Remarkable kinetic stability of (alpha)-thiocarbamoyl substituted 4-methoxybenzyl cations

Remarkable kinetic stability of (alpha)-thiocarbamoyl substituted 4-methoxybenzyl cations

4-Methoxybenzyl cations bearing alpha-(N,N-dimethylcarbamoyl) and alpha-(N,N-dimethylthiocarbamoyl) substituents have been generated photochemically upon irradiation of precursors with pentafluorobenzoate or 4-methoxybenzoate leaving groups.

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Veröffentlicht in:Canadian journal of chemistry 1998-12, Vol.76 (12), p.1910
Hauptverfasser: McClelland, Robert A, Licence, Victoria E, Richard, John P, Williams, Kathleen B, Shrong-Shi Lin
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Sprache:eng
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Carbon
Carbon compounds
Cations
Chemistry
Hydrocarbons
Ions
Irradiation
Kinetics
Photolysis
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container_issue 12
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container_title Canadian journal of chemistry
container_volume 76
creator McClelland, Robert A
Licence, Victoria E
Richard, John P
Williams, Kathleen B
Shrong-Shi Lin
description 4-Methoxybenzyl cations bearing alpha-(N,N-dimethylcarbamoyl) and alpha-(N,N-dimethylthiocarbamoyl) substituents have been generated photochemically upon irradiation of precursors with pentafluorobenzoate or 4-methoxybenzoate leaving groups.
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source Free Full-Text Journals in Chemistry
subjects Carbon
Carbon compounds
Cations
Chemistry
Hydrocarbons
Ions
Irradiation
Kinetics
Photolysis
title Remarkable kinetic stability of (alpha)-thiocarbamoyl substituted 4-methoxybenzyl cations
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