Methane, ethane and propane detection using a compact quartz enhanced photoacoustic sensor and a single interband cascade laser

•We realized a quartz-enhanced photoacoustic (QEPAS) sensor for methane, ethane and propane detection using a single intercascade laser source.•We achieved for ethane a QEPAS record sensitivity of 7 ppb in 1-second integration time.•Detection of propane with QEPAS technique is reported for the first...

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Veröffentlicht in:Sensors and actuators. B, Chemical Chemical, 2019-03, Vol.282, p.952-960
Hauptverfasser: Sampaolo, Angelo, Csutak, Sebastian, Patimisco, Pietro, Giglio, Marilena, Menduni, Giansergio, Passaro, Vittorio, Tittel, Frank K., Deffenbaugh, Max, Spagnolo, Vincenzo
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container_issue
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container_title Sensors and actuators. B, Chemical
container_volume 282
creator Sampaolo, Angelo
Csutak, Sebastian
Patimisco, Pietro
Giglio, Marilena
Menduni, Giansergio
Passaro, Vittorio
Tittel, Frank K.
Deffenbaugh, Max
Spagnolo, Vincenzo
description •We realized a quartz-enhanced photoacoustic (QEPAS) sensor for methane, ethane and propane detection using a single intercascade laser source.•We achieved for ethane a QEPAS record sensitivity of 7 ppb in 1-second integration time.•Detection of propane with QEPAS technique is reported for the first time.•We demonstrated methane, ethane and propane detection at atmospheric pressure avoiding the use of pump and pressure controller systems. Hydrocarbon detection in the gas phase represents a powerful tool to guide oil exploration and production operations for the oil & gas industry. This application requires highly sensitive, selective and robust spectroscopic techniques. In this work, a quartz-enhanced photoacoustic sensor system designed to detect methane (C1), ethane (C2) and propane (C3), employing a single interband cascade laser emitting in the spectral range 3.342–3.349 μm, is reported. Detection levels in the part-per billion concentration range for C1 and C2 and a few parts per million for C3 were achieved. Measurements at both low and atmospheric pressures were carried out for mixtures simulating typical downhole hydrocarbon concentrations.
doi_str_mv 10.1016/j.snb.2018.11.132
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subjects Cascade laser
Cascade lasers
Ethane
Gas sensing
Hydrocarbons
Interband
Methane
Oil exploration
Propane
Quartz
Quartz-enhanced photoacoustic spectroscopy
Spectral emittance
Vapor phases
title Methane, ethane and propane detection using a compact quartz enhanced photoacoustic sensor and a single interband cascade laser
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