Porous anodic oxide film with self-healing ability for corrosion protection of aluminum

Nanopores in aluminum oxide film served as vessels for corrosion inhibitor to add self-healing ability. Aluminum oxide films were immersed into a solution containing corrosion inhibitor to fill the nanopores. To monitor polarization resistance, the aluminum oxide film was coated with polymer, which...

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Veröffentlicht in:Electrochimica acta 2019-02, Vol.296, p.662-668
Hauptverfasser: Yabuki, Akihiro, Nagayama, Yuki, Fathona, Indra Wahyudhin
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container_title Electrochimica acta
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creator Yabuki, Akihiro
Nagayama, Yuki
Fathona, Indra Wahyudhin
description Nanopores in aluminum oxide film served as vessels for corrosion inhibitor to add self-healing ability. Aluminum oxide films were immersed into a solution containing corrosion inhibitor to fill the nanopores. To monitor polarization resistance, the aluminum oxide film was coated with polymer, which was then scratched with a knife-edge. Uniform and large nanopores demonstrated a higher level of polarization resistance. The corrosion inhibitor was released in two steps: a large release due to dissolution was followed by a more sustained release due to corrosion inhibitor desorption. [Display omitted] •Pores in aluminum oxide film were used as vessels for corrosion inhibitor.•Corrosion inhibitor could be inserted into the pores of aluminum oxide film.•Film with large and uniform nanopores showed the highest resistance.•Healing film was detected on the surface of scratched substrates.•Release of corrosion inhibitor occurred in two steps: large and then sustained.
doi_str_mv 10.1016/j.electacta.2018.11.119
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subjects Aluminum
Aluminum oxide
Anodic protection
Corrosion
Corrosion inhibitors
Corrosion prevention
Corrosion resistance
EIS
Knife-edge
Oxide coatings
Polarization
Polymer coating
Porosity
Protective coatings
SEM
Steel
Sustained release
title Porous anodic oxide film with self-healing ability for corrosion protection of aluminum
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