Effect of novel aliphatic fluoro‐diol content on synthesis and properties of waterborne polyurethanes
ABSTRACT This study synthesized a waterborne polyurethane (WPU) prepolymer by using polytetramethylene glycol, isophorone diisocyanate, and 2,2,3,3,4,4,4‐Heptafluoro‐butynic acid 2,2‐bis‐hydroxymethyl‐butyl ester (HFBA). Subsequently, a series of novel HFBA/WPUs were synthesized by adopting ethylene...
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| Veröffentlicht in: | Journal of applied polymer science 2019-06, Vol.136 (21), p.n/a |
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| creator | Tsen, Wen‐Chin Lee, Chia‐Fan Su, Yu‐Ru Gu, Jia‐Hao Suen, Maw‐Cherng |
| description | ABSTRACT
This study synthesized a waterborne polyurethane (WPU) prepolymer by using polytetramethylene glycol, isophorone diisocyanate, and 2,2,3,3,4,4,4‐Heptafluoro‐butynic acid 2,2‐bis‐hydroxymethyl‐butyl ester (HFBA). Subsequently, a series of novel HFBA/WPUs were synthesized by adopting ethylenediamine as the chain extender. The results from Fourier transform infrared spectroscopy demonstrated that the CO groups of HFBA/WPUs shifted to lower wavenumbers as the HFBA content increased. Moreover, when the HFBA content of the synthesized HFBA/WPUs increased, the WPU initial decomposition temperature, glass transition temperature, tensile strength, and Young's modulus also increased. Furthermore, the results of atomic force microscopy identified a relatively high number of humpy protrusions and roughness levels in the HFBA/WPUs with a relatively high HFBA content, causing higher hydrophobicity of these HFBA/WPUs. Furthermore, in vitro platelet and erythrocyte adhesion experiments revealed that increasing the HFBA content lowered platelet and erythrocyte adhesion on the surface of the WPUs. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47356.
SEM micrographs of erythrocyte adhesion for HFBA/WPU‐03. |
| doi_str_mv | 10.1002/app.47356 |
| format | Article |
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This study synthesized a waterborne polyurethane (WPU) prepolymer by using polytetramethylene glycol, isophorone diisocyanate, and 2,2,3,3,4,4,4‐Heptafluoro‐butynic acid 2,2‐bis‐hydroxymethyl‐butyl ester (HFBA). Subsequently, a series of novel HFBA/WPUs were synthesized by adopting ethylenediamine as the chain extender. The results from Fourier transform infrared spectroscopy demonstrated that the CO groups of HFBA/WPUs shifted to lower wavenumbers as the HFBA content increased. Moreover, when the HFBA content of the synthesized HFBA/WPUs increased, the WPU initial decomposition temperature, glass transition temperature, tensile strength, and Young's modulus also increased. Furthermore, the results of atomic force microscopy identified a relatively high number of humpy protrusions and roughness levels in the HFBA/WPUs with a relatively high HFBA content, causing higher hydrophobicity of these HFBA/WPUs. Furthermore, in vitro platelet and erythrocyte adhesion experiments revealed that increasing the HFBA content lowered platelet and erythrocyte adhesion on the surface of the WPUs. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47356.
