Study of the Process of Reversible Insertion of Lithium into Nanostructured Materials Based on Germanium
Nanostructured germanium samples prepared by electrochemical deposition from aqueous solution of 0.05 М germanium oxide onto titanium substrate are tested as the negative electrodes of lithium-ion batteries. The reversible capacity in the process of lithium insertion-extraction is found to be about...
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| Veröffentlicht in: | Russian journal of electrochemistry 2018-12, Vol.54 (12), p.1111-1116 |
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| container_title | Russian journal of electrochemistry |
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| creator | Gavrilin, I. M. Smolyaninov, V. A. Dronov, A. A. Gavrilov, S. A. Trifonov, A. Yu Kulova, T. L. Kuz’mina, A. A. Skundin, A. M. |
| description | Nanostructured germanium samples prepared by electrochemical deposition from aqueous solution of 0.05 М germanium oxide onto titanium substrate are tested as the negative electrodes of lithium-ion batteries. The reversible capacity in the process of lithium insertion-extraction is found to be about 1180 mA h/g, which corresponds to the formation of Li
3.05
Ge alloy. The effective diffusion coefficient of lithium in germanium is shown to be 1.2 × 10
–11
cm
2
/s. The degradation of the germanium electrode upon cycling at 0.6 С rate is less than 0.3% per cycle. |
| doi_str_mv | 10.1134/S1023193518120054 |
| format | Article |
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3.05
Ge alloy. The effective diffusion coefficient of lithium in germanium is shown to be 1.2 × 10
–11
cm
2
/s. The degradation of the germanium electrode upon cycling at 0.6 С rate is less than 0.3% per cycle.</description><identifier>ISSN: 1023-1935</identifier><identifier>EISSN: 1608-3342</identifier><identifier>DOI: 10.1134/S1023193518120054</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aqueous solutions ; Chemistry ; Chemistry and Materials Science ; Diffusion coefficient ; Electrochemistry ; Electrodes ; Germanium oxides ; Insertion ; Lithium ; Lithium-ion batteries ; Nanostructured materials ; Physical Chemistry ; Rechargeable batteries ; Substrates</subject><ispartof>Russian journal of electrochemistry, 2018-12, Vol.54 (12), p.1111-1116</ispartof><rights>Pleiades Publishing, Ltd. 2018</rights><rights>Copyright Springer Nature B.V. 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-a75945b4b8153cfb9600e47c993becc8e478a971b709285aeb759d19aa2063673</citedby><cites>FETCH-LOGICAL-c316t-a75945b4b8153cfb9600e47c993becc8e478a971b709285aeb759d19aa2063673</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1023193518120054$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1023193518120054$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Gavrilin, I. M.</creatorcontrib><creatorcontrib>Smolyaninov, V. A.</creatorcontrib><creatorcontrib>Dronov, A. A.</creatorcontrib><creatorcontrib>Gavrilov, S. A.</creatorcontrib><creatorcontrib>Trifonov, A. Yu</creatorcontrib><creatorcontrib>Kulova, T. L.</creatorcontrib><creatorcontrib>Kuz’mina, A. A.</creatorcontrib><creatorcontrib>Skundin, A. M.</creatorcontrib><title>Study of the Process of Reversible Insertion of Lithium into Nanostructured Materials Based on Germanium</title><title>Russian journal of electrochemistry</title><addtitle>Russ J Electrochem</addtitle><description>Nanostructured germanium samples prepared by electrochemical deposition from aqueous solution of 0.05 М germanium oxide onto titanium substrate are tested as the negative electrodes of lithium-ion batteries. The reversible capacity in the process of lithium insertion-extraction is found to be about 1180 mA h/g, which corresponds to the formation of Li
3.05
Ge alloy. The effective diffusion coefficient of lithium in germanium is shown to be 1.2 × 10
–11
cm
2
