sintered at 900 °C had the most uniform grain size and exhibited optimum microwave dielectric properties, having a relative permittivity of 21.61,
Q
×
f
of 79,100 GHz and temperature coefficient of resonance frequency (τ
f
) of − 12.3 ppm/°C. Thus, it showed potential for low temperature co-fired ceramic applications.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-019-01087-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aluminum oxide ; Boron oxides ; Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Densification ; Dielectric properties ; Diffraction patterns ; Glass ; Grain size ; Lithium oxides ; Low temperature ; Materials Science ; Optical and Electronic Materials ; Permittivity ; Q factors ; Silicon dioxide ; Sintering ; Solid solutions ; Substitution reactions ; X-ray diffraction</subject><ispartof>Journal of materials science. Materials in electronics, 2019-04, Vol.30 (8), p.7711-7716</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Journal of Materials Science: Materials in Electronics is a copyright of Springer, (2019). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-b03eb828ee8cce29677960e0978cbd2df0090e113941e5683a30f28fad66590c3</citedby><cites>FETCH-LOGICAL-c249t-b03eb828ee8cce29677960e0978cbd2df0090e113941e5683a30f28fad66590c3</cites><orcidid>0000-0002-6951-9252</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-019-01087-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-019-01087-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Jing, Xiaolin</creatorcontrib><creatorcontrib>Su, Hua</creatorcontrib><creatorcontrib>Jing, Yulan</creatorcontrib><creatorcontrib>Li, Yuanxun</creatorcontrib><creatorcontrib>Tang, Xiaoli</creatorcontrib><title>Structure and microwave dielectric behaviour of low-temperature-fired Li2Zn1−xCoxTi3O8 (x = 0–0.07) ceramics for low temperature co-fired ceramic applications</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>Low-temperature-fired Li
2
Zn
1−x
Co
x
Ti
3
O
8
(x = 0, 0.03, 0.04, 0.05, 0.06, 0.07) ceramics with 1.5 wt% Li
2
O–B
2
O
3
–SiO
2
–CaO–Al
2
O
3
(LBSCA) glass as sintering aid were attained through a traditional solid-state-reaction method, and the relationship between their structures and microwave dielectric properties were thoroughly investigated. X-ray diffraction patterns revealed that the solid solutions composed of Li
2
ZnTi
3
O
8
and Li
2
CoTi
3
O
8
were produced. The main peaks were identified with the cubic spinel phase of the Li
2
(Zn,Co)Ti
3
O
8
. Co substitution successfully lowered the sintering temperature of Li
2
ZnTi
3
O
8
to approximately 900 °C and accelerated its densification when LBSCA glass was used as the sintering aid. The cobalt content considerably influenced grain homogeneity, grain size and dielectric polarizability, as well as the variation in relative permittivity (ε
r
) and quality factor (
Q
×
f
). When x = 0.04, Li
2
Zn
0.96
Co
0.04
Ti
3
O
8
ceramic sintered at 900 °C had the most uniform grain size and exhibited optimum microwave dielectric properties, having a relative permittivity of 21.61,
Q
×
f
of 79,100 GHz and temperature coefficient of resonance frequency (τ
f
) of − 12.3 ppm/°C. Thus, it showed potential for low temperature co-fired ceramic applications.</description><subject>Aluminum oxide</subject><subject>Boron oxides</subject><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Densification</subject><subject>Dielectric properties</subject><subject>Diffraction patterns</subject><subject>Glass</subject><subject>Grain size</subject><subject>Lithium oxides</subject><subject>Low temperature</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Permittivity</subject><subject>Q factors</subject><subject>Silicon dioxide</subject><subject>Sintering</subject><subject>Solid solutions</subject><subject>Substitution reactions</subject><subject>X-ray diffraction</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kb9uUzEUhy1UJNLCCzBZYqGD22P7_rEHhioqpVKkDAQJsViO77ngKrm-2Ddp2DqWtbxDHyxPgkMilanDkZff9x35_Ah5y-GMA9TniYMqCwZc5wFVs_IFGfGylqxQ4usRGYEua1aUQrwixyndAEBVSDUij5-HuHLDKiK1XUOX3sVwa9dIG48LdEP0js7xh137sIo0tHQRbtmAyx6j3VGs9REbOvHiW8e39w-bcdjMvJwq-n6zvfv9IQ9s7_7AGdSn1GUob0i0DXEnov-JqAsH1yFFbd8vvLODD116TV62dpHwzeE9IV8-Xs7Gn9hkenU9vpgwJwo9sDlInCuhEJVzKHRV17oCBF0rN29E0wJoQM6lLjiWlZJWQitUa5uqKjU4eULe7b19DD9XmAZzk__d5ZVGcA2i0lVR5JTYp_KxUorYmj76pY2_DAez68Ps-zC5D_OvD1NmSO6hlMPdd4xP6meovxAbkyE</recordid><startdate>20190401</startdate><enddate>20190401</enddate><creator>Jing, Xiaolin</creator><creator>Su, Hua</creator><creator>Jing, Yulan</creator><creator>Li, Yuanxun</creator><creator>Tang, Xiaoli</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>L7M</scope><scope>P5Z</scope><scope>P62</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>S0W</scope><orcidid>https://orcid.org/0000-0002-6951-9252</orcidid></search><sort><creationdate>20190401</creationdate><title>Structure