Zinc polyoxometalate immobilized on ionic liquid-modified MCM-41: an efficient reusable catalyst for the selective oxidation of alcohols with hydrogen peroxide
In this study, Keggin-type polyoxometalate [n-C 4 H 9 ) 4 N] x [PW 11 ZnO 39 ].nH 2 O was successfully immobilized on imidazole-functionalized ionic liquid-modified mesoporous MCM-41 by physical adsorption. The PW 11 Zn@MCM-41-Im was characterized by FT-IR, ICP, XRD, SEM, nitrogen adsorption and des...
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| Veröffentlicht in: | Journal of the Iranian Chemical Society 2019-03, Vol.16 (3), p.563-570 |
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| creator | Hajian, Robabeh Jafari, Fereshteh |
| description | In this study, Keggin-type polyoxometalate [n-C
4
H
9
)
4
N]
x
[PW
11
ZnO
39
].nH
2
O was successfully immobilized on imidazole-functionalized ionic liquid-modified mesoporous MCM-41 by physical adsorption. The PW
11
Zn@MCM-41-Im was characterized by FT-IR, ICP, XRD, SEM, nitrogen adsorption and desorption and DRUV–Vis analysis. The results indicated that ZnPW
11
could be successfully immobilized on mesoporous MCM-41-Im. This heterogeneous catalyst showed high catalytic performance and excellent selectivity in the oxidation of alcohols to the corresponding carbonyl groups with hydrogen peroxide. Furthermore, the supported ionic liquid catalyst was recovered by simple filtration and reused in four reaction runs with the preserve of the catalytic activity. |
| doi_str_mv | 10.1007/s13738-018-1534-5 |
| format | Article |
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4
H
9
)
4
N]
x
[PW
11
ZnO
39
].nH
2
O was successfully immobilized on imidazole-functionalized ionic liquid-modified mesoporous MCM-41 by physical adsorption. The PW
11
Zn@MCM-41-Im was characterized by FT-IR, ICP, XRD, SEM, nitrogen adsorption and desorption and DRUV–Vis analysis. The results indicated that ZnPW
11
could be successfully immobilized on mesoporous MCM-41-Im. This heterogeneous catalyst showed high catalytic performance and excellent selectivity in the oxidation of alcohols to the corresponding carbonyl groups with hydrogen peroxide. Furthermore, the supported ionic liquid catalyst was recovered by simple filtration and reused in four reaction runs with the preserve of the catalytic activity.</description><identifier>ISSN: 1735-207X</identifier><identifier>EISSN: 1735-2428</identifier><identifier>DOI: 10.1007/s13738-018-1534-5</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Adsorption ; Alcohol ; Alcohols ; Analytical Chemistry ; Biochemistry ; Carbonyl groups ; Carbonyls ; Catalysis ; Catalysts ; Catalytic activity ; Chemistry ; Chemistry and Materials Science ; Hydrogen peroxide ; Imidazole ; Inorganic Chemistry ; Ionic liquids ; Ions ; Organic Chemistry ; Original Paper ; Oxidation ; Physical Chemistry ; Selectivity ; Solvents</subject><ispartof>Journal of the Iranian Chemical Society, 2019-03, Vol.16 (3), p.563-570</ispartof><rights>Iranian Chemical Society 2018</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-fd684e52e108a7b5657a6c5249be21f87be216abc4d7301cbf3d54f213f6ac723</citedby><cites>FETCH-LOGICAL-c316t-fd684e52e108a7b5657a6c5249be21f87be216abc4d7301cbf3d54f213f6ac723</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13738-018-1534-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13738-018-1534-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27911,27912,41475,42544,51306</link.rule.ids></links><search><creatorcontrib>Hajian, Robabeh</creatorcontrib><creatorcontrib>Jafari, Fereshteh</creatorcontrib><title>Zinc polyoxometalate immobilized on ionic liquid-modified MCM-41: an efficient reusable catalyst for the selective oxidation of alcohols with hydrogen peroxide</title><title>Journal of the Iranian Chemical Society</title><addtitle>J IRAN CHEM SOC</addtitle><description>In this study, Keggin-type polyoxometalate [n-C
4
H
9
)
4
N]
x
[PW
11
ZnO
39
].nH
2
O was successfully immobilized on imidazole-functionalized ionic liquid-modified mesoporous MCM-41 by physical adsorption. The PW
11
Zn@MCM-41-Im was characterized by FT-IR, ICP, XRD, SEM, nitrogen adsorption and desorption and DRUV–Vis analysis. The results indicated that ZnPW
11
