Reaction of arylhydrazines with diaryl ditellurides in the air: Insight into bimolecular homolytic substitution on tellurium via Aryl–Te bond cleavage

The reactivity of diaryl ditelluride and diaryl telluride toward aryl radicals was studied in detail. Diphenyl ditelluride underwent a bimolecular homolytic substitution (SH2) reaction with a phenyl radical generated from phenylhydrazine in the air, to afford diphenyl telluride in excellent yield. B...

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Veröffentlicht in:	Heteroatom chemistry 2018-12, Vol.29 (5-6), p.n/a
Hauptverfasser:	Yamamoto, Yuki, Sato, Fumiya, Kodama, Shintaro, Nomoto, Akihiro, Ogawa, Akiya
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds aryl radical Chemical synthesis Intermetallic compounds Selectivity SH2 Reaction Substitution reactions Tellurides Tellurium
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