Volumes of activation for electrode processes of various charge-types in nonaqueous solvents

Volumes of activation ( V ‡ el ) are reported for electron transfer at a Pt electrode of Mn(CN-cyclo-C 6 H 11 ) 6 2+/+ in acetonitrile, acetone, methanol, and propylene carbonate, and of Fe(phen) 3 3+/2+ in acetonitrile. In all cases, V ‡ el is markedly positive, whereas for the homogeneous self-exc...

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Veröffentlicht in:	Canadian journal of chemistry 2001-12, Vol.79 (12), p.1864-1869
Hauptverfasser:	Matsumoto, Mitsuru, Lamprecht, Delanie, North, Michael R, Swaddle, Thomas W
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Electrodes Electrolysis Electrons Kinetics Organic solvents Solvents
Online-Zugang:	Volltext
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