could be successfully immobilized on mesoporous MCM-41-Im. This heterogeneous catalyst showed high catalytic performance and excellent selectivity in the oxidation of alcohols to the corresponding carbonyl groups with hydrogen peroxide. Furthermore, the supported ionic liquid catalyst was recovered by simple filtration and reused in four reaction runs with the preserve of the catalytic activity.</description><subject>Adsorption</subject><subject>Alcohol</subject><subject>Alcohols</subject><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Carbonyl groups</subject><subject>Carbonyls</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Hydrogen peroxide</subject><subject>Imidazole</subject><subject>Inorganic Chemistry</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Oxidation</subject><subject>Physical Chemistry</subject><subject>Selectivity</subject><subject>Solvents</subject><issn>1735-207X</issn><issn>1735-2428</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kctOHDEQRVsRSOGRD8iupKxN_Gi3O9lFo0CQBmUTJMTGcrvLjJG7PdiehOFn-FU8GlBWrKqkOvfU4jbNZ0bPGKXqa2ZCiZ5Q1hMmRUvkh-aIKSEJb3l_8LZTdfOxOc75nlKpqGyPmudbP1tYx7CNj3HCYoIpCH6a4uCDf8IR4gw-zt5C8A8bP5Ipjt75erhaXJGWfQczAzrnrce5QMJNNkNAsKa6trmAiwnKCiFjQFv8X4T46EdTqhSiAxNsXMWQ4Z8vK1htxxTvcIY1ph2Gp82hMyHjp9d50lyf__yz-EWWvy8uFz-WxArWFeLGrm9RcmS0N2qQnVSms5K33wbkzPVqNzoz2HZUgjI7ODHK1nEmXGes4uKk-bL3rlN82GAu-j5u0lxfas5UX32c9pVie8qmmHNCp9fJTyZtNaN614Pe96BrD3rXg5Y1w_eZXNn5DtN_8_uhF6wSjnc</recordid><startdate>20190313</startdate><enddate>20190313</enddate><creator>Hajian, Robabeh</creator><creator>Jafari, Fereshteh</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20190313</creationdate><title>Zinc polyoxometalate immobilized on ionic liquid-modified MCM-41: an efficient reusable catalyst for the selective oxidation of alcohols with hydrogen peroxide</title><author>Hajian, Robabeh ; Jafari, Fereshteh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-fd684e52e108a7b5657a6c5249be21f87be216abc4d7301cbf3d54f213f6ac723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Adsorption</topic><topic>Alcohol</topic><topic>Alcohols</topic><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Carbonyl groups</topic><topic>Carbonyls</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Hydrogen peroxide</topic><topic>Imidazole</topic><topic>Inorganic Chemistry</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Oxidation</topic><topic>Physical Chemistry</topic><topic>Selectivity</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hajian, Robabeh</creatorcontrib><creatorcontrib>Jafari, Fereshteh</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the Iranian Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hajian, Robabeh</au><au>Jafari, Fereshteh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Zinc polyoxometalate immobilized on ionic liquid-modified MCM-41: an efficient reusable catalyst for the selective oxidation of alcohols with hydrogen peroxide</atitle><jtitle>Journal of the Iranian Chemical Society</jtitle><stitle>J IRAN CHEM SOC</stitle><date>2019-03-13</date><risdate>2019</risdate><volume>16</volume><issue>3</issue><spage>563</spage><epage>570</epage><pages>563-570</pages><issn>1735-207X</issn><eissn>1735-2428</eissn><abstract>In this study, Keggin-type polyoxometalate [n-C
4
H
9
)
4
N]
x
[PW
11
ZnO
39
].nH
2
O was successfully immobilized on imidazole-functionalized ionic liquid-modified mesoporous MCM-41 by physical adsorption. The PW
11
Zn@MCM-41-Im was characterized by FT-IR, ICP, XRD, SEM, nitrogen adsorption and desorption and DRUV–Vis analysis. The results indicated that ZnPW
11
could be successfully immobilized on mesoporous MCM-41-Im. This heterogeneous catalyst showed high catalytic performance and excellent selectivity in the oxidation of alcohols to the corresponding carbonyl groups with hydrogen peroxide. Furthermore, the supported ionic liquid catalyst was recovered by simple filtration and reused in four reaction runs with the preserve of the catalytic activity.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13738-018-1534-5</doi><tpages>8</tpages></addata></record> |
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| ispartof | Journal of the Iranian Chemical Society, 2019-03, Vol.16 (3), p.563-570 |
| issn | 1735-207X 1735-2428 |
| language | eng |
| recordid | cdi_proquest_journals_2178657208 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Adsorption Alcohol Alcohols Analytical Chemistry Biochemistry Carbonyl groups Carbonyls Catalysis Catalysts Catalytic activity Chemistry Chemistry and Materials Science Hydrogen peroxide Imidazole Inorganic Chemistry Ionic liquids Ions Organic Chemistry Original Paper Oxidation Physical Chemistry Selectivity Solvents |
| title | Zinc polyoxometalate immobilized on ionic liquid-modified MCM-41: an efficient reusable catalyst for the selective oxidation of alcohols with hydrogen peroxide |
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