/s. The degradation of the germanium electrode upon cycling at 0.6 С rate is less than 0.3% per cycle.</description><subject>Aqueous solutions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Diffusion coefficient</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Germanium oxides</subject><subject>Insertion</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Nanostructured materials</subject><subject>Physical Chemistry</subject><subject>Rechargeable batteries</subject><subject>Substrates</subject><issn>1023-1935</issn><issn>1608-3342</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LAzEQhoMoWKs_wFvA8-pMsl85qmgt1A-snpdsOmu3tJuaZIX-e7NU8CCe5uN9nxlmGDtHuESU6dUcQUhUMsMSBUCWHrAR5lAmUqbiMOZRTgb9mJ14vwKAskA1Yst56Bc7bhselsRfnDXk_VC-0hc539Zr4tPOkwut7Yb-rA3Ltt_wtguWP-nO-uB6E3pHC_6oA7lWrz2_0T7WkZiQ2-guAqfsqIkKnf3EMXu_v3u7fUhmz5Pp7fUsMRLzkOgiU2lWp3WJmTRNrXIASgujlKzJmDLmpVYF1gUoUWaa6ggsUGktIJd5IcfsYj936-xnTz5UK9u7Lq6sBMabMQMF0YV7l3HWe0dNtXXtRrtdhVAND63-PDQyYs_46O0-yP1O_h_6Bhizdz8</recordid><startdate>20181201</startdate><enddate>20181201</enddate><creator>Gavrilin, I. M.</creator><creator>Smolyaninov, V. A.</creator><creator>Dronov, A. A.</creator><creator>Gavrilov, S. A.</creator><creator>Trifonov, A. Yu</creator><creator>Kulova, T. L.</creator><creator>Kuz’mina, A. A.</creator><creator>Skundin, A. M.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20181201</creationdate><title>Study of the Process of Reversible Insertion of Lithium into Nanostructured Materials Based on Germanium</title><author>Gavrilin, I. M. ; Smolyaninov, V. A. ; Dronov, A. A. ; Gavrilov, S. A. ; Trifonov, A. Yu ; Kulova, T. L. ; Kuz’mina, A. A. ; Skundin, A. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-a75945b4b8153cfb9600e47c993becc8e478a971b709285aeb759d19aa2063673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aqueous solutions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Diffusion coefficient</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Germanium oxides</topic><topic>Insertion</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Nanostructured materials</topic><topic>Physical Chemistry</topic><topic>Rechargeable batteries</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gavrilin, I. M.</creatorcontrib><creatorcontrib>Smolyaninov, V. A.</creatorcontrib><creatorcontrib>Dronov, A. A.</creatorcontrib><creatorcontrib>Gavrilov, S. A.</creatorcontrib><creatorcontrib>Trifonov, A. Yu</creatorcontrib><creatorcontrib>Kulova, T. L.</creatorcontrib><creatorcontrib>Kuz’mina, A. A.</creatorcontrib><creatorcontrib>Skundin, A. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gavrilin, I. M.</au><au>Smolyaninov, V. A.</au><au>Dronov, A. A.</au><au>Gavrilov, S. A.</au><au>Trifonov, A. Yu</au><au>Kulova, T. L.</au><au>Kuz’mina, A. A.</au><au>Skundin, A. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of the Process of Reversible Insertion of Lithium into Nanostructured Materials Based on Germanium</atitle><jtitle>Russian journal of electrochemistry</jtitle><stitle>Russ J Electrochem</stitle><date>2018-12-01</date><risdate>2018</risdate><volume>54</volume><issue>12</issue><spage>1111</spage><epage>1116</epage><pages>1111-1116</pages><issn>1023-1935</issn><eissn>1608-3342</eissn><abstract>Nanostructured germanium samples prepared by electrochemical deposition from aqueous solution of 0.05 М germanium oxide onto titanium substrate are tested as the negative electrodes of lithium-ion batteries. The reversible capacity in the process of lithium insertion-extraction is found to be about 1180 mA h/g, which corresponds to the formation of Li
3.05
Ge alloy. The effective diffusion coefficient of lithium in germanium is shown to be 1.2 × 10
–11
cm
2
/s. The degradation of the germanium electrode upon cycling at 0.6 С rate is less than 0.3% per cycle.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1023193518120054</doi><tpages>6</tpages></addata></record> |
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| subjects | Aqueous solutions Chemistry Chemistry and Materials Science Diffusion coefficient Electrochemistry Electrodes Germanium oxides Insertion Lithium Lithium-ion batteries Nanostructured materials Physical Chemistry Rechargeable batteries Substrates |
| title | Study of the Process of Reversible Insertion of Lithium into Nanostructured Materials Based on Germanium |
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