Branched polyethylenes attainable using thermally enhanced bis(imino)acenaphthene-nickel catalysts: Exploring the effects of temperature and pressure

[Display omitted] •Straightforward and cost-effective process to produce elastomeric polyethylene.•Highly branched polyethylenes by bis(imino)acenaphthene-nickel(II) catalysts.•Highly active catalysts for the polymerization of ethylene.•Access to branched polyethylenes with narrow polydispersity.•Po...

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Veröffentlicht in:	Applied catalysis. A, General General, 2019-03, Vol.573, p.73-86
Hauptverfasser:	Zhang, Qiuyue, Zhang, Randi, Ma, Yanping, Solan, Gregory A., Liang, Tongling, Sun, Wen-Hua
Format:	Artikel
Sprache:	eng
Schlagworte:	1,2-Bis(arylimino)acenaphthene 4,4′-Difluorobenzhydryl groups Aluminum Branched polyethylene Bromine Catalysis Catalysts Catalytic activity Chelates Elastic recovery Fluorine Ligands Nickel Nickel catalysts NMR Nuclear magnetic resonance Organic chemistry Polyethylene Polyethylenes Pressure effects Temperature and pressure effects Temperature effects Thermoplastic elastomers
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