Assembling [M(P 4 Mo 6 ) 2 ] (M = Na, Mn, Na/Cu) dimeric clusters via transition metal/sodium ions into 0D to 3D phosphomolybdates

Six phosphomolybdate compounds based on the sandwich-type cluster [M(P 4 Mo 6 X 31 ) 2 ] (M = Na, Mn, Na/Cu; X = O or OH) have been solvothermally synthesized by using various organic/inorganic cations as templates, namely, (H 3 AEP) 4 [Na(P 4 Mo 6 O 31 H 5.5 ) 2 ]·4H 2 O ( 1 ), (Me 2 NH 2 ) 7 [NaMn...

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