Sulfobridged Polynuclear Complexes of Platinum(II) and Palladium(II)
When the platinum(II) and palladium(II) salts interact with ligands such as cystamine-(mercamine) HSCH 2 CH 2 NH 2 and 2-mercaptoethanol HSCH 2 CH 2 OH under certain conditions, polynuclear complexes of the compositions are obtained: [Pt 6 (SCH 2 CH 2 NH 2 ) 8 ]Cl 4 . 5H 2 O and [Pd 6 (SCH 2 CH 2 OH...
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| Veröffentlicht in: | Moscow University chemistry bulletin 2018-11, Vol.73 (6), p.293-297 |
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| container_title | Moscow University chemistry bulletin |
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| creator | Azizova, A. N. Tagiyev, D. B. Gasimov, Sh. G. Gasanov, Kh. I. |
| description | When the platinum(II) and palladium(II) salts interact with ligands such as cystamine-(mercamine) HSCH
2
CH
2
NH
2
and 2-mercaptoethanol HSCH
2
CH
2
OH under certain conditions, polynuclear complexes of the compositions are obtained: [Pt
6
(SCH
2
CH
2
NH
2
)
8
]Cl
4
. 5H
2
O and [Pd
6
(SCH
2
CH
2
OH)
8
]Cl
4
. In a comparative study of the IR and X-ray spectra of synthesized complexes and ligands, as well as the results of X-ray diffraction studies, it was established that sulfur atoms of 2-mercaptoethanol occupy a bridge position with a mixed coordination of ligands in the palladium complex. In the platinum(II) complex bidentate coordination of ligands is realized through sulfur and nitrogen atoms. |
| doi_str_mv | 10.3103/S0027131418060032 |
| format | Article |
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2
CH
2
NH
2
and 2-mercaptoethanol HSCH
2
CH
2
OH under certain conditions, polynuclear complexes of the compositions are obtained: [Pt
6
(SCH
2
CH
2
NH
2
)
8
]Cl
4
. 5H
2
O and [Pd
6
(SCH
2
CH
2
OH)
8
]Cl
4
. In a comparative study of the IR and X-ray spectra of synthesized complexes and ligands, as well as the results of X-ray diffraction studies, it was established that sulfur atoms of 2-mercaptoethanol occupy a bridge position with a mixed coordination of ligands in the palladium complex. In the platinum(II) complex bidentate coordination of ligands is realized through sulfur and nitrogen atoms.</description><identifier>ISSN: 0027-1314</identifier><identifier>EISSN: 1935-0260</identifier><identifier>DOI: 10.3103/S0027131418060032</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Comparative studies ; Coordination compounds ; Ligands ; Nitrogen atoms ; Palladium ; Platinum ; Sulfur ; X ray spectra ; X-ray diffraction</subject><ispartof>Moscow University chemistry bulletin, 2018-11, Vol.73 (6), p.293-297</ispartof><rights>Allerton Press, Inc. 2018</rights><rights>Copyright Springer Nature B.V. 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c311t-54cc54b0d51b332dbac6cbe4b134f448d53ca593932b16c80d5e34bdab9fa0823</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.3103/S0027131418060032$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.3103/S0027131418060032$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Azizova, A. N.</creatorcontrib><creatorcontrib>Tagiyev, D. B.</creatorcontrib><creatorcontrib>Gasimov, Sh. G.</creatorcontrib><creatorcontrib>Gasanov, Kh. I.</creatorcontrib><title>Sulfobridged Polynuclear Complexes of Platinum(II) and Palladium(II)</title><title>Moscow University chemistry bulletin</title><addtitle>Moscow Univ. Chem. Bull</addtitle><description>When the platinum(II) and palladium(II) salts interact with ligands such as cystamine-(mercamine) HSCH
2
CH
2
NH
2
and 2-mercaptoethanol HSCH
2
CH
2
OH under certain conditions, polynuclear complexes of the compositions are obtained: [Pt
6
(SCH
2
CH
2
NH
2
)
8
]Cl
4
. 5H
2
O and [Pd
6
(SCH
2
CH
2
OH)
8
]Cl
4
