Effect of MnS precipitation on solute equilibrium partition coefficients in high sulfur steel during solidification
The solute equilibrium partition coefficients (ki) of C, Si, Mn, P, and S in high sulfur steel during the solidification process were investigated by the thermodynamic calculation. The effect of MnS precipitation on ki was explored. The results showed that the precipitation of MnS inclusion would in...
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| Veröffentlicht in: | Journal of materials research 2018-10, Vol.33 (20), p.3490-3500 |
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| creator | Gui, Lintao Long, Mujun Chen, Huabiao Chen, Dengfu Duan, Huamei Huang, Yunwei Liu, Tao |
| description | The solute equilibrium partition coefficients (ki) of C, Si, Mn, P, and S in high sulfur steel during the solidification process were investigated by the thermodynamic calculation. The effect of MnS precipitation on ki was explored. The results showed that the precipitation of MnS inclusion would influence the concentrations of solutes Mn and S, leading to the changing of ki. Due to the precipitation of MnS, the kC and kS decreased first and then increased with temperature decreasing, while kSi, kMn, and kP changed monotonously. The impacts of solidification temperature on kSi and kMn were greater than that on kC, kS, and kP. With the increase of S content, kC, kSi, and kP increased while kMn and kS decreased. Whereas, an opposite effect was found with the increase of Mn content. The order of influence extent by S and Mn contents was kSi > kS > kMn > kC > kP. |
| doi_str_mv | 10.1557/jmr.2018.121 |
| format | Article |
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The effect of MnS precipitation on ki was explored. The results showed that the precipitation of MnS inclusion would influence the concentrations of solutes Mn and S, leading to the changing of ki. Due to the precipitation of MnS, the kC and kS decreased first and then increased with temperature decreasing, while kSi, kMn, and kP changed monotonously. The impacts of solidification temperature on kSi and kMn were greater than that on kC, kS, and kP. With the increase of S content, kC, kSi, and kP increased while kMn and kS decreased. Whereas, an opposite effect was found with the increase of Mn content. The order of influence extent by S and Mn contents was kSi > kS > kMn > kC > kP.</description><identifier>ISSN: 0884-2914</identifier><identifier>EISSN: 2044-5326</identifier><identifier>DOI: 10.1557/jmr.2018.121</identifier><language>eng</language><publisher>New York, USA: Cambridge University Press</publisher><subject>Alloy solidification ; Applied and Technical Physics ; Biomaterials ; Carbon ; Chemical partition ; Chemical precipitation ; Continuous casting ; Equilibrium ; Inorganic Chemistry ; Manganese ; Materials Engineering ; Materials research ; Materials Science ; Nanotechnology ; Partitions ; Phase transitions ; Solidification ; Solids ; Sulfur</subject><ispartof>Journal of materials research, 2018-10, Vol.33 (20), p.3490-3500</ispartof><rights>Copyright © Materials Research Society 2018</rights><rights>The Materials Research Society 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c406t-389a7dfcd9b653e215f293b776dfc11abeb72ddfbb3a706445e50ca0678155483</citedby><cites>FETCH-LOGICAL-c406t-389a7dfcd9b653e215f293b776dfc11abeb72ddfbb3a706445e50ca0678155483</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1557/jmr.2018.121$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.cambridge.org/core/product/identifier/S0884291418001218/type/journal_article$$EHTML$$P50$$Gcambridge$$H</linktohtml><link.rule.ids>164,314,776,780,27903,27904,41467,42536,51298,55607</link.rule.ids></links><search><creatorcontrib>Gui, Lintao</creatorcontrib><creatorcontrib>Long, Mujun</creatorcontrib><creatorcontrib>Chen, Huabiao</creatorcontrib><creatorcontrib>Chen, Dengfu</creatorcontrib><creatorcontrib>Duan, Huamei</creatorcontrib><creatorcontrib>Huang, Yunwei</creatorcontrib><creatorcontrib>Liu, Tao</creatorcontrib><title>Effect of MnS precipitation on solute equilibrium partition coefficients in high sulfur steel during solidification</title><title>Journal of materials research</title><addtitle>Journal of Materials Research</addtitle><addtitle>J. Mater. Res</addtitle><description>The solute equilibrium partition coefficients (ki) of C, Si, Mn, P, and S in high sulfur steel during the solidification process were investigated by the thermodynamic calculation. The effect of MnS precipitation on ki was explored. The results showed that the precipitation of MnS inclusion would influence the concentrations of solutes Mn and S, leading to the changing of ki. Due to the precipitation of MnS, the kC and kS decreased first and then increased with temperature decreasing, while kSi, kMn, and kP changed monotonously. The impacts of solidification temperature on kSi and kMn were greater than that on kC, kS, and kP. With the increase of S content, kC, kSi, and kP increased while kMn and kS decreased. Whereas, an opposite effect was found with the increase of Mn content. The order of influence extent by S and Mn contents was kSi > kS > kMn > kC > kP.