Substituent effects on basicity in Group 15 compounds: an analysis based on proton affinities, charge distributions, and dipole polarizabilities

Ab initio calculations on a series of trisubstituted amines, phosphines, and arsines are presented at the MP2/6-311G(d,p) level. Specifically, the species studied are XH 3 , XF 3 , and X(Me) 3 , where X = N, P, or As. The influence of the substituents on the proton affinity is analyzed in terms of t...

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Veröffentlicht in:	Canadian journal of chemistry 1997-01, Vol.75 (1), p.60-67
Hauptverfasser:	Howard, S.T, Foreman, J.P, Edwards, P.G
Format:	Artikel
Sprache:	eng
Schlagworte:	Electrons Protons Quantum chemistry
Online-Zugang:	Volltext
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