Simple tertiary amines as promotors in oxygen tolerant photochemically induced ATRP of acrylates

Well-defined poly(methyl acrylate) (PMA) and poly(n-butyl acrylate) (PBA) are prepared via photochemically induced atom transfer radical polymerization (photoATRP) using ppm amounts of CuBr2/tris[2-(dimethylamino)ethyl]amine (Me6TREN) catalyst complex without degassing of the polymerization mixture....

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Polymer (Guilford) 2019-01, Vol.161, p.122-127
Hauptverfasser:	Bondarev, Dmitrij, Borská, Katarína, Šoral, Michal, Moravčíková, Daniela, Mosnáček, Jaroslav
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylates Acrylic resins Acrylics Amines Atom transfer radical polymerization Chemical industry Controlled architecture Controlled polymerization Copper bromide Degassing Kinetics Ligands Light intensity Luminous intensity Oxygen Oxygen tolerance Photopolymerization Polymerization Reaction kinetics Triethylamine
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!