Photoreactions of Sc3N@Ih‐C80 and Lu3N@Ih‐C80 with disilirane: Isolation and characterization of labile 1,2‐adducts
The photolysis of Sc3N@Ih‐C80 with disilirane (1,2‐disilacyclopropane) afforded the corresponding 1,2‐ and 1,4‐adducts. The relatively unstable 1,2‐product was characterized using spectroscopic and electrochemical analyses, and theoretical calculations. The relative energies of the optimized structu...
Gespeichert in:
| Veröffentlicht in: | Heteroatom chemistry 2018-12, Vol.29 (5-6), p.n/a |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 5-6 |
| container_start_page | |
| container_title | Heteroatom chemistry |
| container_volume | 29 |
| creator | Kako, Masahiro Ozeki, Fumiaki Kanzawa, Shinji Fukazawa, Shinpei Sato, Kumiko Yamada, Michio Maeda, Yutaka Furukawa, Makoto Akasaka, Takeshi |
| description | The photolysis of Sc3N@Ih‐C80 with disilirane (1,2‐disilacyclopropane) afforded the corresponding 1,2‐ and 1,4‐adducts. The relatively unstable 1,2‐product was characterized using spectroscopic and electrochemical analyses, and theoretical calculations. The relative energies of the optimized structures are consistent with the experimentally observed isomerization of the 1,2‐adduct to the 1,4‐adduct. The electron‐donating effects of the silyl groups in these products were confirmed by comparing the redox potentials of the related Sc3N@Ih‐C80 derivatives. The relative stabilities and electronic properties of the 1,2‐ and 1,4‐adducts of Lu3N@Ih‐C80 show similar aspects to those obtained for the corresponding Sc3N@Ih‐C80 derivatives. |
| doi_str_mv | 10.1002/hc.21477 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_wiley</sourceid><recordid>TN_cdi_proquest_journals_2171603207</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2171603207</sourcerecordid><originalsourceid>FETCH-LOGICAL-p2217-d78c40042b9ca3d7236c15d5b76f065a8820d497e76f2aa62880b0593ec4dbd73</originalsourceid><addsrcrecordid>eNpNkMFKxDAQhoMouK6Cj1DwatdJ0japJ6WoW1hUUM8hTbI0S23XpGVZTz6Cz-iTmO568PTP_PzzzTAInWOYYQByVasZwQljB2iCIecxBoYPxzohMcMZPUYn3q8AME5yPkHb57rrO2ek6m3X-qhbRi-KPt6U9c_Xd8Ehkq2OFsN_Z2P7OtLW28Y62ZrrqPRdI8fxXVjV0gWacfZzbwZkIyvbmAhfksCQWg-q96foaCkbb87-dIre7u9ei3m8eHooi9tFvCYEs1gzrhII11e5klQzQjOFU51WLFtClkrOCegkZyb0RMqMcA4VpDk1KtGVZnSKLvbctes-BuN7seoG14aVIvBxBpTAmIr3qU04dCvWzr5LtxUYxPhVUSux-6qYFzulvzCkbG8</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2171603207</pqid></control><display><type>article</type><title>Photoreactions of Sc3N@Ih‐C80 and Lu3N@Ih‐C80 with disilirane: Isolation and characterization of labile 1,2‐adducts</title><source>EZB-FREE-00999 freely available EZB journals</source><source>Alma/SFX Local Collection</source><creator>Kako, Masahiro ; Ozeki, Fumiaki ; Kanzawa, Shinji ; Fukazawa, Shinpei ; Sato, Kumiko ; Yamada, Michio ; Maeda, Yutaka ; Furukawa, Makoto ; Akasaka, Takeshi</creator><creatorcontrib>Kako, Masahiro ; Ozeki, Fumiaki ; Kanzawa, Shinji ; Fukazawa, Shinpei ; Sato, Kumiko ; Yamada, Michio ; Maeda, Yutaka ; Furukawa, Makoto ; Akasaka, Takeshi</creatorcontrib><description>The photolysis of Sc3N@Ih‐C80 with disilirane (1,2‐disilacyclopropane) afforded the corresponding 1,2‐ and 1,4‐adducts. The relatively unstable 1,2‐product was characterized using spectroscopic and electrochemical analyses, and theoretical calculations. The relative energies of the optimized structures are consistent with the experimentally observed isomerization of the 1,2‐adduct to the 1,4‐adduct. The electron‐donating effects of the silyl groups in these products were confirmed by comparing the redox potentials of the related Sc3N@Ih‐C80 derivatives. The relative stabilities and electronic properties of the 1,2‐ and 1,4‐adducts of Lu3N@Ih‐C80 show similar aspects to those obtained for the corresponding Sc3N@Ih‐C80 derivatives.