The first enantioselective strategy towards speciosins

The first enantioselective strategy towards speciosins

Speciosins constitute a group of natural compounds that have never been synthesized enantioselectively. We propose to introduce chirality by the use of enantiopure 3-halo- cis -1,2-cyclohexadienediols of microbial origin. The introduction of the alkynylic side chain by Sonogashira's methodology...

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Veröffentlicht in:New journal of chemistry 2019, Vol.43 (9), p.3653-3655
Hauptverfasser: Peixoto de Abreu Lima, Alejandro, Suescun, Leopoldo, Pandolfi, Enrique, Schapiro, Valeria
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Chirality
Crystallography
Enantiomers
Microorganisms
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container_title New journal of chemistry
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creator Peixoto de Abreu Lima, Alejandro
Suescun, Leopoldo
Pandolfi, Enrique
Schapiro, Valeria
description Speciosins constitute a group of natural compounds that have never been synthesized enantioselectively. We propose to introduce chirality by the use of enantiopure 3-halo- cis -1,2-cyclohexadienediols of microbial origin. The introduction of the alkynylic side chain by Sonogashira's methodology was successful, thus confirming a valuable strategy for the asymmetric preparation of speciosins.
doi_str_mv 10.1039/C8NJ06158K
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chirality
Crystallography
Enantiomers
Microorganisms
title The first enantioselective strategy towards speciosins
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