Synthesis and characterization of bimetallic catalysts Pd-Ru and Pt-Ru supported on γ-alumina and zeolite FAU for the catalytic transformation of HMF
•Bimetallic catalysts Pd-Ru and Pt-Ru supported on FAU and γ-Al2O3 were synthesized.•Two crystallographic phases coexisting in the synthesized zeolite (LTA and FAU).•The phase FAU prevailing when the material was calcinated at 550 °C.•The formation of the Pd-Ru alloy phase was confirmed by XPS and H...
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| Veröffentlicht in: | Fuel (Guildford) 2019-03, Vol.239, p.191-201 |
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| creator | Pérez-Bustos, Héctor Fabio Lucio-Ortiz, Carlos J. de la Rosa, Javier Rivera de Haro del Río, David A. Sandoval-Rangel, Ladislao Martínez-Vargas, Daniela Xulú Maldonado, Carolina Solis Rodriguez-González, Vicente Garza-Navarro, M.A. Morales-Leal, Francisco José |
| description | •Bimetallic catalysts Pd-Ru and Pt-Ru supported on FAU and γ-Al2O3 were synthesized.•Two crystallographic phases coexisting in the synthesized zeolite (LTA and FAU).•The phase FAU prevailing when the material was calcinated at 550 °C.•The formation of the Pd-Ru alloy phase was confirmed by XPS and HRTEM.•Pd-Ru was more selective metal combination to added-value furan derivatives.•Pd-Ru/FAU lost less metal after its first use than Pd-Ru/ γ-Al2O3.•Re-used Pd-Ru/FAU was more selective to furan derivatives and less to byproducts.
It is well known the effects and limitations of the use of fossil fuels, for that reason is necessary to establish alternative sources of energy. The 5-hydroxymethylfurfural (HMF) is a chemical compound that can be obtained from the carbohydrates present in the biomass. Is a key compound for the obtaining of several valuable chemicals, many of them have a promising application as biofuels. In the present work, Pd-Ru and Pt-Ru bimetallic catalysts with low metal content (0.5%) supported on commercial γ-Al2O3 and FAU zeolite prepared by hydrothermal method, were synthesized and characterized to transform HMF into valuable chemicals under mild reaction conditions. Two crystallographic phases were found to coexist in the zeolite synthesized as support, the FAU phase prevailing over the LTA when calcined at 550 °C. The system studied with formic acid as hydrogen donor, under mild reaction conditions, showed a partial hydrogenation of HMF molecule evidenced in the 5-MF and 2,5-DMF formation. Also, a partial oxidation and esterification is happening for the formation of 2,5-DFF and 5-A-2-F, respectively. The catalysts supported on FAU showed better conversion of HMF that catalysts supported on γ-Al2O3. Although all metals showed catalytic activity by separed, Pd-Ru combination was more selective to produce 5-MF, 2,5-DMF and 2,5-DFF than Pt-Ru combination, and showed production of valuable furan derivatives even in their second and thir use. Pd–Ru/FAU catalyst formed a PdRu alloy phase, which can be related to its better catalytic performance. |
| doi_str_mv | 10.1016/j.fuel.2018.10.001 |
| format | Article |
