ZnO as photocatalyst for photoinduced electron transfer–reversible addition–fragmentation chain transfer of methyl methacrylate
In this article, photoinduced electron transfer–reversible addition–fragmentation chain transfer (PET‐RAFT) polymerization of methyl methacrylate (MMA) was investigated at moderate temperature in N,N‐dimethylformamide with ZnO as photocatalyst. The polymerization has a living characteristic: a linea...
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| Veröffentlicht in: | Advances in polymer technology 2018-12, Vol.37 (8), p.2879-2884 |
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| container_title | Advances in polymer technology |
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| creator | Liang, Enxiang Liu, Mu‐sheng He, Binhong Wang, Guo‐Xiang |
| description | In this article, photoinduced electron transfer–reversible addition–fragmentation chain transfer (PET‐RAFT) polymerization of methyl methacrylate (MMA) was investigated at moderate temperature in N,N‐dimethylformamide with ZnO as photocatalyst. The polymerization has a living characteristic: a linear increase in molecular weight (Mn,GPC), good agreement between experimental (Mn,GPC) and theoretical molecular weights (Mn,th), a decrease in molecular weight distribution (Mw/Mn) with increasing monomer conversion, and chain extension. The PET‐RAFT polymerization of MMA can be regulated by switching “ON” and “OFF” the light. |
| doi_str_mv | 10.1002/adv.21959 |
| format | Article |
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The polymerization has a living characteristic: a linear increase in molecular weight (Mn,GPC), good agreement between experimental (Mn,GPC) and theoretical molecular weights (Mn,th), a decrease in molecular weight distribution (Mw/Mn) with increasing monomer conversion, and chain extension. The PET‐RAFT polymerization of MMA can be regulated by switching “ON” and “OFF” the light.</description><identifier>ISSN: 0730-6679</identifier><identifier>EISSN: 1098-2329</identifier><identifier>DOI: 10.1002/adv.21959</identifier><language>eng</language><publisher>London: Hindawi Limited</publisher><subject>Addition polymerization ; Chain transfer ; Electron transfer ; Fragmentation ; living radical polymerization ; methyl methacrylate ; Molecular weight ; Molecular weight distribution ; photocatalyst ; Photocatalysts ; photoinduced electron transfer–reversible addition–fragmentation chain transfer ; Polymerization ; Polymethyl methacrylate ; Zinc oxide ; ZnO</subject><ispartof>Advances in polymer technology, 2018-12, Vol.37 (8), p.2879-2884</ispartof><rights>2018 Wiley Periodicals, Inc.</rights><rights>Copyright © 2019 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3699-ec3c31fde5d66cc7abb402cbe53a10eef2960d23f9837210e4a6ff736ef459573</citedby><cites>FETCH-LOGICAL-c3699-ec3c31fde5d66cc7abb402cbe53a10eef2960d23f9837210e4a6ff736ef459573</cites><orcidid>0000-0002-7467-7466</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Liang, Enxiang</creatorcontrib><creatorcontrib>Liu, Mu‐sheng</creatorcontrib><creatorcontrib>He, Binhong</creatorcontrib><creatorcontrib>Wang, Guo‐Xiang</creatorcontrib><title>ZnO as photocatalyst for photoinduced electron transfer–reversible addition–fragmentation chain transfer of methyl methacrylate</title><title>Advances in polymer technology</title><description>In this article, photoinduced electron transfer–reversible addition–fragmentation chain transfer (PET‐RAFT) polymerization of methyl methacrylate (MMA) was investigated at moderate temperature in N,N‐dimethylformamide with ZnO as photocatalyst. The polymerization has a living characteristic: a linear increase in molecular weight (Mn,GPC), good agreement between experimental (Mn,GPC) and theoretical molecular weights (Mn,th), a decrease in molecular weight distribution (Mw/Mn) with increasing monomer conversion, and chain extension. The PET‐RAFT polymerization of MMA can be regulated by switching “ON” and “OFF” the light.