. In a comparative study of the IR and X-ray spectra of synthesized complexes and ligands, as well as the results of X-ray diffraction studies, it was established that sulfur atoms of 2-mercaptoethanol occupy a bridge position with a mixed coordination of ligands in the palladium complex. In the platinum(II) complex bidentate coordination of ligands is realized through sulfur and nitrogen atoms.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Comparative studies</subject><subject>Coordination compounds</subject><subject>Ligands</subject><subject>Nitrogen atoms</subject><subject>Palladium</subject><subject>Platinum</subject><subject>Sulfur</subject><subject>X ray spectra</subject><subject>X-ray diffraction</subject><issn>0027-1314</issn><issn>1935-0260</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLAzEUhYMoWB8_wN2AG12M3pubzGMp9VUoWKiuhySTKVPSSU06YP-9U0ZwIa4unPOdc-EwdoVwRwh0vwTgORIKLCADIH7EJliSTIFncMwmBzs9-KfsLMY1gMw45RP2uOxd43Vo65Wtk4V3-643zqqQTP1m6-yXjYlvkoVTu7brNzez2W2iuoFUzqm6HZULdtIoF-3lzz1nH89P79PXdP72Mps-zFNDiLtUCmOk0FBL1ES81spkRluhkUQjRFFLMkqWVBLXmJliAC0JXStdNgoKTufseuzdBv_Z27ir1r4P3fCy4piXQBLyYqBwpEzwMQbbVNvQblTYVwjVYazqz1hDho-ZOLDdyobf5v9D35Coaas</recordid><startdate>20181101</startdate><enddate>20181101</enddate><creator>Azizova, A. N.</creator><creator>Tagiyev, D. B.</creator><creator>Gasimov, Sh. G.</creator><creator>Gasanov, Kh. I.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20181101</creationdate><title>Sulfobridged Polynuclear Complexes of Platinum(II) and Palladium(II)</title><author>Azizova, A. N. ; Tagiyev, D. B. ; Gasimov, Sh. G. ; Gasanov, Kh. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c311t-54cc54b0d51b332dbac6cbe4b134f448d53ca593932b16c80d5e34bdab9fa0823</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Comparative studies</topic><topic>Coordination compounds</topic><topic>Ligands</topic><topic>Nitrogen atoms</topic><topic>Palladium</topic><topic>Platinum</topic><topic>Sulfur</topic><topic>X ray spectra</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Azizova, A. N.</creatorcontrib><creatorcontrib>Tagiyev, D. B.</creatorcontrib><creatorcontrib>Gasimov, Sh. G.</creatorcontrib><creatorcontrib>Gasanov, Kh. I.</creatorcontrib><collection>CrossRef</collection><jtitle>Moscow University chemistry bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Azizova, A. N.</au><au>Tagiyev, D. B.</au><au>Gasimov, Sh. G.</au><au>Gasanov, Kh. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sulfobridged Polynuclear Complexes of Platinum(II) and Palladium(II)</atitle><jtitle>Moscow University chemistry bulletin</jtitle><stitle>Moscow Univ. Chem. Bull</stitle><date>2018-11-01</date><risdate>2018</risdate><volume>73</volume><issue>6</issue><spage>293</spage><epage>297</epage><pages>293-297</pages><issn>0027-1314</issn><eissn>1935-0260</eissn><abstract>When the platinum(II) and palladium(II) salts interact with ligands such as cystamine-(mercamine) HSCH
2
CH
2
NH
2
and 2-mercaptoethanol HSCH
2
CH
2
OH under certain conditions, polynuclear complexes of the compositions are obtained: [Pt
6
(SCH
2
CH
2
NH
2
)
8
]Cl
4
. 5H
2
O and [Pd
6
(SCH
2
CH
2
OH)
8
]Cl
4
. In a comparative study of the IR and X-ray spectra of synthesized complexes and ligands, as well as the results of X-ray diffraction studies, it was established that sulfur atoms of 2-mercaptoethanol occupy a bridge position with a mixed coordination of ligands in the palladium complex. In the platinum(II) complex bidentate coordination of ligands is realized through sulfur and nitrogen atoms.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.3103/S0027131418060032</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Moscow University chemistry bulletin, 2018-11, Vol.73 (6), p.293-297 |
| issn | 0027-1314 1935-0260 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science Comparative studies Coordination compounds Ligands Nitrogen atoms Palladium Platinum Sulfur X ray spectra X-ray diffraction |
| title | Sulfobridged Polynuclear Complexes of Platinum(II) and Palladium(II) |
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