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It is well known the effects and limitations of the use of fossil fuels, for that reason is necessary to establish alternative sources of energy. The 5-hydroxymethylfurfural (HMF) is a chemical compound that can be obtained from the carbohydrates present in the biomass. Is a key compound for the obtaining of several valuable chemicals, many of them have a promising application as biofuels. In the present work, Pd-Ru and Pt-Ru bimetallic catalysts with low metal content (0.5%) supported on commercial γ-Al2O3 and FAU zeolite prepared by hydrothermal method, were synthesized and characterized to transform HMF into valuable chemicals under mild reaction conditions. Two crystallographic phases were found to coexist in the zeolite synthesized as support, the FAU phase prevailing over the LTA when calcined at 550 °C. The system studied with formic acid as hydrogen donor, under mild reaction conditions, showed a partial hydrogenation of HMF molecule evidenced in the 5-MF and 2,5-DMF formation. Also, a partial oxidation and esterification is happening for the formation of 2,5-DFF and 5-A-2-F, respectively. The catalysts supported on FAU showed better conversion of HMF that catalysts supported on γ-Al2O3. Although all metals showed catalytic activity by separed, Pd-Ru combination was more selective to produce 5-MF, 2,5-DMF and 2,5-DFF than Pt-Ru combination, and showed production of valuable furan derivatives even in their second and thir use. Pd–Ru/FAU catalyst formed a PdRu alloy phase, which can be related to its better catalytic performance.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2018.10.001</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Aluminum oxide ; Bimetallic ; Bimetals ; Biofuel ; Biofuels ; Carbohydrates ; Catalysis ; Catalysts ; Catalytic activity ; Chemical compounds ; Chemical synthesis ; Chemicals ; Crystallography ; Energy sources ; Esterification ; Formic acid ; Fossil fuels ; Furan ; Hydrogen storage ; Hydroxymethylfurfural ; Metals ; Organic chemistry ; Oxidation ; Palladium ; Platinum ; Ruthenium ; Transitional aluminas ; Zeolites</subject><ispartof>Fuel (Guildford), 2019-03, Vol.239, p.191-201</ispartof><rights>2018 Elsevier Ltd</rights><rights>Copyright Elsevier BV Mar 1, 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-f5075c5dc8aa3cb453761a0c873b73a59f7f77836a3264ad2861fefeea19abc13</citedby><cites>FETCH-LOGICAL-c328t-f5075c5dc8aa3cb453761a0c873b73a59f7f77836a3264ad2861fefeea19abc13</cites><orcidid>0000-0003-2762-6890</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0016236118317125$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Pérez-Bustos, Héctor Fabio</creatorcontrib><creatorcontrib>Lucio-Ortiz, Carlos J.</creatorcontrib><creatorcontrib>de la Rosa, Javier Rivera</creatorcontrib><creatorcontrib>de Haro del Río, David A.</creatorcontrib><creatorcontrib>Sandoval-Rangel, Ladislao</creatorcontrib><creatorcontrib>Martínez-Vargas, Daniela Xulú</creatorcontrib><creatorcontrib>Maldonado, Carolina Solis</creatorcontrib><creatorcontrib>Rodriguez-González, Vicente</creatorcontrib><creatorcontrib>Garza-Navarro, M.A.</creatorcontrib><creatorcontrib>Morales-Leal, Francisco José</creatorcontrib><title>Synthesis and characterization of bimetallic catalysts Pd-Ru and Pt-Ru supported on γ-alumina and zeolite FAU for the catalytic transformation of HMF</title><title>Fuel (Guildford)</title><description>•Bimetallic catalysts Pd-Ru and Pt-Ru supported on FAU and γ-Al2O3 were synthesized.•Two crystallographic phases coexisting in the synthesized zeolite (LTA and FAU).•The phase FAU prevailing when the material was calcinated at 550 °C.•The formation of the Pd-Ru alloy phase was confirmed by XPS and HRTEM.•Pd-Ru was more selective metal combination to added-value furan derivatives.•Pd-Ru/FAU lost less metal after its first use than Pd-Ru/ γ-Al2O3.•Re-used Pd-Ru/FAU was more selective to furan derivatives and less to byproducts.
