Reactivity of IrCl(PPh^sub 3^)^sub 3^ with diphenylacetylene - A direct route to 1-iridaindene
The 1-iridaindene complex, ..., has been prepared from the reaction of ... with PhC...CPh by a novel direct cycloiridation reaction. A plausible mechanistic pathway has been suggested involving ...-coordination assisted ortho- C - H activation and subsequent alkyne hydroiridation reaction to provide...
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| Veröffentlicht in: | Canadian journal of chemistry 2009-01, Vol.87 (1), p.183 |
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| container_title | Canadian journal of chemistry |
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| creator | Choudhury, Joyanta Pratihar, Sanjay Maity, Arnab Kumar Roy, Sujit |
| description | The 1-iridaindene complex, ..., has been prepared from the reaction of ... with PhC...CPh by a novel direct cycloiridation reaction. A plausible mechanistic pathway has been suggested involving ...-coordination assisted ortho- C - H activation and subsequent alkyne hydroiridation reaction to provide the five-member iridacycle. (ProQuest: ... denotes formulae/symbols omitted.) |
| format | Article |
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| fulltext | fulltext |
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| ispartof | Canadian journal of chemistry, 2009-01, Vol.87 (1), p.183 |
| issn | 0008-4042 1480-3291 |
| language | eng |
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| source | Free Full-Text Journals in Chemistry |
| subjects | Chemical compounds Chemical elements Chemical reactions |
| title | Reactivity of IrCl(PPh^sub 3^)^sub 3^ with diphenylacetylene - A direct route to 1-iridaindene |
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