and microwave dielectric behaviour of low-temperature-fired Li2Zn1−xCoxTi3O8 (x = 0–0.07) ceramics for low temperature co-fired ceramic applications</title><author>Jing, Xiaolin ; Su, Hua ; Jing, Yulan ; Li, Yuanxun ; Tang, Xiaoli</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-b03eb828ee8cce29677960e0978cbd2df0090e113941e5683a30f28fad66590c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aluminum oxide</topic><topic>Boron oxides</topic><topic>Ceramics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Densification</topic><topic>Dielectric properties</topic><topic>Diffraction patterns</topic><topic>Glass</topic><topic>Grain size</topic><topic>Lithium oxides</topic><topic>Low temperature</topic><topic>Materials Science</topic><topic>Optical and Electronic Materials</topic><topic>Permittivity</topic><topic>Q factors</topic><topic>Silicon dioxide</topic><topic>Sintering</topic><topic>Solid solutions</topic><topic>Substitution reactions</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jing, Xiaolin</creatorcontrib><creatorcontrib>Su, Hua</creatorcontrib><creatorcontrib>Jing, Yulan</creatorcontrib><creatorcontrib>Li, Yuanxun</creatorcontrib><creatorcontrib>Tang, Xiaoli</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jing, Xiaolin</au><au>Su, Hua</au><au>Jing, Yulan</au><au>Li, Yuanxun</au><au>Tang, Xiaoli</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure and microwave dielectric behaviour of low-temperature-fired Li2Zn1−xCoxTi3O8 (x = 0–0.07) ceramics for low temperature co-fired ceramic applications</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2019-04-01</date><risdate>2019</risdate><volume>30</volume><issue>8</issue><spage>7711</spage><epage>7716</epage><pages>7711-7716</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>Low-temperature-fired Li
2
Zn
1−x
Co
x
Ti
3
O
8
(x = 0, 0.03, 0.04, 0.05, 0.06, 0.07) ceramics with 1.5 wt% Li
2
O–B
2
O
3
–SiO
2
–CaO–Al
2
O
3
(LBSCA) glass as sintering aid were attained through a traditional solid-state-reaction method, and the relationship between their structures and microwave dielectric properties were thoroughly investigated. X-ray diffraction patterns revealed that the solid solutions composed of Li
2
ZnTi
3
O
8
and Li
2
CoTi
3
O
8
were produced. The main peaks were identified with the cubic spinel phase of the Li
2
(Zn,Co)Ti
3
O
8
. Co substitution successfully lowered the sintering temperature of Li
2
ZnTi
3
O
8
to approximately 900 °C and accelerated its densification when LBSCA glass was used as the sintering aid. The cobalt content considerably influenced grain homogeneity, grain size and dielectric polarizability, as well as the variation in relative permittivity (ε
r
) and quality factor (
Q
×
f
). When x = 0.04, Li
2
Zn
0.96
Co
0.04
Ti
3
O
8
ceramic sintered at 900 °C had the most uniform grain size and exhibited optimum microwave dielectric properties, having a relative permittivity of 21.61,
Q
×
f
of 79,100 GHz and temperature coefficient of resonance frequency (τ
f
) of − 12.3 ppm/°C. Thus, it showed potential for low temperature co-fired ceramic applications.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-019-01087-5</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-6951-9252</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0957-4522 |
| ispartof | Journal of materials science. Materials in electronics, 2019-04, Vol.30 (8), p.7711-7716 |
| issn | 0957-4522 1573-482X |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Aluminum oxide Boron oxides Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Densification Dielectric properties Diffraction patterns Glass Grain size Lithium oxides Low temperature Materials Science Optical and Electronic Materials Permittivity Q factors Silicon dioxide Sintering Solid solutions Substitution reactions X-ray diffraction |
| title | Structure and microwave dielectric behaviour of low-temperature-fired Li2Zn1−xCoxTi3O8 (x = 0–0.07) ceramics for low temperature co-fired ceramic applications |
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