</description><subject>Alloy solidification</subject><subject>Applied and Technical Physics</subject><subject>Biomaterials</subject><subject>Carbon</subject><subject>Chemical partition</subject><subject>Chemical precipitation</subject><subject>Continuous casting</subject><subject>Equilibrium</subject><subject>Inorganic Chemistry</subject><subject>Manganese</subject><subject>Materials Engineering</subject><subject>Materials research</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Partitions</subject><subject>Phase transitions</subject><subject>Solidification</subject><subject>Solids</subject><subject>Sulfur</subject><issn>0884-2914</issn><issn>2044-5326</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqFkMtKAzEUQIMoWKs7PyDg1hmTTDKZLqXUB1RcqOuQySRtyryax8K_N9MWXIkQCCQn55IDwC1GOWaMP-w6lxOEqxwTfAZmBFGasYKU52CGqopmZIHpJbjyfocQZojTGfArY7QKcDDwrf-Ao9PKjjbIYIcepuWHNgYN9T7a1tbOxg6O0gV7uFeDNsYqq_vgoe3h1m620MfWRAd90LqFTXS230wW29iEHrzX4MLI1uub0z4HX0-rz-VLtn5_fl0-rjNFURmyolpI3hjVLOqSFZpgZsiiqDkv0yHGstY1J01j6rqQHJWUMs2QkqjkVapBq2IO7o7e0Q37qH0QuyG6Po0UBPMSV5hUNFH3R0q5wXunjRid7aT7FhiJKatIWcWUVaSsCc-OuB-nr2n3K_2Dz0962aV-zUb_8-AHHMmLpA</recordid><startdate>20181029</startdate><enddate>20181029</enddate><creator>Gui, Lintao</creator><creator>Long, Mujun</creator><creator>Chen, Huabiao</creator><creator>Chen, Dengfu</creator><creator>Duan, Huamei</creator><creator>Huang, Yunwei</creator><creator>Liu, Tao</creator><general>Cambridge University Press</general><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>0U~</scope><scope>1-H</scope><scope>3V.</scope><scope>7SR</scope><scope>7WY</scope><scope>7WZ</scope><scope>7XB</scope><scope>87Z</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8FL</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FRNLG</scope><scope>F~G</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K60</scope><scope>K6~</scope><scope>KB.</scope><scope>L.-</scope><scope>L.0</scope><scope>M0C</scope><scope>PDBOC</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>S0W</scope></search><sort><creationdate>20181029</creationdate><title>Effect of MnS precipitation on solute equilibrium partition coefficients in high sulfur steel during solidification</title><author>Gui, Lintao ; Long, Mujun ; Chen, Huabiao ; Chen, Dengfu ; Duan, Huamei ; Huang, Yunwei ; Liu, Tao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c406t-389a7dfcd9b653e215f293b776dfc11abeb72ddfbb3a706445e50ca0678155483</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Alloy solidification</topic><topic>Applied and Technical Physics</topic><topic>Biomaterials</topic><topic>Carbon</topic><topic>Chemical partition</topic><topic>Chemical precipitation</topic><topic>Continuous casting</topic><topic>Equilibrium</topic><topic>Inorganic Chemistry</topic><topic>Manganese</topic><topic>Materials Engineering</topic><topic>Materials research</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Partitions</topic><topic>Phase transitions</topic><topic>Solidification</topic><topic>Solids</topic><topic>Sulfur</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gui, Lintao</creatorcontrib><creatorcontrib>Long, Mujun</creatorcontrib><creatorcontrib>Chen, Huabiao</creatorcontrib><creatorcontrib>Chen, Dengfu</creatorcontrib><creatorcontrib>Duan, Huamei</creatorcontrib><creatorcontrib>Huang, Yunwei</creatorcontrib><creatorcontrib>Liu, Tao</creatorcontrib><collection>CrossRef</collection><collection>Global News & ABI/Inform Professional</collection><collection>Trade PRO</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Global (Alumni Edition)</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Business Premium Collection (Alumni)</collection><collection>ABI/INFORM Global (Corporate)</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>Materials Science Database</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Professional Standard</collection><collection>ABI/INFORM Global</collection><collection>Materials Science Collection</collection><collection>ProQuest One Business</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gui, Lintao</au><au>Long, Mujun</au><au>Chen, Huabiao</au><au>Chen, Dengfu</au><au>Duan, Huamei</au><au>Huang, Yunwei</au><au>Liu, Tao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of MnS precipitation on solute equilibrium partition coefficients in high sulfur steel during solidification</atitle><jtitle>Journal of materials research</jtitle><stitle>Journal of Materials Research</stitle><addtitle>J. Mater. Res</addtitle><date>2018-10-29</date><risdate>2018</risdate><volume>33</volume><issue>20</issue><spage>3490</spage><epage>3500</epage><pages>3490-3500</pages><issn>0884-2914</issn><eissn>2044-5326</eissn><abstract>The solute equilibrium partition coefficients (ki) of C, Si, Mn, P, and S in high sulfur steel during the solidification process were investigated by the thermodynamic calculation. The effect of MnS precipitation on ki was explored. The results showed that the precipitation of MnS inclusion would influence the concentrations of solutes Mn and S, leading to the changing of ki. Due to the precipitation of MnS, the kC and kS decreased first and then increased with temperature decreasing, while kSi, kMn, and kP changed monotonously. The impacts of solidification temperature on kSi and kMn were greater than that on kC, kS, and kP. With the increase of S content, kC, kSi, and kP increased while kMn and kS decreased. Whereas, an opposite effect was found with the increase of Mn content. The order of influence extent by S and Mn contents was kSi > kS > kMn > kC > kP.</abstract><cop>New York, USA</cop><pub>Cambridge University Press</pub><doi>10.1557/jmr.2018.121</doi><tpages>11</tpages></addata></record> |
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| subjects | Alloy solidification Applied and Technical Physics Biomaterials Carbon Chemical partition Chemical precipitation Continuous casting Equilibrium Inorganic Chemistry Manganese Materials Engineering Materials research Materials Science Nanotechnology Partitions Phase transitions Solidification Solids Sulfur |
| title | Effect of MnS precipitation on solute equilibrium partition coefficients in high sulfur steel during solidification |
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