</description><subject>Addition polymerization</subject><subject>Chain transfer</subject><subject>Electron transfer</subject><subject>Fragmentation</subject><subject>living radical polymerization</subject><subject>methyl methacrylate</subject><subject>Molecular weight</subject><subject>Molecular weight distribution</subject><subject>photocatalyst</subject><subject>Photocatalysts</subject><subject>photoinduced electron transfer–reversible addition–fragmentation chain transfer</subject><subject>Polymerization</subject><subject>Polymethyl methacrylate</subject><subject>Zinc oxide</subject><subject>ZnO</subject><issn>0730-6679</issn><issn>1098-2329</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kL1OwzAUhS0EEqUw8AaWmBjS-idx6rEqv1KlLsDAYjnONU2VxsV2i7Ih8Qi8IU9CSpCYmI7O0XfulQ5C55SMKCFsrMvdiFGZyQM0oEROEsaZPEQDknOSCJHLY3QSwooQSlPBB-jjuVlgHfBm6aIzOuq6DRFb5_ukasqtgRJDDSZ61-DodRMs-K_3Tw878KEqasC6LKtYuaZLrdcva2ii3ntslrr6K2Fn8Rrisq1_RBvf1jrCKTqyug5w9qtD9Hhz_TC7S-aL2_vZdJ4YLqRMwHDDqS0hK4UwJtdFkRJmCsi4pgTAMilIybiVE56zLkm1sDbnAmyaySznQ3TR391497qFENXKbX3TvVSM5iwjaUYnHXXZU8a7EDxYtfHVWvtWUaL2G6tuY_WzcceOe_atqqH9H1TTq6e-8Q3x84Pc</recordid><startdate>201812</startdate><enddate>201812</enddate><creator>Liang, Enxiang</creator><creator>Liu, Mu‐sheng</creator><creator>He, Binhong</creator><creator>Wang, Guo‐Xiang</creator><general>Hindawi Limited</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-7467-7466</orcidid></search><sort><creationdate>201812</creationdate><title>ZnO as photocatalyst for photoinduced electron transfer–reversible addition–fragmentation chain transfer of methyl methacrylate</title><author>Liang, Enxiang ; Liu, Mu‐sheng ; He, Binhong ; Wang, Guo‐Xiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3699-ec3c31fde5d66cc7abb402cbe53a10eef2960d23f9837210e4a6ff736ef459573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Addition polymerization</topic><topic>Chain transfer</topic><topic>Electron transfer</topic><topic>Fragmentation</topic><topic>living radical polymerization</topic><topic>methyl methacrylate</topic><topic>Molecular weight</topic><topic>Molecular weight distribution</topic><topic>photocatalyst</topic><topic>Photocatalysts</topic><topic>photoinduced electron transfer–reversible addition–fragmentation chain transfer</topic><topic>Polymerization</topic><topic>Polymethyl methacrylate</topic><topic>Zinc oxide</topic><topic>ZnO</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liang, Enxiang</creatorcontrib><creatorcontrib>Liu, Mu‐sheng</creatorcontrib><creatorcontrib>He, Binhong</creatorcontrib><creatorcontrib>Wang, Guo‐Xiang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Advances in polymer technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liang, Enxiang</au><au>Liu, Mu‐sheng</au><au>He, Binhong</au><au>Wang, Guo‐Xiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>ZnO as photocatalyst for photoinduced electron transfer–reversible addition–fragmentation chain transfer of methyl methacrylate</atitle><jtitle>Advances in polymer technology</jtitle><date>2018-12</date><risdate>2018</risdate><volume>37</volume><issue>8</issue><spage>2879</spage><epage>2884</epage><pages>2879-2884</pages><issn>0730-6679</issn><eissn>1098-2329</eissn><abstract>In this article, photoinduced electron transfer–reversible addition–fragmentation chain transfer (PET‐RAFT) polymerization of methyl methacrylate (MMA) was investigated at moderate temperature in N,N‐dimethylformamide with ZnO as photocatalyst. 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| language | eng |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Alma/SFX Local Collection |
| subjects | Addition polymerization Chain transfer Electron transfer Fragmentation living radical polymerization methyl methacrylate Molecular weight Molecular weight distribution photocatalyst Photocatalysts photoinduced electron transfer–reversible addition–fragmentation chain transfer Polymerization Polymethyl methacrylate Zinc oxide ZnO |
| title | ZnO as photocatalyst for photoinduced electron transfer–reversible addition–fragmentation chain transfer of methyl methacrylate |
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