An XPS Study of the Interaction of a Palladium Foil with NO2
The interaction of a palladium foil with nitrogen dioxide in a temperature range of 30–450°C at three NO 2 pressures of 10 –6 , 10 –5 , and 10 –4 mbar was studied by X-ray photoelectron spectroscopy (XPS). In all cases, a three-dimensional oxide film was formed on the surface of palladium metal star...
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| Veröffentlicht in: | Kinetics and catalysis 2018-11, Vol.59 (6), p.786-791 |
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| container_title | Kinetics and catalysis |
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| creator | Smirnov, M. Yu Klembovskii, I. O. Kalinkin, A. V. Bukhtiyarov, V. I. |
| description | The interaction of a palladium foil with nitrogen dioxide in a temperature range of 30–450°C at three NO
2
pressures of 10
–6
, 10
–5
, and 10
–4
mbar was studied by X-ray photoelectron spectroscopy (XPS). In all cases, a three-dimensional oxide film was formed on the surface of palladium metal starting with a temperature of 150°C. Based on the measurements of the Pd 3
d
5/2
, Pd 3
p
3/2
, and O 1
s
binding energies and the [Pd] : [O] atomic ratio, it was found that the film consisted of the palladium oxide PdO. The oxide film thickness
d
was estimated based on the weakening of the Pd 3
d
line of metallic palladium. As the interaction temperature was increased,
d
initially increased to reach a maximum of ~3.5–5 nm; thereafter, it began to decrease due to the decomposition of PdO to a metallic state. |
| doi_str_mv | 10.1134/S0023158418060150 |
| format | Article |
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2
pressures of 10
–6
, 10
–5
, and 10
–4
mbar was studied by X-ray photoelectron spectroscopy (XPS). In all cases, a three-dimensional oxide film was formed on the surface of palladium metal starting with a temperature of 150°C. Based on the measurements of the Pd 3
d
5/2
, Pd 3
p
3/2
, and O 1
s
binding energies and the [Pd] : [O] atomic ratio, it was found that the film consisted of the palladium oxide PdO. The oxide film thickness
d
was estimated based on the weakening of the Pd 3
d
line of metallic palladium. As the interaction temperature was increased,
d
initially increased to reach a maximum of ~3.5–5 nm; thereafter, it began to decrease due to the decomposition of PdO to a metallic state.</description><identifier>ISSN: 0023-1584</identifier><identifier>EISSN: 1608-3210</identifier><identifier>DOI: 10.1134/S0023158418060150</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Catalysis ; Chemistry ; Chemistry and Materials Science ; Film thickness ; Foils ; Nitrogen dioxide ; Oxide coatings ; Palladium ; Photoelectrons ; Physical Chemistry ; X ray photoelectron spectroscopy</subject><ispartof>Kinetics and catalysis, 2018-11, Vol.59 (6), p.786-791</ispartof><rights>Pleiades Publishing, Ltd. 2018</rights><rights>Copyright Springer Nature B.V. 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-fd683280aeb0c9e12314ba46186f779ac69b22df3f9a0d487be074f9f81e7daa3</citedby><cites>FETCH-LOGICAL-c337t-fd683280aeb0c9e12314ba46186f779ac69b22df3f9a0d487be074f9f81e7daa3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0023158418060150$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0023158418060150$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Smirnov, M. Yu</creatorcontrib><creatorcontrib>Klembovskii, I. O.</creatorcontrib><creatorcontrib>Kalinkin, A. V.</creatorcontrib><creatorcontrib>Bukhtiyarov, V. I.</creatorcontrib><title>An XPS Study of the Interaction of a Palladium Foil with NO2</title><title>Kinetics and catalysis</title><addtitle>Kinet Catal</addtitle><description>The interaction of a palladium foil with nitrogen dioxide in a temperature range of 30–450°C at three NO
2
pressures of 10
–6
, 10
–5
, and 10
–4
mbar was studied by X-ray photoelectron spectroscopy (XPS). In all cases, a three-dimensional oxide film was formed on the surface of palladium metal starting with a temperature of 150°C. Based on the measurements of the Pd 3
d
5/2
, Pd 3
p
3/2
, and O 1
s
binding energies and the [Pd] : [O] atomic ratio, it was found that the film consisted of the palladium oxide PdO. The oxide film thickness
