Reactive kinetics of carbon dioxide loaded aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol and piperazine using a pressure drop method
In this study, a new pressure drop method has been used to investigate the kinetics of carbon dioxide reaction with aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol (AEPD) with piperazine (PZ). The blending of a small amount of PZ with AEPD has a significant effect on the observed rate constant, kob...
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| Veröffentlicht in: | International journal of chemical kinetics 2019-04, Vol.51 (4), p.291-298 |
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| container_title | International journal of chemical kinetics |
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| creator | Ullah, Sami Suleman, Humbul Tahir, Muhammad Suleman Sagir, Muhammad Muhammad, Shabbir Al‐Sehemi, Abdullah G. Zafar, Masood‐ur‐Rauf Kareem, Firas A. Abdul Maulud, Abdulhalim Shah Bustam, Mohamad Azmi |
| description | In this study, a new pressure drop method has been used to investigate the kinetics of carbon dioxide reaction with aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol (AEPD) with piperazine (PZ). The blending of a small amount of PZ with AEPD has a significant effect on the observed rate constant, kobs. It was observed that kobs values of the blend increased more than twice than the summation of kobs values of individual alkanolamines. The reaction kinetics in this study were modeled by assuming a termolecular mechanism. The addition of 0.1 mol/L of PZ to 1 mol/L AEPD exhibited an observed rate constant, kobs of 8824.1 s−1, which is comparable to other alkanolamine mixtures. Hence, PZ/AEPD mixtures can be potentially used for rapid carbon dioxide capture. |
| doi_str_mv | 10.1002/kin.21252 |
| format | Article |
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The addition of 0.1 mol/L of PZ to 1 mol/L AEPD exhibited an observed rate constant, kobs of 8824.1 s−1, which is comparable to other alkanolamine mixtures. Hence, PZ/AEPD mixtures can be potentially used for rapid carbon dioxide capture.</description><identifier>ISSN: 0538-8066</identifier><identifier>EISSN: 1097-4601</identifier><identifier>DOI: 10.1002/kin.21252</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>Alkanolamines ; Carbon dioxide ; Carbon sequestration ; kinetic modeling ; Pressure drop ; pressure drop method ; Reaction kinetics</subject><ispartof>International journal of chemical kinetics, 2019-04, Vol.51 (4), p.291-298</ispartof><rights>2019 Wiley Periodicals, Inc.</rights><rights>2019 Wiley Periodicals, Inc., A Wiley Company</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2972-76c04a9d05843cf3ac8328d94c5327e89df339016b8b199822c1fa073a6f4b383</citedby><cites>FETCH-LOGICAL-c2972-76c04a9d05843cf3ac8328d94c5327e89df339016b8b199822c1fa073a6f4b383</cites><orcidid>0000-0002-9669-5737</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fkin.21252$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fkin.21252$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Ullah, Sami</creatorcontrib><creatorcontrib>Suleman, Humbul</creatorcontrib><creatorcontrib>Tahir, Muhammad Suleman</creatorcontrib><creatorcontrib>Sagir, Muhammad</creatorcontrib><creatorcontrib>Muhammad, Shabbir</creatorcontrib><creatorcontrib>Al‐Sehemi, Abdullah G.