Photoinduced decarboxylative azidation of cyclic amino acids
The direct decarboxylative azidation of cyclic α-amino acids has been achieved via visible light-mediated organo-photoredox catalysis. This synthetic strategy allows the simple preparation of azide-contaning building blocks and has been used in the selective modification of N-terminal proline residu...
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Veröffentlicht in: | Organic & biomolecular chemistry 2019-02, Vol.17 (7), p.1839-1842 |
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container_title | Organic & biomolecular chemistry |
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creator | Marcote, David C Street-Jeakings, Rosie Dauncey, Elizabeth Douglas, James J Ruffoni, Alessandro Leonori, Daniele |
description | The direct decarboxylative azidation of cyclic α-amino acids has been achieved
via
visible light-mediated organo-photoredox catalysis. This synthetic strategy allows the simple preparation of azide-contaning building blocks and has been used in the selective modification of N-terminal proline residues of two di-peptides.
The direct decarboxylative azidation of cyclic α-amino acids has been achieved
via
visible light-mediated organo-photoredox catalysis. |
doi_str_mv | 10.1039/c8ob02702a |
format | Article |
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via
visible light-mediated organo-photoredox catalysis. This synthetic strategy allows the simple preparation of azide-contaning building blocks and has been used in the selective modification of N-terminal proline residues of two di-peptides.
The direct decarboxylative azidation of cyclic α-amino acids has been achieved
via
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via
visible light-mediated organo-photoredox catalysis. This synthetic strategy allows the simple preparation of azide-contaning building blocks and has been used in the selective modification of N-terminal proline residues of two di-peptides.
The direct decarboxylative azidation of cyclic α-amino acids has been achieved
via
visible light-mediated organo-photoredox catalysis.</description><subject>Amino acids</subject><subject>Catalysis</subject><subject>Peptides</subject><subject>Photoredox catalysis</subject><subject>Proline</subject><issn>1477-0520</issn><issn>1477-0539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpd0UtLw0AQB_BFFFurF-9KwIsI1X1lH-ClFl9QqAc9h33iliRbs4lYP73R1gqeZmB-DMN_ADhG8BJBIq-MiBpiDrHaAUNEOR_DnMjdbY_hAByktIAQSc7oPhgQyDCRjAzB9dNrbGOobWeczawzqtHxY1WqNry7TH0G23exzqLPzMqUwWSqCnXMlAk2HYI9r8rkjjZ1BF7ubp-nD-PZ_P5xOpmNDSWyHSujKEKY51QTrLV2WFnGtWPa-lx6T43JRQ6dk0gIobw0XnjMhcqtMDjHZATO13uXTXzrXGqLKiTjylLVLnapwIjljEHKWE_P_tFF7Jq6v65XXEhCuZS9ulgr08SUGueLZRMq1awKBIvvTIupmN_8ZDrp8elmZacrZ7f0N8QenKxBk8x2-vcU8gVqSXsN</recordid><startdate>20190213</startdate><enddate>20190213</enddate><creator>Marcote, David C</creator><creator>Street-Jeakings, Rosie</creator><creator>Dauncey, Elizabeth</creator><creator>Douglas, James J</creator><creator>Ruffoni, Alessandro</creator><creator>Leonori, Daniele</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7T7</scope><scope>7TM</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8617-2548</orcidid><orcidid>https://orcid.org/0000-0002-7692-4504</orcidid><orcidid>https://orcid.org/0000-0002-9681-0459</orcidid><orcidid>https://orcid.org/0000-0002-6953-5615</orcidid></search><sort><creationdate>20190213</creationdate><title>Photoinduced decarboxylative azidation of cyclic amino acids</title><author>Marcote, David C ; Street-Jeakings, Rosie ; Dauncey, Elizabeth ; Douglas, James J ; Ruffoni, Alessandro ; Leonori, Daniele</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c439t-aca4112754b32bbbe2ad67be6bdf59ff4cc5850ee91888af9cf8f278a5d8c2523</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Amino acids</topic><topic>Catalysis</topic><topic>Peptides</topic><topic>Photoredox catalysis</topic><topic>Proline</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Marcote, David C</creatorcontrib><creatorcontrib>Street-Jeakings, Rosie</creatorcontrib><creatorcontrib>Dauncey, Elizabeth</creatorcontrib><creatorcontrib>Douglas, James J</creatorcontrib><creatorcontrib>Ruffoni, Alessandro</creatorcontrib><creatorcontrib>Leonori, Daniele</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Nucleic Acids Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Organic & biomolecular chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Marcote, David C</au><au>Street-Jeakings, Rosie</au><au>Dauncey, Elizabeth</au><au>Douglas, James J</au><au>Ruffoni, Alessandro</au><au>Leonori, Daniele</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photoinduced decarboxylative azidation of cyclic amino acids</atitle><jtitle>Organic & biomolecular chemistry</jtitle><addtitle>Org Biomol Chem</addtitle><date>2019-02-13</date><risdate>2019</risdate><volume>17</volume><issue>7</issue><spage>1839</spage><epage>1842</epage><pages>1839-1842</pages><issn>1477-0520</issn><eissn>1477-0539</eissn><abstract>The direct decarboxylative azidation of cyclic α-amino acids has been achieved
via
visible light-mediated organo-photoredox catalysis. This synthetic strategy allows the simple preparation of azide-contaning building blocks and has been used in the selective modification of N-terminal proline residues of two di-peptides.
The direct decarboxylative azidation of cyclic α-amino acids has been achieved
via
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language | eng |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Amino acids Catalysis Peptides Photoredox catalysis Proline |
title | Photoinduced decarboxylative azidation of cyclic amino acids |
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