d
was estimated based on the weakening of the Pd 3
d
line of metallic palladium. As the interaction temperature was increased,
d
initially increased to reach a maximum of ~3.5–5 nm; thereafter, it began to decrease due to the decomposition of PdO to a metallic state.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Film thickness</subject><subject>Foils</subject><subject>Nitrogen dioxide</subject><subject>Oxide coatings</subject><subject>Palladium</subject><subject>Photoelectrons</subject><subject>Physical Chemistry</subject><subject>X ray photoelectron spectroscopy</subject><issn>0023-1584</issn><issn>1608-3210</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kFFLwzAUhYMoOKc_wLeAz9V7k7RJwZcx3BwMN5iCbyVtE9fRtTNJkf17Wyb4ID5duOc7514OIbcI94hcPGwAGMdYCVSQAMZwRkaYgIo4Qzgno0GOBv2SXHm_AwCBIh2Rx0lD39cbugldeaStpWFr6KIJxukiVG0zrDRd67rWZdXt6aytavpVhS19WbFrcmF17c3NzxyTt9nT6_Q5Wq7mi-lkGRWcyxDZMlGcKdAmhyI12D8qci0SVImVMtVFkuaMlZbbVEMplMwNSGFTq9DIUms-Jnen3INrPzvjQ7ZrO9f0JzOGSqYyBh73FJ6owrXeO2Ozg6v22h0zhGwoKftTUu9hJ4_v2ebDuN_k_03fXbll0Q</recordid><startdate>20181101</startdate><enddate>20181101</enddate><creator>Smirnov, M. Yu</creator><creator>Klembovskii, I. O.</creator><creator>Kalinkin, A. V.</creator><creator>Bukhtiyarov, V. I.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20181101</creationdate><title>An XPS Study of the Interaction of a Palladium Foil with NO2</title><author>Smirnov, M. Yu ; Klembovskii, I. O. ; Kalinkin, A. V. ; Bukhtiyarov, V. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-fd683280aeb0c9e12314ba46186f779ac69b22df3f9a0d487be074f9f81e7daa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Film thickness</topic><topic>Foils</topic><topic>Nitrogen dioxide</topic><topic>Oxide coatings</topic><topic>Palladium</topic><topic>Photoelectrons</topic><topic>Physical Chemistry</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Smirnov, M. Yu</creatorcontrib><creatorcontrib>Klembovskii, I. O.</creatorcontrib><creatorcontrib>Kalinkin, A. V.</creatorcontrib><creatorcontrib>Bukhtiyarov, V. I.</creatorcontrib><collection>CrossRef</collection><jtitle>Kinetics and catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Smirnov, M. Yu</au><au>Klembovskii, I. O.</au><au>Kalinkin, A. V.</au><au>Bukhtiyarov, V. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An XPS Study of the Interaction of a Palladium Foil with NO2</atitle><jtitle>Kinetics and catalysis</jtitle><stitle>Kinet Catal</stitle><date>2018-11-01</date><risdate>2018</risdate><volume>59</volume><issue>6</issue><spage>786</spage><epage>791</epage><pages>786-791</pages><issn>0023-1584</issn><eissn>1608-3210</eissn><abstract>The interaction of a palladium foil with nitrogen dioxide in a temperature range of 30–450°C at three NO
2
pressures of 10
–6
, 10
–5
, and 10
–4
mbar was studied by X-ray photoelectron spectroscopy (XPS). In all cases, a three-dimensional oxide film was formed on the surface of palladium metal starting with a temperature of 150°C. Based on the measurements of the Pd 3
d
5/2
, Pd 3
p
3/2
, and O 1
s
binding energies and the [Pd] : [O] atomic ratio, it was found that the film consisted of the palladium oxide PdO. The oxide film thickness
d
was estimated based on the weakening of the Pd 3
d
line of metallic palladium. As the interaction temperature was increased,
d
initially increased to reach a maximum of ~3.5–5 nm; thereafter, it began to decrease due to the decomposition of PdO to a metallic state.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0023158418060150</doi><tpages>6</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| ispartof | Kinetics and catalysis, 2018-11, Vol.59 (6), p.786-791 |
| issn | 0023-1584 1608-3210 |
| language | eng |
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| source | SpringerNature Complete Journals |
| subjects | Catalysis Chemistry Chemistry and Materials Science Film thickness Foils Nitrogen dioxide Oxide coatings Palladium Photoelectrons Physical Chemistry X ray photoelectron spectroscopy |
| title | An XPS Study of the Interaction of a Palladium Foil with NO2 |
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