</description><identifier>ISSN: 1042-7163</identifier><identifier>EISSN: 1098-1071</identifier><identifier>DOI: 10.1002/hc.21477</identifier><language>eng</language><publisher>London: Hindawi Limited</publisher><subject>Adducts ; Derivatives ; disilirane ; endohedral metallofullerene ; fullerene ; Isomerization ; organosilicon compound ; Photolysis ; Sc3N@C80 & Lu3N@C80</subject><ispartof>Heteroatom chemistry, 2018-12, Vol.29 (5-6), p.n/a</ispartof><rights>2018 Wiley Periodicals, Inc.</rights><rights>Copyright © 2018 Wiley Periodicals, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-2669-5870 ; 0000-0002-4073-4354</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kako, Masahiro</creatorcontrib><creatorcontrib>Ozeki, Fumiaki</creatorcontrib><creatorcontrib>Kanzawa, Shinji</creatorcontrib><creatorcontrib>Fukazawa, Shinpei</creatorcontrib><creatorcontrib>Sato, Kumiko</creatorcontrib><creatorcontrib>Yamada, Michio</creatorcontrib><creatorcontrib>Maeda, Yutaka</creatorcontrib><creatorcontrib>Furukawa, Makoto</creatorcontrib><creatorcontrib>Akasaka, Takeshi</creatorcontrib><title>Photoreactions of Sc3N@Ih‐C80 and Lu3N@Ih‐C80 with disilirane: Isolation and characterization of labile 1,2‐adducts</title><title>Heteroatom chemistry</title><description>The photolysis of Sc3N@Ih‐C80 with disilirane (1,2‐disilacyclopropane) afforded the corresponding 1,2‐ and 1,4‐adducts. The relatively unstable 1,2‐product was characterized using spectroscopic and electrochemical analyses, and theoretical calculations. The relative energies of the optimized structures are consistent with the experimentally observed isomerization of the 1,2‐adduct to the 1,4‐adduct. The electron‐donating effects of the silyl groups in these products were confirmed by comparing the redox potentials of the related Sc3N@Ih‐C80 derivatives. The relative stabilities and electronic properties of the 1,2‐ and 1,4‐adducts of Lu3N@Ih‐C80 show similar aspects to those obtained for the corresponding Sc3N@Ih‐C80 derivatives.</description><subject>Adducts</subject><subject>Derivatives</subject><subject>disilirane</subject><subject>endohedral metallofullerene</subject><subject>fullerene</subject><subject>Isomerization</subject><subject>organosilicon compound</subject><subject>Photolysis</subject><subject>Sc3N@C80 & Lu3N@C80</subject><issn>1042-7163</issn><issn>1098-1071</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpNkMFKxDAQhoMouK6Cj1DwatdJ0japJ6WoW1hUUM8hTbI0S23XpGVZTz6Cz-iTmO568PTP_PzzzTAInWOYYQByVasZwQljB2iCIecxBoYPxzohMcMZPUYn3q8AME5yPkHb57rrO2ek6m3X-qhbRi-KPt6U9c_Xd8Ehkq2OFsN_Z2P7OtLW28Y62ZrrqPRdI8fxXVjV0gWacfZzbwZkIyvbmAhfksCQWg-q96foaCkbb87-dIre7u9ei3m8eHooi9tFvCYEs1gzrhII11e5klQzQjOFU51WLFtClkrOCegkZyb0RMqMcA4VpDk1KtGVZnSKLvbctes-BuN7seoG14aVIvBxBpTAmIr3qU04dCvWzr5LtxUYxPhVUSux-6qYFzulvzCkbG8</recordid><startdate>201812</startdate><enddate>201812</enddate><creator>Kako, Masahiro</creator><creator>Ozeki, Fumiaki</creator><creator>Kanzawa, Shinji</creator><creator>Fukazawa, Shinpei</creator><creator>Sato, Kumiko</creator><creator>Yamada, Michio</creator><creator>Maeda, Yutaka</creator><creator>Furukawa, Makoto</creator><creator>Akasaka, Takeshi</creator><general>Hindawi Limited</general><scope/><orcidid>https://orcid.org/0000-0002-2669-5870</orcidid><orcidid>https://orcid.org/0000-0002-4073-4354</orcidid></search><sort><creationdate>201812</creationdate><title>Photoreactions of Sc3N@Ih‐C80 and Lu3N@Ih‐C80 with disilirane: Isolation and characterization of labile 1,2‐adducts</title><author>Kako, Masahiro ; Ozeki, Fumiaki ; Kanzawa, Shinji ; Fukazawa, Shinpei ; Sato, Kumiko ; Yamada, Michio ; Maeda, Yutaka ; Furukawa, Makoto ; Akasaka, Takeshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2217-d78c40042b9ca3d7236c15d5b76f065a8820d497e76f2aa62880b0593ec4dbd73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Adducts</topic><topic>Derivatives</topic><topic>disilirane</topic><topic>endohedral metallofullerene</topic><topic>fullerene</topic><topic>Isomerization</topic><topic>organosilicon compound</topic><topic>Photolysis</topic><topic>Sc3N@C80 & Lu3N@C80</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kako, Masahiro</creatorcontrib><creatorcontrib>Ozeki, Fumiaki</creatorcontrib><creatorcontrib>Kanzawa, Shinji</creatorcontrib><creatorcontrib>Fukazawa, Shinpei</creatorcontrib><creatorcontrib>Sato, Kumiko</creatorcontrib><creatorcontrib>Yamada, Michio</creatorcontrib><creatorcontrib>Maeda, Yutaka</creatorcontrib><creatorcontrib>Furukawa, Makoto</creatorcontrib><creatorcontrib>Akasaka, Takeshi</creatorcontrib><jtitle>Heteroatom chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kako, Masahiro</au><au>Ozeki, Fumiaki</au><au>Kanzawa, Shinji</au><au>Fukazawa, Shinpei</au><au>Sato, Kumiko</au><au>Yamada, Michio</au><au>Maeda, Yutaka</au><au>Furukawa, Makoto</au><au>Akasaka, Takeshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photoreactions of Sc3N@Ih‐C80 and Lu3N@Ih‐C80 with disilirane: Isolation and characterization of labile 1,2‐adducts</atitle><jtitle>Heteroatom chemistry</jtitle><date>2018-12</date><risdate>2018</risdate><volume>29</volume><issue>5-6</issue><epage>n/a</epage><issn>1042-7163</issn><eissn>1098-1071</eissn><abstract>The photolysis of Sc3N@Ih‐C80 with disilirane (1,2‐disilacyclopropane) afforded the corresponding 1,2‐ and 1,4‐adducts. The relatively unstable 1,2‐product was characterized using spectroscopic and electrochemical analyses, and theoretical calculations. The relative energies of the optimized structures are consistent with the experimentally observed isomerization of the 1,2‐adduct to the 1,4‐adduct. The electron‐donating effects of the silyl groups in these products were confirmed by comparing the redox potentials of the related Sc3N@Ih‐C80 derivatives. The relative stabilities and electronic properties of the 1,2‐ and 1,4‐adducts of Lu3N@Ih‐C80 show similar aspects to those obtained for the corresponding Sc3N@Ih‐C80 derivatives.</abstract><cop>London</cop><pub>Hindawi Limited</pub><doi>10.1002/hc.21477</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-2669-5870</orcidid><orcidid>https://orcid.org/0000-0002-4073-4354</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1042-7163 |
| ispartof | Heteroatom chemistry, 2018-12, Vol.29 (5-6), p.n/a |
| issn | 1042-7163 1098-1071 |
| language | eng |
| recordid | cdi_proquest_journals_2171603207 |
| source | EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection |
| subjects | Adducts Derivatives disilirane endohedral metallofullerene fullerene Isomerization organosilicon compound Photolysis Sc3N@C80 & Lu3N@C80 |
| title | Photoreactions of Sc3N@Ih‐C80 and Lu3N@Ih‐C80 with disilirane: Isolation and characterization of labile 1,2‐adducts |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T22%3A01%3A54IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Photoreactions%20of%20Sc3N@Ih%E2%80%90C80%20and%20Lu3N@Ih%E2%80%90C80%20with%20disilirane:%20Isolation%20and%20characterization%20of%20labile%201,2%E2%80%90adducts&rft.jtitle=Heteroatom%20chemistry&rft.au=Kako,%20Masahiro&rft.date=2018-12&rft.volume=29&rft.issue=5-6&rft.epage=n/a&rft.issn=1042-7163&rft.eissn=1098-1071&rft_id=info:doi/10.1002/hc.21477&rft_dat=%3Cproquest_wiley%3E2171603207%3C/proquest_wiley%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2171603207&rft_id=info:pmid/&rfr_iscdi=true |