Crevice corrosion behavior of Alloy 690 in high-temperature water

Characterizations of oxide films formed on Alloy 690 during crevice corrosion in 290 °C pure water were investigated. It was found that different hydrochemistry conditions and potential drop affected the development of oxide films within the crevice. The thick oxide film formed at crevice mouth main...

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Veröffentlicht in:Journal of nuclear materials 2019-03, Vol.515, p.326-337
Hauptverfasser: Ning, Fangqiang, Wu, Xinqiang, Tan, Jibo
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Tan, Jibo
description Characterizations of oxide films formed on Alloy 690 during crevice corrosion in 290 °C pure water were investigated. It was found that different hydrochemistry conditions and potential drop affected the development of oxide films within the crevice. The thick oxide film formed at crevice mouth mainly consisted of compact NiO and NiFe2O4 due to the precipitation of Ni2+ and Fe2+, while the thin oxide film formed within the crevice mainly consisted of an outer layer of Cr(OH)3 and (Fe, Ni)Cr2O4, and a continuous inner layer of Cr2O3, which was attributed to the hydrolysis of Cr3+ and decreased the pH value of the crevice solution. Possible mechanisms of crevice corrosion and growth of the oxide films at different sites along the crevice in high-temperature water are discussed. •The crevice affects the development of oxide films within the crevice.•Hydrochemistry conditions within the crevice are strongly affected by crevice.•The Cr3+ hydrolysis results in formation of Cr-rich oxides within the crevice.•The oxide film at crevice mouth is thick, while it is thin within the crevice.
doi_str_mv 10.1016/j.jnucmat.2018.12.050
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It was found that different hydrochemistry conditions and potential drop affected the development of oxide films within the crevice. The thick oxide film formed at crevice mouth mainly consisted of compact NiO and NiFe2O4 due to the precipitation of Ni2+ and Fe2+, while the thin oxide film formed within the crevice mainly consisted of an outer layer of Cr(OH)3 and (Fe, Ni)Cr2O4, and a continuous inner layer of Cr2O3, which was attributed to the hydrolysis of Cr3+ and decreased the pH value of the crevice solution. 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Possible mechanisms of crevice corrosion and growth of the oxide films at different sites along the crevice in high-temperature water are discussed. •The crevice affects the development of oxide films within the crevice.•Hydrochemistry conditions within the crevice are strongly affected by crevice.•The Cr3+ hydrolysis results in formation of Cr-rich oxides within the crevice.•The oxide film at crevice mouth is thick, while it is thin within the crevice.</description><subject>Alloy</subject><subject>Casting</subject><subject>Chromic hydroxide</subject><subject>Corrosion</subject><subject>Crevice corrosion</subject><subject>Heat resistant alloys</subject><subject>High temperature</subject><subject>High-temperature corrosion</subject><subject>Iron</subject><subject>Nickel base alloys</subject><subject>Nickel ferrites</subject><subject>Oxidation</subject><subject>Oxide coatings</subject><subject>Superalloys</subject><subject>XPS</subject><issn>0022-3115</issn><issn>1873-4820</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkMtqwzAQRUVpoWnaTygIurY7I0u2vCoh9AWBbtq1kOVxI5NYqWyn5O_rkOy7ms09d7iHsXuEFAHzxzZtu9Ft7ZAKQJ2iSEHBBZuhLrJEagGXbAYgRJIhqmt20_ctAKgS1IwtlpH23hF3IcbQ-9DxitZ270PkoeGLzSYceF4C9x1f--91MtB2R9EOYyT-aweKt-yqsZue7s53zr5enj-Xb8nq4_V9uVglLsuKIdE6b0onK1lgoVAqqOqydBbRKdBFLfMmqwsFIpOFoEo6AJc73ciqETUoXWdz9nDq3cXwM1I_mDaMsZteGoF6IkvQakqpU8pNa_pIjdlFv7XxYBDM0ZZpzdmWOdoyKMxka-KeThxNE_aeoumdp85R7SO5wdTB_9PwB1wBdDA</recordid><startdate>201903</startdate><enddate>201903</enddate><creator>Ning, Fangqiang</creator><creator>Wu, Xinqiang</creator><creator>Tan, Jibo</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>7ST</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>SOI</scope></search><sort><creationdate>201903</creationdate><title>Crevice corrosion behavior of Alloy 690 in high-temperature water</title><author>Ning, Fangqiang ; Wu, Xinqiang ; Tan, Jibo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-886f9c4b471751450bd99ca11c5087d46f3d75023472eb4c00c6c8f4bf2d058d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Alloy</topic><topic>Casting</topic><topic>Chromic hydroxide</topic><topic>Corrosion</topic><topic>Crevice corrosion</topic><topic>Heat resistant alloys</topic><topic>High temperature</topic><topic>High-temperature corrosion</topic><topic>Iron</topic><topic>Nickel base alloys</topic><topic>Nickel ferrites</topic><topic>Oxidation</topic><topic>Oxide coatings</topic><topic>Superalloys</topic><topic>XPS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ning, Fangqiang</creatorcontrib><creatorcontrib>Wu, Xinqiang</creatorcontrib><creatorcontrib>Tan, Jibo</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Journal of nuclear materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ning, Fangqiang</au><au>Wu, Xinqiang</au><au>Tan, Jibo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crevice corrosion behavior of Alloy 690 in high-temperature water</atitle><jtitle>Journal of nuclear materials</jtitle><date>2019-03</date><risdate>2019</risdate><volume>515</volume><spage>326</spage><epage>337</epage><pages>326-337</pages><issn>0022-3115</issn><eissn>1873-4820</eissn><abstract>Characterizations of oxide films formed on Alloy 690 during crevice corrosion in 290 °C pure water were investigated. It was found that different hydrochemistry conditions and potential drop affected the development of oxide films within the crevice. The thick oxide film formed at crevice mouth mainly consisted of compact NiO and NiFe2O4 due to the precipitation of Ni2+ and Fe2+, while the thin oxide film formed within the crevice mainly consisted of an outer layer of Cr(OH)3 and (Fe, Ni)Cr2O4, and a continuous inner layer of Cr2O3, which was attributed to the hydrolysis of Cr3+ and decreased the pH value of the crevice solution. Possible mechanisms of crevice corrosion and growth of the oxide films at different sites along the crevice in high-temperature water are discussed. •The crevice affects the development of oxide films within the crevice.•Hydrochemistry conditions within the crevice are strongly affected by crevice.•The Cr3+ hydrolysis results in formation of Cr-rich oxides within the crevice.•The oxide film at crevice mouth is thick, while it is thin within the crevice.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jnucmat.2018.12.050</doi><tpages>12</tpages></addata></record>
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subjects Alloy
Casting
Chromic hydroxide
Corrosion
Crevice corrosion
Heat resistant alloys
High temperature
High-temperature corrosion
Iron
Nickel base alloys
Nickel ferrites
Oxidation
Oxide coatings
Superalloys
XPS
title Crevice corrosion behavior of Alloy 690 in high-temperature water
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