It is well known the effects and limitations of the use of fossil fuels, for that reason is necessary to establish alternative sources of energy. The 5-hydroxymethylfurfural (HMF) is a chemical compound that can be obtained from the carbohydrates present in the biomass. Is a key compound for the obtaining of several valuable chemicals, many of them have a promising application as biofuels. In the present work, Pd-Ru and Pt-Ru bimetallic catalysts with low metal content (0.5%) supported on commercial γ-Al2O3 and FAU zeolite prepared by hydrothermal method, were synthesized and characterized to transform HMF into valuable chemicals under mild reaction conditions. Two crystallographic phases were found to coexist in the zeolite synthesized as support, the FAU phase prevailing over the LTA when calcined at 550 °C. The system studied with formic acid as hydrogen donor, under mild reaction conditions, showed a partial hydrogenation of HMF molecule evidenced in the 5-MF and 2,5-DMF formation. Also, a partial oxidation and esterification is happening for the formation of 2,5-DFF and 5-A-2-F, respectively. The catalysts supported on FAU showed better conversion of HMF that catalysts supported on γ-Al2O3. Although all metals showed catalytic activity by separed, Pd-Ru combination was more selective to produce 5-MF, 2,5-DMF and 2,5-DFF than Pt-Ru combination, and showed production of valuable furan derivatives even in their second and thir use. Pd–Ru/FAU catalyst formed a PdRu alloy phase, which can be related to its better catalytic performance.</description><subject>Aluminum oxide</subject><subject>Bimetallic</subject><subject>Bimetals</subject><subject>Biofuel</subject><subject>Biofuels</subject><subject>Carbohydrates</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemical compounds</subject><subject>Chemical synthesis</subject><subject>Chemicals</subject><subject>Crystallography</subject><subject>Energy sources</subject><subject>Esterification</subject><subject>Formic acid</subject><subject>Fossil fuels</subject><subject>Furan</subject><subject>Hydrogen storage</subject><subject>Hydroxymethylfurfural</subject><subject>Metals</subject><subject>Organic chemistry</subject><subject>Oxidation</subject><subject>Palladium</subject><subject>Platinum</subject><subject>Ruthenium</subject><subject>Transitional aluminas</subject><subject>Zeolites</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp9UM1KAzEQDqJg_XkBTwHPW5PN7mYLXkSsCoqi9hym2QmmbDc1yQr1QXwR38NnMtuKR08zfHw_Mx8hJ5yNOePV2WJsemzHOeN1AsaM8R0y4rUUmeSl2CWjhFRZLiq-Tw5CWDDGZF0WI_L5vO7iKwYbKHQN1a_gQUf09gOidR11hs7tEiO0rdVUQ1rWIQb62GRP_UbyGIct9KuV8xEbmkTfXxm0_dJ2sGF8oGttRDq9mFHjPE15v04xeUYPXUjw8i_w5n56RPYMtAGPf-chmU2vXi5vsruH69vLi7tMi7yOmSmZLHXZ6BpA6HlRCllxYDo9PpcCyomRRspaVCDyqoAmrytu0CACn8Bcc3FITre-K-_eegxRLVzvuxSpcl7nhZwUFUusfMvS3oXg0aiVt0vwa8WZGvpXCzX0r4b-Byy1nUTnWxGm-98tehW0xU5jYz3qqBpn_5P_AObZkYs</recordid><startdate>20190301</startdate><enddate>20190301</enddate><creator>Pérez-Bustos, Héctor Fabio</creator><creator>Lucio-Ortiz, Carlos J.</creator><creator>de la Rosa, Javier Rivera</creator><creator>de Haro del Río, David A.</creator><creator>Sandoval-Rangel, Ladislao</creator><creator>Martínez-Vargas, Daniela Xulú</creator><creator>Maldonado, Carolina Solis</creator><creator>Rodriguez-González, Vicente</creator><creator>Garza-Navarro, M.A.</creator><creator>Morales-Leal, Francisco José</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0003-2762-6890</orcidid></search><sort><creationdate>20190301</creationdate><title>Synthesis and characterization of bimetallic catalysts Pd-Ru and Pt-Ru supported on γ-alumina and zeolite FAU for the catalytic transformation of HMF</title><author>Pérez-Bustos, Héctor Fabio ; Lucio-Ortiz, Carlos J. ; de la Rosa, Javier Rivera ; de Haro del Río, David A. ; Sandoval-Rangel, Ladislao ; Martínez-Vargas, Daniela Xulú ; Maldonado, Carolina Solis ; Rodriguez-González, Vicente ; Garza-Navarro, M.A. ; Morales-Leal, Francisco José</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-f5075c5dc8aa3cb453761a0c873b73a59f7f77836a3264ad2861fefeea19abc13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aluminum oxide</topic><topic>Bimetallic</topic><topic>Bimetals</topic><topic>Biofuel</topic><topic>Biofuels</topic><topic>Carbohydrates</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemical compounds</topic><topic>Chemical synthesis</topic><topic>Chemicals</topic><topic>Crystallography</topic><topic>Energy sources</topic><topic>Esterification</topic><topic>Formic acid</topic><topic>Fossil fuels</topic><topic>Furan</topic><topic>Hydrogen storage</topic><topic>Hydroxymethylfurfural</topic><topic>Metals</topic><topic>Organic chemistry</topic><topic>Oxidation</topic><topic>Palladium</topic><topic>Platinum</topic><topic>Ruthenium</topic><topic>Transitional aluminas</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pérez-Bustos, Héctor Fabio</creatorcontrib><creatorcontrib>Lucio-Ortiz, Carlos J.