</creatorcontrib><creatorcontrib>Zafar, Masood‐ur‐Rauf</creatorcontrib><creatorcontrib>Kareem, Firas A. Abdul</creatorcontrib><creatorcontrib>Maulud, Abdulhalim Shah</creatorcontrib><creatorcontrib>Bustam, Mohamad Azmi</creatorcontrib><title>Reactive kinetics of carbon dioxide loaded aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol and piperazine using a pressure drop method</title><title>International journal of chemical kinetics</title><description>In this study, a new pressure drop method has been used to investigate the kinetics of carbon dioxide reaction with aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol (AEPD) with piperazine (PZ). The blending of a small amount of PZ with AEPD has a significant effect on the observed rate constant, kobs. It was observed that kobs values of the blend increased more than twice than the summation of kobs values of individual alkanolamines. The reaction kinetics in this study were modeled by assuming a termolecular mechanism. The addition of 0.1 mol/L of PZ to 1 mol/L AEPD exhibited an observed rate constant, kobs of 8824.1 s−1, which is comparable to other alkanolamine mixtures. Hence, PZ/AEPD mixtures can be potentially used for rapid carbon dioxide capture.</description><subject>Alkanolamines</subject><subject>Carbon dioxide</subject><subject>Carbon sequestration</subject><subject>kinetic modeling</subject><subject>Pressure drop</subject><subject>pressure drop method</subject><subject>Reaction kinetics</subject><issn>0538-8066</issn><issn>1097-4601</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kMlOwzAURS0EEqWw4A8ssUIirYcM9hJVDBUVSAjWlmM74JLGwU6AsuIT4Bf5ElzCls27b3HuGy4AhxhNMEJk-mSbCcEkI1tghBEvkjRHeBuMUEZZwlCe74K9EJYIIc5xNgJft0aqzr4YGJ2msypAV0ElfekaqK17s9rA2kltNJTPvXF9gGVtGr3ByPfHp1zZxkXd9KZ7XNdR8QmNtfWulY2JQ2ooo6G1rfHyPa6BfbDNA5Sw9SaE3huoIwtX0e_0PtipZB3MwZ-Owf352d3sMlncXMxnp4tEEV6QpMgVSiXXKGMpVRWVilHCNE9VRklhGNcVpRzhvGQl5pwRonAlUUFlXqUlZXQMjoa58c74WOjE0vW-iSsFwYyinBCMI3U8UMq7ELypROvtSvq1wEhsEhcxN_GbeGSnA_tqa7P-HxRX8-vB8QOiH4fz</recordid><startdate>201904</startdate><enddate>201904</enddate><creator>Ullah, Sami</creator><creator>Suleman, Humbul</creator><creator>Tahir, Muhammad Suleman</creator><creator>Sagir, Muhammad</creator><creator>Muhammad, Shabbir</creator><creator>Al‐Sehemi, Abdullah G.</creator><creator>Zafar, Masood‐ur‐Rauf</creator><creator>Kareem, Firas A. Abdul</creator><creator>Maulud, Abdulhalim Shah</creator><creator>Bustam, Mohamad Azmi</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-9669-5737</orcidid></search><sort><creationdate>201904</creationdate><title>Reactive kinetics of carbon dioxide loaded aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol and piperazine using a pressure drop method</title><author>Ullah, Sami ; Suleman, Humbul ; Tahir, Muhammad Suleman ; Sagir, Muhammad ; Muhammad, Shabbir ; Al‐Sehemi, Abdullah G. ; Zafar, Masood‐ur‐Rauf ; Kareem, Firas A. 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Abdul</creatorcontrib><creatorcontrib>Maulud, Abdulhalim Shah</creatorcontrib><creatorcontrib>Bustam, Mohamad Azmi</creatorcontrib><collection>CrossRef</collection><jtitle>International journal of chemical kinetics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ullah, Sami</au><au>Suleman, Humbul</au><au>Tahir, Muhammad Suleman</au><au>Sagir, Muhammad</au><au>Muhammad, Shabbir</au><au>Al‐Sehemi, Abdullah G.</au><au>Zafar, Masood‐ur‐Rauf</au><au>Kareem, Firas A. 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The reaction kinetics in this study were modeled by assuming a termolecular mechanism. The addition of 0.1 mol/L of PZ to 1 mol/L AEPD exhibited an observed rate constant, kobs of 8824.1 s−1, which is comparable to other alkanolamine mixtures. Hence, PZ/AEPD mixtures can be potentially used for rapid carbon dioxide capture.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/kin.21252</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-9669-5737</orcidid></addata></record> |
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| subjects | Alkanolamines Carbon dioxide Carbon sequestration kinetic modeling Pressure drop pressure drop method Reaction kinetics |
| title | Reactive kinetics of carbon dioxide loaded aqueous blend of 2‐amino‐2‐ethyl‐1,3‐propanediol and piperazine using a pressure drop method |
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