Photoreactions of Sc3N@Ih‐C80 and Lu3N@Ih‐C80 with disilirane: Isolation and characterization of labile 1,2‐adducts

The photolysis of Sc3N@Ih‐C80 with disilirane (1,2‐disilacyclopropane) afforded the corresponding 1,2‐ and 1,4‐adducts. The relatively unstable 1,2‐product was characterized using spectroscopic and electrochemical analyses, and theoretical calculations. The relative energies of the optimized structu...

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Veröffentlicht in:	Heteroatom chemistry 2018-12, Vol.29 (5-6), p.n/a
Hauptverfasser:	Kako, Masahiro, Ozeki, Fumiaki, Kanzawa, Shinji, Fukazawa, Shinpei, Sato, Kumiko, Yamada, Michio, Maeda, Yutaka, Furukawa, Makoto, Akasaka, Takeshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Derivatives disilirane endohedral metallofullerene fullerene Isomerization organosilicon compound Photolysis Sc3N@C80 & Lu3N@C80
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