</creatorcontrib><creatorcontrib>de la Rosa, Javier Rivera</creatorcontrib><creatorcontrib>de Haro del Río, David A.</creatorcontrib><creatorcontrib>Sandoval-Rangel, Ladislao</creatorcontrib><creatorcontrib>Martínez-Vargas, Daniela Xulú</creatorcontrib><creatorcontrib>Maldonado, Carolina Solis</creatorcontrib><creatorcontrib>Rodriguez-González, Vicente</creatorcontrib><creatorcontrib>Garza-Navarro, M.A.</creatorcontrib><creatorcontrib>Morales-Leal, Francisco José</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pérez-Bustos, Héctor Fabio</au><au>Lucio-Ortiz, Carlos J.</au><au>de la Rosa, Javier Rivera</au><au>de Haro del Río, David A.</au><au>Sandoval-Rangel, Ladislao</au><au>Martínez-Vargas, Daniela Xulú</au><au>Maldonado, Carolina Solis</au><au>Rodriguez-González, Vicente</au><au>Garza-Navarro, M.A.</au><au>Morales-Leal, Francisco José</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of bimetallic catalysts Pd-Ru and Pt-Ru supported on γ-alumina and zeolite FAU for the catalytic transformation of HMF</atitle><jtitle>Fuel (Guildford)</jtitle><date>2019-03-01</date><risdate>2019</risdate><volume>239</volume><spage>191</spage><epage>201</epage><pages>191-201</pages><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>•Bimetallic catalysts Pd-Ru and Pt-Ru supported on FAU and γ-Al2O3 were synthesized.•Two crystallographic phases coexisting in the synthesized zeolite (LTA and FAU).•The phase FAU prevailing when the material was calcinated at 550 °C.•The formation of the Pd-Ru alloy phase was confirmed by XPS and HRTEM.•Pd-Ru was more selective metal combination to added-value furan derivatives.•Pd-Ru/FAU lost less metal after its first use than Pd-Ru/ γ-Al2O3.•Re-used Pd-Ru/FAU was more selective to furan derivatives and less to byproducts.
It is well known the effects and limitations of the use of fossil fuels, for that reason is necessary to establish alternative sources of energy. The 5-hydroxymethylfurfural (HMF) is a chemical compound that can be obtained from the carbohydrates present in the biomass. Is a key compound for the obtaining of several valuable chemicals, many of them have a promising application as biofuels. In the present work, Pd-Ru and Pt-Ru bimetallic catalysts with low metal content (0.5%) supported on commercial γ-Al2O3 and FAU zeolite prepared by hydrothermal method, were synthesized and characterized to transform HMF into valuable chemicals under mild reaction conditions. Two crystallographic phases were found to coexist in the zeolite synthesized as support, the FAU phase prevailing over the LTA when calcined at 550 °C. The system studied with formic acid as hydrogen donor, under mild reaction conditions, showed a partial hydrogenation of HMF molecule evidenced in the 5-MF and 2,5-DMF formation. Also, a partial oxidation and esterification is happening for the formation of 2,5-DFF and 5-A-2-F, respectively. The catalysts supported on FAU showed better conversion of HMF that catalysts supported on γ-Al2O3. Although all metals showed catalytic activity by separed, Pd-Ru combination was more selective to produce 5-MF, 2,5-DMF and 2,5-DFF than Pt-Ru combination, and showed production of valuable furan derivatives even in their second and thir use. Pd–Ru/FAU catalyst formed a PdRu alloy phase, which can be related to its better catalytic performance.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2018.10.001</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0003-2762-6890</orcidid></addata></record> |
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| subjects | Aluminum oxide Bimetallic Bimetals Biofuel Biofuels Carbohydrates Catalysis Catalysts Catalytic activity Chemical compounds Chemical synthesis Chemicals Crystallography Energy sources Esterification Formic acid Fossil fuels Furan Hydrogen storage Hydroxymethylfurfural Metals Organic chemistry Oxidation Palladium Platinum Ruthenium Transitional aluminas Zeolites |
| title | Synthesis and characterization of bimetallic catalysts Pd-Ru and Pt-Ru supported on γ-alumina and zeolite FAU for the catalytic transformation of HMF |
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