SEM micrographs of erythrocyte adhesion for HFBA/WPU‐03.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.47356</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Adhesion ; Aliphatic compounds ; Atomic force microscopy ; Atomic properties ; chain extender ; decomposition temperature ; Diisocyanates ; Erythrocytes ; Ethylenediamine ; Fourier transforms ; Glass transition temperature ; Hydrophobicity ; Materials science ; Modulus of elasticity ; platelet adhesion ; Polymers ; Polytetramethylene glycol ; Polyurethane resins ; Synthesis ; Temperature ; waterborne polyurethanes</subject><ispartof>Journal of applied polymer science, 2019-06, Vol.136 (21), p.n/a</ispartof><rights>2019 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2976-56d2c36d65ad74b1ad016773a8dd4ce33b736c326b6ce83eed14ac5399dd747e3</citedby><cites>FETCH-LOGICAL-c2976-56d2c36d65ad74b1ad016773a8dd4ce33b736c326b6ce83eed14ac5399dd747e3</cites><orcidid>0000-0003-2023-2178</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.47356$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.47356$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Tsen, Wen‐Chin</creatorcontrib><creatorcontrib>Lee, Chia‐Fan</creatorcontrib><creatorcontrib>Su, Yu‐Ru</creatorcontrib><creatorcontrib>Gu, Jia‐Hao</creatorcontrib><creatorcontrib>Suen, Maw‐Cherng</creatorcontrib><title>Effect of novel aliphatic fluoro‐diol content on synthesis and properties of waterborne polyurethanes</title><title>Journal of applied polymer science</title><description>ABSTRACT
This study synthesized a waterborne polyurethane (WPU) prepolymer by using polytetramethylene glycol, isophorone diisocyanate, and 2,2,3,3,4,4,4‐Heptafluoro‐butynic acid 2,2‐bis‐hydroxymethyl‐butyl ester (HFBA). Subsequently, a series of novel HFBA/WPUs were synthesized by adopting ethylenediamine as the chain extender. The results from Fourier transform infrared spectroscopy demonstrated that the CO groups of HFBA/WPUs shifted to lower wavenumbers as the HFBA content increased. Moreover, when the HFBA content of the synthesized HFBA/WPUs increased, the WPU initial decomposition temperature, glass transition temperature, tensile strength, and Young's modulus also increased. Furthermore, the results of atomic force microscopy identified a relatively high number of humpy protrusions and roughness levels in the HFBA/WPUs with a relatively high HFBA content, causing higher hydrophobicity of these HFBA/WPUs. Furthermore, in vitro platelet and erythrocyte adhesion experiments revealed that increasing the HFBA content lowered platelet and erythrocyte adhesion on the surface of the WPUs. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47356.
SEM micrographs of erythrocyte adhesion for HFBA/WPU‐03.</description><subject>Adhesion</subject><subject>Aliphatic compounds</subject><subject>Atomic force microscopy</subject><subject>Atomic properties</subject><subject>chain extender</subject><subject>decomposition temperature</subject><subject>Diisocyanates</subject><subject>Erythrocytes</subject><subject>Ethylenediamine</subject><subject>Fourier transforms</subject><subject>Glass transition temperature</subject><subject>Hydrophobicity</subject><subject>Materials science</subject><subject>Modulus of elasticity</subject><subject>platelet adhesion</subject><subject>Polymers</subject><subject>Polytetramethylene glycol</subject><subject>Polyurethane resins</subject><subject>Synthesis</subject><subject>Temperature</subject><subject>waterborne polyurethanes</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp10LtOwzAUBmALgUQpDLyBJSaGtHac2MlYVeUiVaIDzJZjn9BUwQ52QtWNR-AZeRJcwsp0hvOdi36ErimZUULSueq6WSZYzk_QhJJSJBlPi1M0iT2aFGWZn6OLEHaEUJoTPkGvq7oG3WNXY-s-oMWqbbqt6huN63Zw3n1_fpnGtVg724ON0OJwsP0WQhOwsgZ33nXg-wbCccle9eAr5y3gzrWHwUO_VRbCJTqrVRvg6q9O0cvd6nn5kKyf7h-Xi3Wi01LwJOcm1YwbnisjsooqQygXgqnCmEwDY5VgXLOUV1xDwQAMzZTOWVma6AWwKboZ98a33gcIvdy5wdt4Uqa0yChJOeFR3Y5KexeCh1p2vnlT_iApkcccZcxR_uYY7Xy0-6aFw_9QLjabceIHyXt3dA</recordid><startdate>20190605</startdate><enddate>20190605</enddate><creator>Tsen, Wen‐Chin</creator><creator>Lee, Chia‐Fan</creator><creator>Su, Yu‐Ru</creator><creator>Gu, Jia‐Hao</creator><creator>Suen, Maw‐Cherng</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-2023-2178</orcidid></search><sort><creationdate>20190605</creationdate><title>Effect