RhIAr/AuIAr′ Transmetalation: A Case of Group Exchange Pivoting on the Formation of M−M′ Bonds through Oxidative Insertion

By combining kinetic experiments, theoretical calculations, and microkinetic modeling, we show that Pf/Rf (C6F5/C6Cl2F3) exchange between [AuPf(AsPh3)] and trans‐[RhRf(CO)(AsPh3)2] does not occur by typical concerted Pf/Rf transmetalation via electron‐deficient double bridges. Instead, it involves a...

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Veröffentlicht in:	Angewandte Chemie International Edition 2019-03, Vol.58 (11), p.3501-3505
Hauptverfasser:	Peñas‐Defrutos, Marconi N., Bartolomé, Camino, García‐Melchor, Max, Espinet, Pablo
Format:	Artikel
Sprache:	eng
Schlagworte:	bimetallic catalysis density functional calculations Exchanging gold Insertion Isomerization oxidative addition rhodium
Online-Zugang:	Volltext
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