Theory of the voltammetric response of electrodes of submicron dimensions. Violation of electroneutrality in the presence of excess supporting electrolyte
The steady-state voltammetric behavior of spherical electrodes of nanometer dimensions is computed by numerical solution of the Nernst-Planck and Poisson equations. The results are discussed in terms of a recent report of unusually large heterogeneous rate constants obtained by steady-state voltamet...
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| Veröffentlicht in: | Analytical chemistry (Washington) 1993-12, Vol.65 (23), p.3343-3353 |
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| container_title | Analytical chemistry (Washington) |
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| creator | Smith, Christopher P White, Henry S |
| description | The steady-state voltammetric behavior of spherical electrodes of nanometer dimensions is computed by numerical solution of the Nernst-Planck and Poisson equations. The results are discussed in terms of a recent report of unusually large heterogeneous rate constants obtained by steady-state voltametry at electrodes of nanometer dimensions. |
| doi_str_mv | 10.1021/ac00071a002 |
| format | Article |
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| fulltext | fulltext |
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| ispartof | Analytical chemistry (Washington), 1993-12, Vol.65 (23), p.3343-3353 |
| issn | 0003-2700 1520-6882 |
| language | eng |
| recordid | cdi_proquest_journals_217889550 |
| source | ACS Publications |
| subjects | Chemistry Electrochemistry Electrodes: preparations and properties Exact sciences and technology General and physical chemistry Other electrodes |
| title | Theory of the voltammetric response of electrodes of submicron dimensions. Violation of electroneutrality in the presence of excess supporting electrolyte |
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