of novel aliphatic fluoro‐diol content on synthesis and properties of waterborne polyurethanes</title><author>Tsen, Wen‐Chin ; Lee, Chia‐Fan ; Su, Yu‐Ru ; Gu, Jia‐Hao ; Suen, Maw‐Cherng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2976-56d2c36d65ad74b1ad016773a8dd4ce33b736c326b6ce83eed14ac5399dd747e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Adhesion</topic><topic>Aliphatic compounds</topic><topic>Atomic force microscopy</topic><topic>Atomic properties</topic><topic>chain extender</topic><topic>decomposition temperature</topic><topic>Diisocyanates</topic><topic>Erythrocytes</topic><topic>Ethylenediamine</topic><topic>Fourier transforms</topic><topic>Glass transition temperature</topic><topic>Hydrophobicity</topic><topic>Materials science</topic><topic>Modulus of elasticity</topic><topic>platelet adhesion</topic><topic>Polymers</topic><topic>Polytetramethylene glycol</topic><topic>Polyurethane resins</topic><topic>Synthesis</topic><topic>Temperature</topic><topic>waterborne polyurethanes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tsen, Wen‐Chin</creatorcontrib><creatorcontrib>Lee, Chia‐Fan</creatorcontrib><creatorcontrib>Su, Yu‐Ru</creatorcontrib><creatorcontrib>Gu, Jia‐Hao</creatorcontrib><creatorcontrib>Suen, Maw‐Cherng</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tsen, Wen‐Chin</au><au>Lee, Chia‐Fan</au><au>Su, Yu‐Ru</au><au>Gu, Jia‐Hao</au><au>Suen, Maw‐Cherng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of novel aliphatic fluoro‐diol content on synthesis and properties of waterborne polyurethanes</atitle><jtitle>Journal of applied polymer science</jtitle><date>2019-06-05</date><risdate>2019</risdate><volume>136</volume><issue>21</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>ABSTRACT
This study synthesized a waterborne polyurethane (WPU) prepolymer by using polytetramethylene glycol, isophorone diisocyanate, and 2,2,3,3,4,4,4‐Heptafluoro‐butynic acid 2,2‐bis‐hydroxymethyl‐butyl ester (HFBA). Subsequently, a series of novel HFBA/WPUs were synthesized by adopting ethylenediamine as the chain extender. The results from Fourier transform infrared spectroscopy demonstrated that the CO groups of HFBA/WPUs shifted to lower wavenumbers as the HFBA content increased. Moreover, when the HFBA content of the synthesized HFBA/WPUs increased, the WPU initial decomposition temperature, glass transition temperature, tensile strength, and Young's modulus also increased. Furthermore, the results of atomic force microscopy identified a relatively high number of humpy protrusions and roughness levels in the HFBA/WPUs with a relatively high HFBA content, causing higher hydrophobicity of these HFBA/WPUs. Furthermore, in vitro platelet and erythrocyte adhesion experiments revealed that increasing the HFBA content lowered platelet and erythrocyte adhesion on the surface of the WPUs. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47356.
SEM micrographs of erythrocyte adhesion for HFBA/WPU‐03.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.47356</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-2023-2178</orcidid></addata></record> |
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| subjects | Adhesion Aliphatic compounds Atomic force microscopy Atomic properties chain extender decomposition temperature Diisocyanates Erythrocytes Ethylenediamine Fourier transforms Glass transition temperature Hydrophobicity Materials science Modulus of elasticity platelet adhesion Polymers Polytetramethylene glycol Polyurethane resins Synthesis Temperature waterborne polyurethanes |
| title | Effect of novel aliphatic fluoro‐diol content on synthesis and properties of waterborne polyurethanes |
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